A5003969062- Advanced Photocatalysis Techniques
- Chemistry and Chemical Engineering
- Various Chemistry Research Topics
- Metal-Organic Frameworks: Synthesis and Applications
- History and advancements in chemistry
- Catalytic Processes in Materials Science
- TiO2 Photocatalysis and Solar Cells
- Coordination Chemistry and Organometallics
- Catalysis and Oxidation Reactions
- Catalysts for Methane Reforming
- Science, Research, and Medicine
- Covalent Organic Framework Applications
- Advanced Nanomaterials in Catalysis
- Catalytic Cross-Coupling Reactions
- N-Heterocyclic Carbenes in Organic and Inorganic Chemistry
ETH Zurich
2015-2017
Bioengineering (Switzerland)
2015
Charles Humbert 8
2015
University of Auckland
2012
Trinity College Dublin
2010
Abstract A composite of the metal–organic framework (MOF) NH 2 ‐MIL‐125(Ti) and molecular ionic nickel(II) species, catalyzed hydrogen evolution from water under UV light. In 95 v/v % aqueous conditions produced in quantities two orders magnitude higher than that virgin an order greater catalyst. a acetonitrile mixture, demonstrated TOF 28 mol H g(Ni) −1 h remained active for up to 50 h, sustaining catalysis three times longer yielding 20‐fold amount hydrogen. Appraisal physical mixtures MOF...
Treatment of N2,N6-bis(6-acrylamidopyridin-2-yl)pyridine-2,6-dicarboxamide with benzimidazole gives the acyclic aza-Michael addition product N2,N6-bis(6-(3-(1H-benzo[d]imidazol-1-yl)propanamido)pyridin-2-yl)pyridine-2,6-dicarboxamide (2). The macrocycle N1,N7-pyridine-2,6-dimethyl-N2,N6-bis(6-(3-(1H-benzo[d]imidazol-1-yl)propanamido)pyridin-2-yl)pyridine-2,6-dicarboxamide dibromide ([H2L2]Br2) is formed through double alkylation 2 2,6-bis(bromomethyl)pyridine. imidazole analogues and...
Metal organic frameworks offer an impressive physical, chemical and electronic mutability for sustaining water splitting half-reactions under several catalytic regimes.
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