The CO2 solubilities (including Henry's constant) in physical- and chemical-based ILs/DESs the COSMO-RS models describing these properties were comprehensively collected summarized. summarized results indicate that are superior to physical-based for capture, especially those ILs have functionalized cation anion, superbase DESs; some of DESs higher than ILs; best ILs, as well [BMIM][BF4] (4.20 mol kg−1), [DETAH][Im] (11.91 [L-Arg]-Gly 1:6 (4.92 kg−1) TBD-EG 1:4 (12.90 respectively. Besides...

A porous liquid is a unique medium that combines the cavity of solids with fluidity liquids. This special characteristic offers potential in various applications. Here we report type II photoresponsive ionic (PPIL) from dissolving metal-organic polyhedron (PMOP, constructed dicopper and azobenzene-containing carboxylate) polyethylene-glycol-functionalized bulky (IL). Owing to favorable ion interactions, IL molecules encircle outside PMOP, inter cavities are maintained. The azobenzene...

The melting points of ionic liquids (ILs) reported since 2020 were surveyed, collected, and reviewed, which further combined with the previous data to provide a database 3129 ILs ranging from 177.15 645.9 K in points. In addition, factors that affect point macro, micro, thermodynamic perspectives summarized analyzed. Then development quantitative structure-property relationship (QSPR), group contribution method (GCM), conductor-like screening model for realistic solvents (COSMO-RS)...

Viscosity is one of the most important fundamental properties fluids. However, accurate acquisition viscosity for ionic liquids (ILs) remains a critical challenge. In this study, an approach integrating prior physical knowledge into machine learning (ML) model was proposed to predict reliably. The method based on 16 quantum chemical descriptors determined from first principles calculations and used as input ML models represent size, structure, interactions ILs. Three strategies residuals...

The heat capacity of ionic liquids is an important physical property, and experimental measuring usually used as a common method to obtain them. Owing the huge number that can be potentially synthesized, it desirable acquire theoretical predictions. In this work, Conductor-like Screening Model for Real Solvents (COSMO-RS) was predict pure liquids, intensive literature survey conducted providing database verify prediction COSMO-RS. shows available 117 at temperatures ranging 77.66–520 K since...

The CO2 solubilities (including Henry’s constants) and viscosities in ionic liquids (ILs)/deep eutectic solvents (DESs)-based hybrid were comprehensively collected summarized. literature survey results of solubility illustrated that the addition to ILs/DESs can significantly enhance solubility, some ILs-based are super DESs-based solvents. best IL–H2O, IL–organic, IL–amine, DES–H2O, DES–organic [DMAPAH][Formate] (2.5:1) + H2O (20 wt %) (4.61 mol/kg, 298 K, 0.1 MPa), [P4444][Pro] PEG400 (70...

Laparoscopic cholecystectomy (LC) with laparoscopic common bile duct exploration (LCBDE) is convenient in treating cholelithiasis and choledocholithiasis due to its advantage of accelerated recovery. This retrospective study aimed summarize the experience treatment via three-port approach LCBDE Eastern China.Patients diagnosed between July 2019 October 2021 were included. Patients who received LC+LCBDE+primary suturing (CBD) a assigned LCBDE-P group, those LC+LCBDE+T-tube drainage CBD...

To improve the efficiency of electrolyte perturbed-chain statistical associating fluid theory-density functional theory (ePC-SAFT-DFT) calculation confined system, in this work, first, Chebyshev pseudo-spectral collocation method was extended to spherical pores. Second, it combined with Anderson mixing algorithm accelerate iterative process. The results show that can reduce computation time significantly. Finally, based on accelerated ePC-SAFT-DFT program, a systematic study effects...

Developing immobilized-ionic liquids (ILs) sorbents is important for CO2 separation, and prior theoretically screening ILs desirable considering the huge number of ILs. In this study, compressibility was proposed as a new additional index ILs, developed predictive theoretical model, i.e., electrolyte perturbed-chain statistical associating fluid theory, used to predict properties wide variety in temperature pressure range provide systematic data. screening, firstly, isothermal...

