A5012561717- Metal-Organic Frameworks: Synthesis and Applications
- Process Optimization and Integration
- Chemical Synthesis and Characterization
- Adsorption and biosorption for pollutant removal
- Advanced Control Systems Optimization
- Zeolite Catalysis and Synthesis
- Covalent Organic Framework Applications
- Membrane Separation and Gas Transport
- Mesoporous Materials and Catalysis
- Plant Micronutrient Interactions and Effects
- Membrane Separation Technologies
- Extraction and Separation Processes
- Radioactive element chemistry and processing
- Boron Compounds in Chemistry
- Catalysis for Biomass Conversion
- Innovative Microfluidic and Catalytic Techniques Innovation
- Muon and positron interactions and applications
- Analytical Chemistry and Chromatography
- Chemical and Physical Properties in Aqueous Solutions
- Phase Equilibria and Thermodynamics
- Thermodynamic properties of mixtures
- Boron and Carbon Nanomaterials Research
- MXene and MAX Phase Materials
- Catalytic Processes in Materials Science
- Magnesium Oxide Properties and Applications
Hong Kong Polytechnic University
2025
Tianjin University
2015-2024
Collaborative Innovation Center of Chemical Science and Engineering Tianjin
2024
State Key Laboratory of Chemical Engineering
2024
Ministry of Education of the People's Republic of China
2014-2023
Powder Metallurgy Institute
2015
National Institute of Technology Warangal
2015
Northeast Forestry University
2009-2010
Zhaotong University
2005
Topology and porosity control of Zr6-based MOFs was achieved by introducing steric functionalization into the conformations substituted tetracarboxylate linkers.
Ginsenosides, the major bioactive components of Panax ginseng, are regarded as promising high-value pharmaceutical compounds. In ginsenosides produced from their precursor protopanaxadiol. Recently, an artificial biosynthetic pathway protopanaxadiol was built in Saccharomyces cerevisiae by introducing a P. ginseng dammarenediol-II synthase, cytochrome P450-type synthase (PPDS), and Arabidopsis thaliana NADPH-cytochrome P450 reductase (ATR1). this engineered yeast strain, however, low...
Metal–organic frameworks (MOFs) have been extensively investigated as Lewis acidic catalysts for a variety of reactions. However, the identity and nature MOF nodes in catalysis remain ill-defined. Herein, series isostructural MOFs (M-NU-1008), with M being hexanuclear clusters transition metals (Zr Hf), lanthanide (Ce), or an actinide (Th), were successfully synthesized evaluated acid catalysts, CO2 cycloaddition styrene oxide was used test reaction. Superior catalytic activity observed...
Zr6-based metal–organic frameworks (MOFs) with tetratopic organic linkers have been extensively investigated owing to their versatile structural tunability. While diverse topologies and polymorphism in the resulting MOFs are often encountered Zr6 nodes, reports on phase transitions within these systems rare. Thus, we a limited understanding of polymorph transformations, hindering rational development pure materials. In this study, transition from microporous MOF, scu-NU-906, mesoporous...
Abstract The intrinsic porosity in the periodic structures of metal–organic frameworks (MOFs) endows them with a great potential for membrane separation. However, facile fabrication crystalline MOF membranes has been challenging and limited to few materials economic environmental considerations. Herein, continuous Zr‐MOF thin film thickness ≈180 nm fabricated via situ recrystallization nanoparticles on porous support under formic acid vapor. Owing inherent microporosity well‐established...
Water-stable metal–organic framework (MOF) UiO-66 was studied in boron removal from water for the first time. XRD, SEM, nitrogen adsorption/desorption isotherms, and thermogravimetric analysis (TG) were employed to confirm structure. The adsorption kinetics, thermodynamics, mechanism, recycling on further investigated batch process. exhibits great performance of 10.59 mmol·g–1 at 45 °C, process reaches equilibrium rapidly 1 h. Pseudo-second-order model, intraparticle diffusion, Boyd model...
Abstract Hybrid metal halide perovskite solar cells (PSCs) are emerging as highly competitive next‐generation photovoltaics due to their excellent performance and low production cost. However, the construction of high‐efficiency PSCs typically requires an inert nitrogen environment within a glove box, inadvertently increasing manufacturing costs hindering transition from lab‐scale industrial‐scale production. In this work, air ambient fabrication pure α‐phase FAPbI 3 with stability,...
Ethanol is a more reduced substrate than sugars. Here, 13 C‐metabolic flux analysis (MFA) revealed that ethanol catabolism could supply sufficient acetyl‐CoA and reducing equivalent for PPD biosynthesis. Then, we described modular engineering strategy to optimize multigene pathway protopanaxadiol (PPD) production from in Saccharomyces cerevisiae . biosynthesis was divided into four modules: mevalonate (MVA) module, triterpene sterol formation module. Combinatorially overexpressing every gene...
Selected by the conductive value change (Δ) caused generated proton in boric acid-polyol solutions, pyrocatechol (CL) and nitropyrocatechol (NCL) were grafted into mesoporous MCM-41 material for boron removal isotopic separation. The adsorption kinetics, isotherms thermodynamics, effect of pH, mechanism, regeneration, separation performance on new materials explored this study. equilibrium was reached within 10 h, with maximum capacity reaching up to 1.799 mmol g–1 CL-MCM-41 at pH 9 1.548...
The continuously developing lithium battery market makes seeking a reliable supply top priority for technology companies. Although metal–organic frameworks have been extensively researched as adsorbents owing to their exceptional properties, adsorption has scarcely investigated. Herein, we prepared novel cuboid rod-shaped three-dimensional framework termed TJU-21 composed of fluorine-pillared coordination layers Fe–O inorganic chains and benzene-1,3,5-tricarboxylate (BTC) linkages. Besides...
ZSM-5 (Zeolite Scony Moblie-5) (SiO2/Al2O3 = 360, 470), NaY, 13X (pellet, powder) and coconut shell activated carbon (YK-AC) are employed for acetic acid separation from dilute aqueous solutions via adsorption. Zeolite exhibits a much higher adsorption capacity than other zeolites carbon. The effects of time different initial concentrations were studied. At 71.77 g·kg–1, the concentration, in pellet exhibited highest uptake 354.03 mg·g–1 at 318 K. Meanwhile, equilibrium, kinetics,...