A5007937244- Lanthanide and Transition Metal Complexes
- X-ray Diffraction in Crystallography
- Crystallization and Solubility Studies
- Metal-Organic Frameworks: Synthesis and Applications
- Magnetism in coordination complexes
- Chemical Thermodynamics and Molecular Structure
- Synthesis and Characterization of Heterocyclic Compounds
- Thermal and Kinetic Analysis
- Chemical Reaction Mechanisms
- Polyoxometalates: Synthesis and Applications
- Radioactive element chemistry and processing
- Energetic Materials and Combustion
- Crystal Structures and Properties
- Luminescence Properties of Advanced Materials
- Synthesis and biological activity
- Advanced Polymer Synthesis and Characterization
- Crystal structures of chemical compounds
- Chemical Synthesis and Characterization
- Crystallography and molecular interactions
- biodegradable polymer synthesis and properties
Maria Curie-Skłodowska University
2012-2025
Faculty (United Kingdom)
2014
The thermal characterisation and toxicity profile of a class disubstituted heterofused triazinones were revealed in this article for the first time. behaviour molecules 1–12 was investigated by means TG DSC analyses performed an air atmosphere coupled TG/FTIR technique nitrogen atmosphere. heating affects both stability compounds degradation mechanism. A two-step occurs air, while one-step takes place nitrogen, preceded melting process. Compound 3 shows highest stability, molecule 10—the...
To avoid problems associated with the storage and processing of newly developed potential medicines, there is a need to carry out thermal studies in preclinical phase drug development. The behaviour decomposition pathway whole novel class patented molecular pharmaceutics, i.e., ethyl 2-[4-oxo-8-(R-phenyl)-4,6,7,8-tetrahydroimidazo[2,1-c][1,2,4]triazin-3-yl]acetates (1-6) were reported for first time inert oxidative atmospheres. experiments conducted use simultaneous...
Novel<italic>p</italic>-xylylene-bis(thioacetic) acid (<bold>p-XBTA</bold>) and its co-crystals with 2-amino-4,6-dimethylpyrimidine (DMP) have been synthesized characterized by single-crystal X-ray diffraction, infrared spectroscopy thermal analysis methods (TG/DSC).
Abstract The synthesis and characterization of luminescent hybrid composites based on bisphenol A glycerolate (1 glycerol/phenol) diacrylate (BPA-Acr) as a cross-linking monomer N -vinylpyrrolidone (NVP) an active diluent, in the presence UV initiator (Irgacure 651), are presented. Eu(III) Tb(III) carboxylate complexes were added components composites. In their preparation, constant concentration (1%) BPA-Acr to NVP (10:3) ratio applied. structures obtained materials confirmed by infrared...
Solvothermal reactions of lanthanide (III) salts with 1,2-phenylenediacetic acid in N,N′-dimethylformamide (DMF) solvent lead to the formation metal complexes general formula Ln2(1,2-pda)3(DMF)2, where Ln(III) = Pr(1), Sm(2), Eu(3), Tb(4), Dy(5), and Er(6), 1,2-pda [C6H4(CH2COO)2]2−. The compounds were characterized by elemental analysis, powder single-crystal X-ray diffraction methods, thermal analysis methods (TG-DSC TG-FTIR), infrared luminescence spectroscopy. They exhibit structural...
Two coordination polymers of erbium(III) and neodymium(III) ions with 1,3,5-benzenetricarboxylic acid were synthesized under the solvothermal conditions from dimethylformamide solution. They characterized by attenuated total reflectance Fourier transform spectroscopy (ATR-FTIR), thermogravimetry differential scanning calorimetry (TG-DSC), thermogravimetric analysis coupled infrared (TG-FTIR) X-ray diffractions methods. The single-crystal confirmed formation three-dimensional framework...
In this article, for the first time, TG-DSC and TG-FTIR investigations of potential pharmaceutics, i.e., analgesic anticancer active annelated triazinones (1–9) have been presented. The thermal behaviour these molecules was established in oxidative inert conditions. solid–liquid phase transition each compound documented by one sharp DSC peak confirming high purity sample studied. All were characterised terms calorimetric changes mass during their heating. They revealed stability observed...
Two new 3D coordination polymers (CPs), formulated as [Zn(p-XBT)]n (1H) and [Cd(p-XBT)]n (2H), were assembled from a virtually unexplored p-xylylene-bis(2-mercaptoacetic) acid linker (p-XBTA) characterized by infrared spectroscopy (FTIR), powder X-ray diffraction (PXRD), thermal analysis methods (TG-DSC, TG-FTIR), single-crystal diffraction, topological analysis. different synthetic strategies explored, namely the precipitation (P) hydrothermal (H) methods, resulting in Zn(II) derivative...