A5028875697- Crystallization and Solubility Studies
- X-ray Diffraction in Crystallography
- Synthesis and characterization of novel inorganic/organometallic compounds
- Organometallic Complex Synthesis and Catalysis
- Organoboron and organosilicon chemistry
- Inorganic Chemistry and Materials
- Inorganic Fluorides and Related Compounds
- Fluorine in Organic Chemistry
- N-Heterocyclic Carbenes in Organic and Inorganic Chemistry
- Cryospheric studies and observations
- Zeolite Catalysis and Synthesis
- French Urban and Social Studies
- Advanced Battery Materials and Technologies
- Polar Research and Ecology
- Advancements in Battery Materials
- Coordination Chemistry and Organometallics
- Geology and Paleoclimatology Research
- Asymmetric Hydrogenation and Catalysis
University of Freiburg
2020-2024
Bibliothèque Nationale du Royaume du Maroc
2014
École nationale supérieure des sciences de l'information et des bibliothèques
2014
Bibliothèque Nationale de France
2014
Abstract Weakly coordinating anions (WCAs) are considered promising candidates for application as electrolytes in multivalent post‐lithium batteries. One strong candidate electrolyte salt Mg battery is [Mg(L) x ][Al(OR F ) 4 ] 2 (L=MeCN (acetonitrile), DME (1,2‐dimethoxyethane); =3, 6; R =C(CF 3 that contains [Al(OR − one of the least WCAs known. Here we present a novel synthetic route, which vibrational, NMR and XRD analyses show formation clean, pristine without common contaminants found...
Syntheses and characterization of two salts [(L)GaGa(L)][pf]2 ([pf]- = [Al(ORF)4]-; RF C(CF3)3) are reported. They include the first dicationic digallene [(L)Ga⇆Ga(L)]2+ (L CDPPh C(PPh3)2) a digallane [(L)Ga-Ga(L)]2+ [NacNacMes]-). The CDPPh-supported dication includes trans-bent [L-GaGa-L]2+ bond that is analogous to neutral R-GaGa-R molecules related Robinson's famous "Digallyne" [R-GaGa-R]2-. widely used "Jones magnesium dimer", but very short GaII-GaII single bond.
Abstract The earth‐metal olefin complex [Ga I (COD) 2 ] + [Al(OR F ) 4 − (COD=1,5‐cyclooctadiene; R =C(CF 3 constitutes the first homoleptic of any main‐group metal accessible as a bulk compound. It is straight forward to prepare in good yield and an that—similar many transition‐metals—may adopt +1 +3 oxidation states opening potential applications. Crystallographic‐, vibrational‐ computational investigations give insight atypical bonding between metal. They are compared classical...
Abstract In this work, we present the solid‐state structures of solvent‐free Ga[ pf ] and In[ salts ([ − =[Al(OR F ) 4 ; R =C(CF 3 ), which are very rare examples with truly ‘naked’ metal cations. Both may serve as starting materials for subvalent gallium indium chemistry weakly coordinating ligands providing freedom choice solvents future. On other hand, report rationalize formation isolation [M(OEt 2 ][ [M(MeCN) (M=Ga, In), underlining surprising stability these group 13 M + ions against...
Abstract This review addresses the coordination chemistry (mainly) enabled by using univalent [M(fluoroarene) 2–3 ] + [Al(OR F ) 4 − ‐salts (M=Ga, In; R =C(CF 3 as robust starting materials. In course of this work, it became clear that orbital energy n s 2 (n=4, 5) lone pair in such [:M(L) cations reacts drastically depending on quality ligand employed. Activation with strong σ‐donor ligands might be used for bond activation and oxidative addition reactions. Yet, unexpectedly, sterically...
The reaction of bisdicyclohexylphosphinoethane (dcpe) and the subvalent M
The tetracationic, univalent cluster compounds [{M(dmpe)}
Already 1 mol% of subvalent [Ga(PhF)2]+[pf]- ([pf]- = [Al(ORF)4]-, RF C(CF3)3) initiates the hydrosilylation olefinic double bonds under mild conditions. Reactions with HSiMe3 and HSiEt3 as substrates efficiently yield anti-Markovnikov anti-addition products, while bulkier such HSiiPr3 are less reactive. Investigating underlying mechanism by gas chromatography STEM analysis, we unexpectedly found that H2 metallic Ga0 formed. Without addition olefins, formation R3Si-F-Al(ORF)3 (R alkyl), a...
Over recent decades, the West Antarctic Ice Sheet (WAIS) has witnessed a large increase in ice shelf melting. This loss is recognized to be associated with response changes ocean state, particular of Circumpolar Deep Water (CDW) on Amundsen Sea continental shelf. It been shown that variability CDW inflow strongly related wind changes. While instrumental-based atmospheric reanalysis products are available since 1979, given strong natural climate, this period few decades might too short...
New perspectives in GaI and InI chemistry: The salts of 'naked' M+ (M = Ga, In) ions with a weakly coordinating, fluorinated alkoxyaluminate anion have been isolated, the stability this coordinating solvents acetonitrile diethyl ether has demonstrated. results will allow coordination chemistry weak ligands reactivity standard to be examined. cover portrays these new possibilities as hikers mysterious nighttime landscape. More information can found Research Article by I. Krossing co-workers...
Abstract The earth‐metal olefin complex [Ga I (COD) 2 ] + [Al(OR F ) 4 − (COD=1,5‐cyclooctadiene; R =C(CF 3 constitutes the first homoleptic of any main‐group metal accessible as a bulk compound. It is straight forward to prepare in good yield and an that—similar many transition‐metals—may adopt +1 +3 oxidation states opening potential applications. Crystallographic‐, vibrational‐ computational investigations give insight atypical bonding between metal. They are compared classical...
Abstract Die Reaktion von Bis dicyclohexylphosphinoethan (dcpe) und den subvalenten M I ‐Quellen [M (PhF) 2 ][ pf ] (M=Ga + , In ; [ − =[Al(OR F ) 4 R =C(CF 3 ergab die Salze [{M(dcpe)} ersten bisher dokumentierten dikationischen, trans ‐gefalteten Digallen‐ Diindenstrukturen enthalten. nicht‐klassischen ⇆M ‐Doppelbindungen sind überraschend kurz zeigen eine ditetrylenartige Struktur. Bindungssituation wurde durch quantenchemische Berechnungen, QTAIM‐ ( Quantum Theory of Atoms in Molecules...