A5071486260- Organometallic Complex Synthesis and Catalysis
- Synthesis and characterization of novel inorganic/organometallic compounds
- X-ray Diffraction in Crystallography
- Crystallization and Solubility Studies
- Ferrocene Chemistry and Applications
- Mesoporous Materials and Catalysis
- Synthetic Organic Chemistry Methods
- Coordination Chemistry and Organometallics
- Carbon dioxide utilization in catalysis
- Polyoxometalates: Synthesis and Applications
- Chemical Synthesis and Reactions
- Metal complexes synthesis and properties
- Inorganic Chemistry and Materials
- Nanomaterials for catalytic reactions
- biodegradable polymer synthesis and properties
- Organoboron and organosilicon chemistry
- Analytical Chemistry and Chromatography
- Crystallography and molecular interactions
- Adsorption and biosorption for pollutant removal
- Zeolite Catalysis and Synthesis
- Analytical chemistry methods development
- Organometallic Compounds Synthesis and Characterization
- Electrochemical Analysis and Applications
- Magnetism in coordination complexes
- Carbohydrate Chemistry and Synthesis
Universidad Rey Juan Carlos
2010-2019
Instituto de Química y Fisicoquímica Biológicas
2014-2018
Hospital Universitario de Móstoles
2015
Higher Institute of Technologies and Applied Sciences
2014
Universidad Autónoma de Occidente
2012
University of Castilla-La Mancha
1996-2008
Universidad de Alcalá
1992-2003
Centre National de la Recherche Scientifique
1996-1999
Universitat Autònoma de Barcelona
1997
Freie Universität Berlin
1996
Mesoporous silica material based drug delivery systems (DDSs) containing curcumin show biocompatibility in normal cells and an effective anti-cancer effect cancer cells.
A mesoporous silica (SBA-15) has been chemically modified with 2-mercaptopyrimidine using the homogeneous route. This synthetic route involved reaction of 3-chloropropyltriethoxysilane prior to immobilization on support. The resulting material characterized by powder X-ray diffraction, nitrogen gas sorption, FT-IR and MAS NMR spectroscopy, thermogravimetry elemental analysis. solid was employed as a Cd(II) adsorbent from aqueous solutions at room temperature. effects several variables...
The reaction of the heteroscorpionate lithium salts [Li(tbpamd)(THF)] [tbpamd = N-ethyl-N'-tert-butylbis(3,5-dimethylpyrazol-1-yl)acetamidinate] and [Li(pbpamd)(THF)] [pbpamd N,N'-diisopropylbis(3,5-dimethylpyrazol-1-yl)acetamidinate] with 1 equiv RMgCl proceeds to give very high yields neutral alkyl magnesium complexes [Mg(R)(NNN)] (NNN tbpamd, R C3H5 1, tBu 2, CH2SiMe3 3; NNN pbpamd, 4, 5, 6). On heating toluene solutions 1−3, 6, a ligand redistribution process occurs corresponding...
The reaction of the hybrid scorpionate/cyclopentadienyl lithium salt [Li(bpzcp)(THF)] [bpzcp = 2,2-bis(3,5-dimethylpyrazol-1-yl)-1,1-diphenylethylcyclopentadienyl] with 1 equiv RMgCl proceeds cleanly to give very high yields corresponding monoalkyl κ2-NN-η5-C5H4 magnesium complexes [Mg(R)(κ2-η5-bpzcp)] (R Me 1, Et 2, nBu 3, tBu 4, CH2SiMe3 5, CH2Ph 6). Hydrolysis NH4Cl/H2O in ether affords two previously described regioisomers: (bpzcpH)...
Abstract The next generation : grafting of titanocene complexes on the surfaces MCM‐41 and SBA‐15 led to a new anticancer drugs, which are very active against human cancer cells. magnified image Dehydroxylated were modified by two different ([Ti(η 5 ‐C H 4 Me) 2 Cl ] [Ti{Me Si(η Me )(η )}Cl ]) give materials, have been characterized powder X‐ray diffraction, fluorescence, nitrogen gas sorption, MAS‐NMR spectroscopy, thermogravimetry, SEM, TEM. toxicity resulting materials toward...
The reaction of bis(3,5-di-tert-butylpyrazol-1-yl)methane (bdtbpzm) with BunLi and carbodiimide derivatives, namely, N,N′-diisopropyl 1-tert-butyl-3-ethyl carbodiimides, gives rise to the new sterically hindered lithium acetamidinate [Li(tbptamd)(THF)] (1) [tbptamd = N-ethyl-N′-tert-butylbis(3,5-di-tert-butylpyrazol-1-yl)acetamidinate] [Li(pbptamd)(THF)] (2) [pbptamd N,N′-diisopropylbis(3,5-di-tert-butylpyrazol-1-yl)acetamidinate]. Subsequent hydrolysis 1 2, recently reported...
Mesoporous silicas (SBA-15 and MCM-41) have been functionalized by two different methods. Using the heterogeneous route silylating agent, 3-chloropropyltriethoxysilane, was initially immobilized onto mesoporous silica surface to give chlorinated Cl-SBA-15 or Cl-MCM-41. In a second reaction multifunctionalized N,S donor compound (2-mercaptobenzothiazol) incorporated obtain denoted as MBT-SBA-15-Het MBT-MCM-41-Het. homogeneous route, functionalization achieved via one step of with an organic...
Four different titanocene complexes, [Ti(η5-C5H5)2Cl2] (1), [Ti(η5-C5H5)(η5-C5H4Pri)Cl2] (2), [Ti(η5-C5H5)(η5-C5H4But)Cl2] (3) and [Ti(η5-C5H5){η5-C5H3(SiMe3)2}Cl2] (4), have been grafted onto dehydroxylated MCM-41 to give the novel materials MCM-41/[Ti(η5-C5H5)2Cl2] (S1), MCM-41/[Ti(η5-C5H5)(η5-C5H4Pri)Cl2] (S2), MCM-41/[Ti(η5-C5H5)(η5-C5H4But)Cl2] (S3) MCM-41/[Ti(η5-C5H5){η5-C5H3(SiMe3)2}Cl2] (S4), which characterized by powder X-ray diffraction, fluorescence, nitrogen gas sorption,...
Pd nanoparticles have been supported onto SBA-15 and MSU-2 present interesting catalytic cytotoxic properties.
Abstract A series of alkenyl‐substituted titanocene compounds have been supported on the mesoporous silica‐based material KIT‐6. The corresponding functionalised materials were completely characterised by different techniques (solid‐state multinuclear NMR spectroscopy, IR N 2 adsorption–desorption isotherms, X‐ray fluorescence and diffraction, SEM TEM) to observe incorporation derivatives external surface Both tested in vitro against a wide variety human cancer normal cell lines. very high...
The new title complexes of tantalum are true hydrides whereas the niobium have bonding interactions among three hydrogen atoms, as evidenced by short n.m.r. T1 values and unusual couplings 1J(H,H) which vary with temperature from less than 3 to about 100 Hz.
Abstract In this work, a mesoporous silica has been chemically modified with 5‐mercapto‐1‐methyl‐1‐H‐tetrazol using the homogeneous route (MTTZ‐HMS). This synthetic involved reaction of 3‐chloropropyltriethoxysilane, prior to immobilization on support. The resulting material characterized and employed as solid phase extractant for Pb(II). effect several variables (stirring time, pH, temperature, metal concentration, presence other metals) studied batch column techniques. experiments, 15 min...