A5086374760- X-ray Diffraction in Crystallography
- Crystallization and Solubility Studies
- Metal-Organic Frameworks: Synthesis and Applications
- Covalent Organic Framework Applications
- Boron Compounds in Chemistry
- Plant responses to elevated CO2
- Membrane Separation and Gas Transport
- Crystallography and molecular interactions
- Boron and Carbon Nanomaterials Research
- Organoboron and organosilicon chemistry
- Carbon dioxide utilization in catalysis
- Carbon Dioxide Capture Technologies
- Inorganic Fluorides and Related Compounds
- Radiopharmaceutical Chemistry and Applications
- Parasites and Host Interactions
- Plant Water Relations and Carbon Dynamics
- Parasite Biology and Host Interactions
- Oxidative Organic Chemistry Reactions
- Supramolecular Chemistry and Complexes
- Catalytic Processes in Materials Science
- Radioactive element chemistry and processing
- Ecology and Vegetation Dynamics Studies
- Zeolite Catalysis and Synthesis
- Species Distribution and Climate Change
- Gas Sensing Nanomaterials and Sensors
Zhejiang Normal University
2020-2025
Jiangxi University of Science and Technology
2025
Institute of Mountain Hazards and Environment
2014-2024
Chinese Academy of Sciences
2008-2024
Ningbo University
2023
Third Affiliated Hospital of Southern Medical University
2021-2023
Southern Medical University Shenzhen Hospital
2021-2023
Shandong First Medical University
2023
Zhejiang University
2015-2022
State Key Laboratory of Chemical Engineering
2021
A novel 3D metal-organic framework BSF-1 based on the closo-dodecaborate cluster [B12 H12 ]2- was readily prepared at room temperature by supramolecular assembly of CuB12 and 1,2-bis(4-pyridyl)acetylene. The permanent microporous structure studied X-ray crystallography, powder diffraction, IR spectroscopy, thermogravimetric analysis, gas sorption. experimental theoretical study sorption behavior for N2 , C2 H2 H4 CO2 C3 H8 H6 CH4 indicated excellent separation selectivities /CH4 as well...
Abstract Separation of acetylene (C 2 H ) from carbon dioxide (CO or ethylene 4 is important in industry but limited by the low capacity and selectivity owing to their similar molecular sizes physical properties. Herein, we report two novel dodecaborate‐hybrid metal–organic frameworks, MB 12 (dpb) (termed as BSF‐3 BSF‐3‐Co for M=Cu Co), highly selective capture C . The high remarkable /CO resulted unique anionic boron cluster functionality well suitable pore size with cooperative...
Abstract The separation of C 2 H /CO is an important process in industry but challenged by the trade‐off capacity and selectivity owning to their similar physical properties identical kinetic molecular size. We report first example symmetrically interpenetrated dodecaborate pillared MOF, ZNU‐1, for benchmark selective from CO with a high 76.3 cm 3 g −1 record 56.6 (298 K, 1 bar) among all robust porous materials without open metal sites. Single crystal structure analysis modeling indicated...
Ethylene (C
Propyne/propylene (C3 H4 /C3 H6 ) separation is an important but challenging industrial process to produce polymer-grade C3 and recover high-purity . Herein, we report ultrastable TiF62- anion cross-linked metal-organic framework (ZNU-2) with precisely controlled pore size, shape functionality for benchmark storage (3.9/7.7 mmol g-1 at 0.01/1.0 bar 298 K) record high (10/90) potential (31.0 mol kg-1 ). The remarkable (1/99, 10/90, 50/50) performance was fully demonstrated by simulated...
Abstract The rational design of porous materials for CO 2 capture under realistic process conditions is highly desirable. However, trade‐offs exist among a nanopore's capacity, selectivity, adsorption heat, and stability. In this study, new generation anion‐pillared metal‐organic frameworks (MOFs) are reported with customizable cages benchmark from flue gas. optimally designed TIFSIX‐Cu‐TPA exhibits high excellent /N thermal stability, chemical stability in acid solution acidic atmosphere,...
Separation of acetylene (C2 H2 ) from carbon dioxide (CO2 or ethylene H4 is industrially important but still challenging so far. Herein, we developed two novel robust metal organic frameworks AlFSIX-Cu-TPBDA (ZNU-8) with znv topology and SIFSIX-Cu-TPBDA (ZNU-9) wly for efficient capture C2 CO2 . Both ZNU-8 ZNU-9 feature multiple anion functionalities hierarchical porosity. Notably, more anionic binding sites three distinct cages displays both an extremely large capacity (7.94 mmol/g) a high...
The efficient separation of C2H2 from C2H2/CO2 or C2H2/CO2/CH4 mixtures is crucial for achieving high-purity (>99%), essential in producing contemporary commodity chemicals. In this report, we present ZNU-12, a metal–organic framework with space-partitioned pores formed by inorganic fluorinated anions, highly and separation. framework, partitioned SiF62– anions into three distinct cages, enables both high capacity (176.5 cm3/g at 298 K 1.0 bar) outstanding selectivity over CO2 (13.4) CH4...
The efficient removal of trace impurities is significant for the production high-purity olefins. This review summarizes latest advancements in deep purification ethylene and propylene using MOF materials.
A novel hydrophobic carborane-hybrid microporous metal–organic framework ZNU-10 was prepared for reversed C 2 H 6 adsorption and efficient 4 /C separation under humid conditions.
Abstract 1,2,3‐Trisubstituted closo ‐dodecaborates with B−O, B−N, and B−C bonds as well a fused borane oxazole ring have been synthesized by rhodium‐catalyzed direct cage B−H alkenylation annulation of ureido boranes in the first reported example regioselective bond functionalization [B 12 H ] 2− transition‐metal catalysis. This reaction proceeded at room temperature under ambient conditions exhibited excellent selectivity for efficient monoalkenylation good functional‐group tolerance. The...
A novel ultramicroporous boron cage-hybrid supramolecular framework BSF-2 comprising cluster [B<sub>12</sub>H<sub>11</sub>I]<sup>2−</sup>pillars was designed for highly selective light hydrocarbon separation.
This review provides a comprehensive summary of the research progress metal–organic frameworks in application capture and abatement toxic gases vapors.
The separation of trace alkyne (C2H2/C3H4) impurities from alkenes (C2H4/C3H6) is a significant but challenging process to produce polymer‐grade C2H4 and C3H6. Herein, we reported an optimally designed charge‐separated organic framework CPOS‐1 with confined polar channels for highly efficient alkyne/alkene separation. exhibits excellent stability, remarkably high C2H2 (18.4 cm3/g) C3H4 (20.9 uptakes at 0.01 bar 298 K, benchmark C2H2/C2H4 (25.1) C3H4/C3H6 (43.9) selectivities 1/99 mixtures....
A highly sensitive flexible material TIFSIX-14-Cu-i with benchmark C<sub>3</sub>H<sub>4</sub>/C<sub>3</sub>H<sub>6</sub> separation performance was designed through control of the threshold pressure.
Abstract The synthesis and application of icosahedral boron cluster compounds has been studied extensively since their discovery several decades ago; however, two aspects chemistry have received little attention: possibility to form inorganic/organic fused boraheterocycles potential act as antimicrobial agents. This work comprises the preparation a class 3D diborabenzoxazole analogues with closo ‐dodecaborate in place benzene moiety. presented synthetic procedures provide access wide range...