A5066297730- Crystallization and Solubility Studies
- X-ray Diffraction in Crystallography
- Organometallic Compounds Synthesis and Characterization
- Crystal structures of chemical compounds
- Crystallography and molecular interactions
- Metal complexes synthesis and properties
- Synthesis and biological activity
- Organometallic Complex Synthesis and Catalysis
- Organoboron and organosilicon chemistry
- Synthesis and characterization of novel inorganic/organometallic compounds
- Thermal and Kinetic Analysis
- Metal-Organic Frameworks: Synthesis and Applications
- Synthesis and Characterization of Heterocyclic Compounds
- Electrocatalysts for Energy Conversion
- Nonlinear Optical Materials Research
- Structural and Chemical Analysis of Organic and Inorganic Compounds
- Inorganic and Organometallic Chemistry
- Synthesis and Reactivity of Sulfur-Containing Compounds
- Chemical Synthesis and Reactions
- Chalcogenide Semiconductor Thin Films
- Advanced battery technologies research
- Covalent Organic Framework Applications
- Ferrocene Chemistry and Applications
- Fuel Cells and Related Materials
- Polyoxometalates: Synthesis and Applications
Allama Iqbal Open University
2014-2024
Government College University, Lahore
2024
Middlebury College
2024
Pakistan Institute of Engineering and Applied Sciences
2023
Mirpur University of Science and Technology
2022
Quaid-i-Azam University
2000-2009
University of Bayreuth
2002-2003
Fuel cell technology is the supreme alternate option for replacement of fossil fuel in current era. Pt alloys can perform well as electrodes being used catalytic materials to very notorious oxygen reduction reaction. In this regard, first, a layered metal-organic framework with empirical formula [C8H10CdO7] n ·4H2O synthesized and characterized using various experimental theoretical techniques. Then, nanostructured porous carbon material sheet morphology (PC900) having high BET surface area...
In the current study, two organic salts (1 and 2) are synthesized, then crystalline structures characterized by FTIR, UV spectroscopy, X-ray crystallographic studies. The 1 2 optimized at M06/6-311G(d,p)level of theory further utilized for analysis natural bond orbitals (NBOs), population, frontier molecular (FMOs), global reactivity parameters, which confirmed stability studied compounds charge transfer phenomenon in compounds. studies revealed that more stable than 3. lowest energy merged...
Electrocatalytic hydrogen generation in alkaline medium has become widely used a variety of sectors. However, the possibility for additional performance improvement is hampered by slow kinetics. Because this restriction, careful control over processes such as water dissociation, hydroxyl desorption and recombination required. Covalent organic frameworks (COFs) based on porphyrin polyoxometalates (POMs) show encouraging electrocatalytic performance, offering viable route effective sustainable...
Abstract Four novel thiourea derivatives containing a thiazole moiety were synthesized and characterized by IR, 1H 13C NMR, mass spectrometry elemental analysis. The crystal structure of 1a was determined from single X-ray diffraction data. It crystallizes in monoclinic space group P21/n with unit cell dimensions = 11.7752(6) Å, b= 3.8677(2) c= 27.4126(13) Å β 92.734(5) Å. There is strong intramolecular hydrogen bond the type N-H⋯O, H⋯O distance 2.5869(19) fragmentation pattern has also been...
(Z)-4-(4-cyanophenylamino)-4-oxobut-2-enoic acid (LH) and its new triphenyltin (IV) derivative (Ph3SnL) were synthesized further investigated for their binding with ds.DNA under physiological conditions {pH: 4.7 (stomach); 7.4 (blood), 37 °C} using UV–Visible/fluorescence spectroscopy, cyclic voltammetry viscosity measurement techniques. Spectral responses as well experimental findings from all the techniques i.e., constant (Kb), site size (n) free energy change (ΔG) correlated each other...
Tributyltin (IV) compounds are promising candidates for drug development. In the current study, we evaluated in-vitro and in-silico profile of carboxylate derivatives tributyltin complexes.ADMET drug-likeliness properties were predicted using MetaPrint2D React, preADMET, SwissADME Molsoft tools. SwissTargetPrediction molecular targets compounds. In-vitro bioactivity was by quantifying cytotoxicity against HepG2, THP-1 cell lines, isolated lymphocytes leishmania promastigotes as well...
MIL-101(Cr), an achiral metal-organic framework, made up of a terephthalic acid ligand and metal chromium ion was selected as template. Its structural features are unsaturated Lewis sites that can be easily activated it has extremely high specific surface area, big pore size, good thermal/chemical/water stability. This framework modified to introduce chirality within the structure develop chiral frameworks (CMOFs). Here, natural ligands, amino acids (l-proline, l-thioproline l-tyrosine),...
Gemcitabine (GEM) is used to treat various cancers such as breast, pancreatic, non-small lung, ovarian, bladder, and cervical cancers. GEM, however, has the problem of non-selectivity. Water-soluble, fluorescent, mono-dispersed carbon dots (CDs) were fabricated by ultrasonication sucrose. The CDs further conjugated with GEM through amide linkage. physical morphological properties these dot-gemcitabine (CD-GEM) conjugates determined using different analytical techniques. In vitro cytotoxicity...