A5100668520- Crystallization and Solubility Studies
- X-ray Diffraction in Crystallography
- Metal complexes synthesis and properties
- Advanced biosensing and bioanalysis techniques
- Click Chemistry and Applications
- Carbon dioxide utilization in catalysis
- Synthesis and Biological Evaluation
- Nanoplatforms for cancer theranostics
- Organometallic Complex Synthesis and Catalysis
- Lanthanide and Transition Metal Complexes
- Molecular Sensors and Ion Detection
- DNA and Nucleic Acid Chemistry
- biodegradable polymer synthesis and properties
- Organometallic Compounds Synthesis and Characterization
- Composting and Vermicomposting Techniques
- Synthesis and Catalytic Reactions
- Chemical Synthesis and Reactions
- Viral gastroenteritis research and epidemiology
- CO2 Reduction Techniques and Catalysts
- Mycorrhizal Fungi and Plant Interactions
- Electrochemical Analysis and Applications
- Metal-Catalyzed Oxygenation Mechanisms
- Animal Disease Management and Epidemiology
- Chemical Reactions and Isotopes
- Catalytic C–H Functionalization Methods
South China Agricultural University
2020-2025
Chongqing Medical and Pharmaceutical College
2017-2024
Chongqing Medical University
2017-2024
Key Laboratory of Guangdong Province
2024
China University of Petroleum, East China
2024
Soochow University
2021-2024
Chinese Academy of Fishery Sciences
2024
Shanxi Academy of Agricultural Sciences
2023
Shanxi Agricultural University
2023
Zhanjiang Experimental Station
2021
A Ru(<sc>ii</sc>) arene complex displays DNA binding, cleavage, and fluorescence imaging upon visible light illumination.
Comprehensive Summary Eight zwitterionic rare earth metal complexes stabilized by amino‐bridged tris(phenolato) ligands bearing quaternary ammonium side‐arms were synthesized and characterized. These used as single‐component catalysts for the cycloaddition of CO 2 epoxides, their catalytic activities are obviously higher than those binary analogues. Further studies revealed that halide anions (Cl – , Br I ) influenced activity, lanthanum complex iodide anion showed highest activity this...
One-carbon (C1) catalysis refers to the conversion of compounds with a single carbon atom, especially monoxide (CO), dioxide (CO
The photoactivated nanodrug Ru–T FAND by self-assembly of RuDPB and TH287 was developed to achieve triple anti-cancer therapy.
We report the thermally induced self-assembly evolution of 4,4',4″-(1,3,4,6,7,9,9b-heptaazaphenalene-2,5,8-triyl) tris-benzoic acid (HTBA) molecules on Au(111) at submonolayer coverage using scanning tunneling microscopy (STM). STM imaging reveals a structural transformation from honeycomb network stabilized by hydrogen bonds room temperature to step-like phase with partial deprotonation 320 K and finally chiral pinwheel formed fully deprotonated 380 K. The features coexisting enantiomorphic...
An azopyridine-based Ru(<sc>ii</sc>) complex was synthesized as a glutathione (GSH)-responsive photoactivated DNA covalent binding agent.
The Eurasian avian-like swine (EA) H1N1 virus has affected the Chinese industry, and human infection cases have been reported occasionally. However, little is known about pathogenic mechanism of EA virus. In this study, we compared mouse pathogenicity A/swine/Guangdong/YJ4/2014 (YJ4) A/swine/Guangdong/MS285/2017 (MS285) viruses, which had similar genotype to A/Hunan/42443/2015 (HuN-like). None mice inoculated with 106 TCID50 YJ4 survived at 7 days post infection, while survival rate MS285...
The emission enhancement behavior and photocleavage activity of a ruthenium(II) arene complex, [(η6-p-cymene)Ru(dppn)(py)]2+ (1) (dppn = 4,5,9,16-tetraaza-dibenzo[a,c]naphthacene, py pyridine), towards DNA were compared with [(η6-p-cymene)Ru(bpy)(py)]2+ (2), [Ru(bpy)2(dppz)]2+ (3) [Ru(bpy)2(dppn)]2+ (4) (bpy 2,2′-bipyridine, dppz dipyrido-[3,2-a:2′,3′-c]phenazine). It was found that 1 emits fluorescence from the dppn-based ligand-centered (LC) singlet excited state generates oxygen (1O2) LC...
[Ru(bpy)2(py-SO3)](+) (bpy = 2,2'-bipyridine and py-SO3 pyridine-2-sulfonate) was found to undergo dissociation upon visible light irradiation (≥470 nm) via Ru-O homolysis, producing reactive free radical species, is thus able not only photobind but also photocleave DNA in hypoxic conditions.
Super-hydrophobic porous absorbents are convenient, low-cost, efficient and environment-friendly materials in the treatment of oil spills.
Comprehensive Summary Four heterometallic rare earth(III)‐cobalt(II) complexes (rare earth = Y ( 1 ), Sm 2 Nd 3 La 4 )) stabilized by an o ‐phenylenediamine‐bridged tris(phenolato) ligand (L) have been synthesized and characterized. In these tetranuclear complexes, one polydentate L coordinates to earth(III) ion, cobalt(II) respectively, while two ions are bridged four acetate groups. These were applied in the copolymerization of cyclohexene oxide CO , which showed good activity (TON up 440)...
Still fluorescent upon coordination to Ru: [(η6-p-cymene)Ru(dppn)(py)]2+ (dppn=4,5,9,16-tetraaza-dibenzo[a,c]naphthacene) is highly due the coordinated dppn with a fluorescence quantum yield of 0.31 in acetonitrile, which nearly same as free (0.33) and one highest all luminescent RuII complexes. The underlying mechanism may shed light on development arene-based anticancer theranostic agents (see scheme). Detailed facts importance specialist readers are published "Supporting Information"....
TNBG-5602 is a newly synthesized compound with an isoquinoline structure. In the present study, we demonstrated anticancer effect of in in-vitro and in-vivo models investigated its possible mechanism.The antiproliferation vitro was evaluated human liver cancer cell line QGY-7701. The acute toxicity mice. activity vivo assessed xenograft model QGY-7701.The results CCK-8 assay showed that can effectively inhibit proliferation cells vitro. test mice LD50 172 mg/kg. model, could remarkably...
Dinuclear aluminum methyl complexes bearing aromatic diamine-bridged tetra(phenolato) ligands and the mononuclear complex with phenylamine-bridged bis(phenolato) ligand have been synthesized characterized. Structure determination revealed that Al-Al distances in these dinuclear are tunable by choice of suitable backbone ligands. The catalytic behaviors mono- for cyclohexene oxide (CHO) polymerization were investigated. activities Al observed to increase decrease distances, appeared better...
With a decrease in the basicity of monodentate ligand X, photodissociation efficiencies complexes increase gradually.