Developing novel hybrid ionic liquid/porous material/co-solvent absorbents with the confinement effect is essential for CO2 separation. In this study, solubilities in 1-hexyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide/titanium dioxide/polyethylene glycol ([Hmim][Tf2N]/TiO2-PEG200) different ratios of [Hmim][Tf2N]/TiO2 and various roughnesses TiO2 (P25 T500) were measured described Henry's law. Furthermore, contribution on solubility was quantified, relationship between surface...

Abstract To predict the size ( m , σ ) and energy ε parameters of perturbed‐chain statistical associating fluid theory (PC‐SAFT) based on conductor‐like screening model for realistic solvents (COSMO‐RS), in this work, PC‐SAFT 304 substances were reviewed summarized, their COSMO‐RS results linked to predicted, relationships between obtained 3 cases (Case 1: n ‐alkanes, Case 2: category‐specific relationships, 3: generic 138 substances). 2 (including 1) shows lowest average absolute relative...

Viscosity is one of the most important fundamental properties fluids. However, accurate acquisition viscosity for ionic liquids (ILs) remains a critical challenge. In this study, an approach integrating prior physical knowledge into machine learning(ML) model was proposed to predict reliably. The method based on 16 quantum chemical descriptors determined from first principles calculations and used as input ML models represent size, structure, interactions ILs. Three strategies residuals...

The fluids near the solid substrate display different properties compared to bulk owing asymmetric interaction between fluid and substrate; however, best of our knowledge, no work has been conducted determine interfacial experimentally. In this work, we combined a pycnometer with experimental measurements data processing standard thermodynamic for first time. study, 1-hexyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide ([Hmim][NTf 2 ]) titanium dioxide (P25) were chosen as probes...

Abstract A porous liquid is a unique medium that combines the cavity of solids with fluidity liquids. This special characteristic offers potential in various applications. Here we report type II photoresponsive ionic (PPIL) from dissolving metal‐organic polyhedron (PMOP, constructed dicopper and azobenzene‐containing carboxylate) polyethylene‐glycol‐functionalized bulky (IL). Owing to favorable ion interactions, IL molecules encircle outside PMOP, inter cavities are maintained. The...

Background: Laparoscopic cholecystectomy (LC) with laparoscopic common bile duct exploration (LCBDE) is convenient in treating cholelithiasis and choledocholithiasis due to its advantage of accelerated recovery. This retrospective study aimed summarize the experience treatment via three-port approach LCBDE Eastern China.Methods: Patients diagnosed between July 2019 October 2021 at Xishan People’s Hospital Wuxi City were included this study. During treatment, patients who received...

Abstract Background Laparoscopic cholecystectomy (LC) plus laparoscopic common bile duct exploration (LCBDE) in combination with choledocholithiasis is convenient the treatment of cholelithiasis. It has advantage accelerated recovery. This retrospective study aimed to summarize experience cholelithiasis and via LC LCBDE approach Eastern China. Methods Patients diagnosed between July 2019 October 2021 at Xishan People’s Hospital Wuxi City were included study. During treatment, patients who...

Abstract Porous liquid is a unique medium that combines permanent porosity of porous solid with the fluidity liquid, and this special characteristic makes it potential in various applications. Here we report first photoresponsive ionic (PPIL) by solubilizing metal-organic polyhedron (PMOP, constructed from dicopper azobenzene-containing carboxylate) polyethylene-glycol-functionalized bulky (IL). Owing to favorable ion interactions, IL molecules encircle outside PMOP cages, inter cavities are...

Abstract Background Laparoscopic cholecystectomy (LC) plus laparoscopic common bile duct exploration (LCBDE) is convenient in the treatment of cholelithiasis combination with choledocholithiasis. It has advantage accelerated recovery. This retrospective study aimed to summarize experience and choledocholithiasis via LC LCBDE approach Eastern China. Methods Patients diagnosed between July 2019 October 2021 at Xishan People’s Hospital Wuxi City were included study. During treatment, patients...