Ilya V. Korolkov

ORCID: 0000-0003-4419-1040
Publications
Citations
Views
---
Saved
---
About
Contact & Profiles
Research Areas
  • Crystallization and Solubility Studies
  • X-ray Diffraction in Crystallography
  • Magnetism in coordination complexes
  • Lanthanide and Transition Metal Complexes
  • Crystallography and molecular interactions
  • Metal complexes synthesis and properties
  • Crystal structures of chemical compounds
  • Metal-Organic Frameworks: Synthesis and Applications
  • Luminescence Properties of Advanced Materials
  • Thermal and Kinetic Analysis
  • Inorganic Chemistry and Materials
  • Semiconductor materials and devices
  • Organometallic Compounds Synthesis and Characterization
  • Chemical Thermodynamics and Molecular Structure
  • Organometallic Complex Synthesis and Catalysis
  • Crystal Structures and Properties
  • Solid-state spectroscopy and crystallography
  • Polyoxometalates: Synthesis and Applications
  • Catalysis and Oxidation Reactions
  • Inorganic Fluorides and Related Compounds
  • Radioactive element chemistry and processing
  • Inorganic and Organometallic Chemistry
  • Perovskite Materials and Applications
  • Electronic and Structural Properties of Oxides
  • Chemical Synthesis and Characterization

Siberian Branch of the Russian Academy of Sciences
2016-2025

Nikolaev Institute of Inorganic Chemistry
2015-2024

Kemerovo State University
2021-2022

Novosibirsk State University
2003-2021

Novosibirsk Tuberculosis Research Institute
2017-2021

Russian Academy of Sciences
2002-2016

Far Eastern State Transport University
2012

Japan Synchrotron Radiation Research Institute
2005

Lviv University
2005

Shiraz University
2004

A high quality inclusion-free Bi2Se3 crystal has been grown by the Bridgman method with use of a rotating heat field. large-area atomically flat Bi2Se3(0001) surface excellent crystallographic formed cleavage. Chemical and microstructural properties have evaluated reflection high-energy electron diffraction, atomic force microscopy (AFM), scanning tunneling (STM), spectroscopic ellipsometry, X-ray photoelectron spectroscopy. There was no oxidation detected after over month in air under...

10.1021/cg201163v article EN Crystal Growth & Design 2011-10-10

The redox-active rhenium octahedral cluster unit [Re6Se8(CN)6]4– was combined with Gd3+ ions and dicarboxylate linkers in novel types of metal–organic frameworks (MOFs) that display a set functional properties. hydrolytically stable complexes [{Gd(H2O)3}2(L)Re6Se8(CN)6]·nH2O (1, L = furan-2,5-dicarboxylate, fdc; 2, thiophene-2,5-dicarboxylate, tdc) exhibit 3D framework trigonal symmetry where 1D chains [{Gd(H2O)3}2(L)]4+ are connected by clusters. Frameworks contain spacious channels filled...

10.1021/acs.inorgchem.7b02974 article EN Inorganic Chemistry 2018-02-05

In the presence of different cations, reactions [SbBr6 ]3- and I2 result in a new family diverse supramolecular 1D polyiodide-bromoantimonate networks. The coordination number Sb, as well geometry assembling {Ix }n- polyhalide units, can vary, resulting unprecedented structural types. nature I⋅⋅⋅Br interactions was studied by DFT calculations; estimated energy values are 1.6-6.9 kcal mol-1 . Some compounds showed strong photoconductivity thin films, suggesting multiple feasible applications...

10.1002/chem.201802100 article EN Chemistry - A European Journal 2018-07-19

Reactions between BiCl 3 , Br 2 and chlorides of pyridinium ( 1 ), 4,4′‐propylenedipyridinium or trimethylphenylammonium ) in aqueous HCl lead to the formation chlorobismuthate complexes trapping {Br } solid state into two‐dimensional polyhalide supramolecular networks. The nature non‐covalent ··· Cl interactions was studied by theoretical methods; estimated energies these are 1.9–6.0 kcal/mol.

10.1002/ejic.201700908 article EN European Journal of Inorganic Chemistry 2017-10-25

Reactions of [SbBr6]3– containing HBr solutions with bromide salts 1,1′-(1,2-ethanediyl)bis(pyridine) (PyC22+) or 1,1′-(1,2-ethanediyl)bis(3,5-dimethylpyridine) (3,5-MePyC22+) initially result in the formation deep orange complexes Cat[SbBr5] (1 and 2), featuring unusual Sb···Br interactions solid state. In mother liquor, 1 transforms into discrete binuclear (C2Py)2[Sb2Br10], which demonstrates polymorphism (triclinic 3 monoclinic 4), while 2 polymeric (3,5-MePy){[SbBr4]} (5). DFT...

10.1021/acs.inorgchem.0c03699 article EN Inorganic Chemistry 2021-01-26

Three novel polybromotellurates(IV) were obtained by reactions of TeO 2 in conc. HBr with Br and tri‐ or tetraalkylammonium salts. They contain [TeBr 6 ] 2– octahedra connected {Br } linkers into one‐ pseudo‐two‐dimensional networks. The thermal stability the products was investigated TGA; additionally, all compounds characterized Raman spectroscopy. Energies ··· interactions estimated DFT calculations (QTAIM method).

10.1002/ejic.201800383 article EN European Journal of Inorganic Chemistry 2018-06-04

A mononuclear complex, [FeL2](BF4)2·xH2O (1LS∙xH2O), where L is 4-(3,5-dimethyl-1H-pyrazol-1-yl)-2-(pyridin-2-yl)-6-methylpyrimidine, can be converted into several phases showing different spin crossover regimes. In the first heating 1LS∙xH2O loses water molecules and converts a mixture of two high phases, 1A/HS 1C/HS. Further cycling produces low phase 1A/LS. The transition 1A/LS↔1A/HS accompanied by 130 K wide hysteresis loop (Tc↑ = 490 K, Tc↓ 360 K). Annealing complex at 500 yields 1C/HS...

10.1039/c3dt53440e article EN Dalton Transactions 2013-12-23

New binuclear chloride and bromide complexes of Bi(<sc>iii</sc>) demonstrate strong reversible solvatochromism.

10.1039/c5nj00889a article EN New Journal of Chemistry 2015-01-01
Coming Soon ...