A5003164222- Carbon dioxide utilization in catalysis
- Organometallic Complex Synthesis and Catalysis
- Asymmetric Hydrogenation and Catalysis
- Catalysts for Methane Reforming
- Metal-Organic Frameworks: Synthesis and Applications
- Covalent Organic Framework Applications
- Catalysis and Oxidation Reactions
- Catalytic Processes in Materials Science
- Catalysis for Biomass Conversion
- biodegradable polymer synthesis and properties
- Fluid Dynamics and Mixing
- Chemical Synthesis and Reactions
- Microfluidic and Capillary Electrophoresis Applications
- Educational Innovations and Challenges
- Fusion materials and technologies
- CO2 Reduction Techniques and Catalysts
- Cyclopropane Reaction Mechanisms
- Nanomaterials for catalytic reactions
- nanoparticles nucleation surface interactions
- Catalysis and Hydrodesulfurization Studies
- Innovative Microfluidic and Catalytic Techniques Innovation
- Granular flow and fluidized beds
- Advanced Polymer Synthesis and Characterization
Lomonosov Moscow State University
2018-2024
Moscow State University
2023
Faculty (United Kingdom)
2021
Northern (Arctic) Federal University
2020
Center for Strategic Research
2020
Abstract This review deals with heterogeneous hydroformylation catalysts, specifically metal complexes fixed in an organic polymer structure. It describes the main catalyst synthesis methods, provides data on of unsaturated compounds (including asymmetric hydroformylation), and shows how those can be used. The special focus is systematization catalysts developed basis porous polymers. Due to their structure, resistance media high concentration heteroatoms they contain, these materials...
Due to their unique structural and mechanical characteristics, zeolites are of great interest as carriers for the design catalysts. This review is focused on progress in development new zeolite-based catalysts hydroformylation. The procedures materials synthesis modification, methods metal introduction, effect catalyst structure activity, selectivity, stability hydroformylation discussed. highlights role up-to-date analytical techniques fine-tuned active selective greatest achievements over...
A novel method of producing short-chain acetals <italic>via</italic> tandem hydroformylation–acetalization under biphasic conditions is developed.
Abstract For the first time mixture of methyl formate and water is used as an alternative syngas source for hydroformylation unsaturated compounds in presence rhodium catalysts modified with phosphine ligands to obtain aldehydes. Under reaction conditions, decomposes producing methanol carbon monoxide. The water‐gas shift (WGSR) takes place under same conditions resulting dioxide hydrogen generation. Influence different parameters (temperature, ratios reagents, type ligand) on process...
The article considers network interaction of Russian universities to solve strategic problems macroregions development. Network is a common model cooperation between abroad, and in recent years, connection with the new challenges facing education, it has become relevant for universities. briefly presents main forms organization methods managing interaction, its advantages over traditional types joint activities Based on four years work framework Association “National Arctic Research...
Abstract A phosphine-containing porous polymer (TPDB), and a rhodium catalyst based on it, were synthesized. Proceeding from the relevant TEM, NMR, IR spectroscopy, XPS data obtained, it was assumed that both Rh(I) complexes Rh(0) nanoparticles are stabilized in pores act as catalyst’s active phase. The size of (2–6 nm) is consistent with pores. tested model reaction octene-1 hydroformylation at 2.0 MPa (CO : H 2 = 1 1) temperature range 60–120°C. It demonstrated can be used repeatedly, its...
Homogeneous hydroformylation is an important industrial reaction for the production of aldehydes and alcohols. Rh metal complexes modified with tertiary amine ligands allow tandem one-pot reactions converting olefins directly into alcohols, more often, such are performed in microfluidic flow regimes relevant to both academic research automatization. The yield depends on coordination atoms or formation clusters; therefore, knowledge about local atomic electronic structure active sites under...
Nowadays reductive hydroformylation over Rh/NR3 catalysts is of great interest to both industry and academia, however, some its aspects remain controversial or unclear, including those which might turn essential for developing new active optimization parameters. In this work, we studied in depth separately stages the process – olefins hydrogenation aldehydes, estimated role amine structure them. Also, first time, investigated catalytic system under reaction conditions by situ XAS method gain...