A5055131988- Organophosphorus compounds synthesis
- Molten salt chemistry and electrochemical processes
- Organometallic Complex Synthesis and Catalysis
- Synthesis and Reactivity of Sulfur-Containing Compounds
- Biochemical Acid Research Studies
- Metallurgical Processes and Thermodynamics
- Metal complexes synthesis and properties
- N-Heterocyclic Carbenes in Organic and Inorganic Chemistry
- Chemical Reaction Mechanisms
- Extraction and Separation Processes
- Crystal structures of chemical compounds
- Carbohydrate Chemistry and Synthesis
- Synthetic Organic Chemistry Methods
- Advancements in Semiconductor Devices and Circuit Design
- Nuclear Materials and Properties
- Asymmetric Hydrogenation and Catalysis
- Semiconductor materials and devices
- Hydrogen embrittlement and corrosion behaviors in metals
- Nuclear materials and radiation effects
- Advancements in Battery Materials
- Carbon dioxide utilization in catalysis
- Fluorine in Organic Chemistry
- Synthesis and Reactions of Organic Compounds
- Biochemical and Molecular Research
- Corrosion Behavior and Inhibition
Yunnan University
2025
Chinese Academy of Sciences
2015-2024
Shanghai Institute of Applied Physics
2015-2024
University of Chinese Academy of Sciences
2015-2024
North University of China
2024
Capital Medical University
2017-2023
Beijing Anzhen Hospital
2017-2023
Central China Normal University
2012-2022
Xiamen University
2020-2021
Collaborative Innovation Center of Chemistry for Energy Materials
2021
A series of iron(II) (7a−11a) and cobalt(II) (7b−11b) 2-(1-methyl-2-benzimidazolyl)-6-(1-(arylimino)ethyl)pyridyl complexes were synthesized, as well bidentate ligated by 2-(2-benzimidazolyl)-6-methylpyridine, 2-(carboethoxyl)-6-(2-benzimidazolyl)pyridine, 2-(1-methyl-2-benzimidazolyl)-6-acetylpyridine. All organic compounds fully characterized NMR IR spectroscopy elemental analysis, while the metal carefully examined analysis. Their molecular structures determined single-crystal X-ray...
A series of nickel complexes ligated by 2-(2-benzimidazole)-6-methylpyridine, 2-(1-methyl-2-benzimidazole)-6-acetylpyridine, and 2-(1-methyl-2-benzimidazole)-6-(1-aryliminoethyl)pyridine was synthesized examined IR spectroscopic elemental analysis. Their molecular structures were determined single-crystal X-ray diffraction On activation with diethylaluminum chloride (Et2AlCl), all the exhibited good catalytic activities for ethylene oligomerization, nickel(II) bearing...
Abstract A series of 2‐(benzimidazol‐2‐yl)‐1,10‐phenanthrolines and their nickel(II) complexes were synthesized characterized by elemental spectroscopic analysis along with single‐crystal X‐ray crystallography. diffraction revealed that 1a 6a have a six‐coordinate distorted octahedral geometry due to the coordination solvent molecules, whereas 3a is centrosymmetric dimer in solid state 5b displays five‐coordinate trigonal‐bipyramidal geometry. Upon activation diethylaluminum chloride (Et 2...
On the basis of previous work for optimization O,O-diethyl α-(substituted phenoxyacetoxy)alkylphosphonates, further extensive synthetic modifications were made to substituents in alkylphosphonate and phenoxy moieties title compounds. New O,O-dimethyl phenoxyacetoxy)alkylphosphonates synthesized as potential inhibitors pyruvate dehydorogenase complex (PDHc). Their herbicidal activity efficacy vitro against PDHc examined. Some these compounds exhibited significant demonstrated be effective...
A series of (8-(benzoimidazol-2-yl)quinoline)dichlorocobalt(II) complexes was prepared and characterized, single-crystal X-ray diffraction revealed the distorted-tetrahedral geometry around cobalt atom. Activated with methylaluminoxane (MAO), these cobaltous showed special properties ethylene reactivity: oligomerization an observed activity up to 3 × 104 g (mol Co)−1 h–1 atm–1 reaction temperature lower than 60 °C at ambient or 10 atm pressure polymerization 1 105 higher 30 pressure,...
ABSTRACT A novel, halogen‐free, phosphorus–nitrogen containing flame retardant 2[4‐(2,4,6‐Tris{4‐[(5,5‐dimethyl‐2‐oxo‐2λ 5 ‐[1,3,2]dioxaphosphinan‐2‐yl)hydroxymethyl]phenoxy}‐(1,3,5)‐triazine (TNTP) was successfully synthesized in a three‐step process, and characterized by FTIR, NMR spectroscopy, mass spectra, elemental analysis. series of modified DGEBA epoxy resin with different loadings TNTP were prepared cured 4,4‐diaminodiphenylsulfone (DDS). Thermal gravimetric analysis vertical...
The electrochemical behavior of Eu(III)/Eu(II) ( C Eu total = 2.34 × 10 −5 mol g −1 ) in LiF-BeF 2 (FLiBe) molten salt is studied by cyclic voltammetry (CV), square wave (SWV), chrono potentiometry (CP) and linear polarization (LP) the temperature range 773 to 973 K. coexistence Eu(III) Eu(II) ratio are determined SWV test. redox reaction couple on an inert tungsten electrode demonstrated be a quasi-reversible process with diffusion controlled mass transfer. coefficient activation energy...
This work proved the stable valence state of Cr in molten FLINAK is Cr(<sc>iii</sc>) determined by CV and SWV. The conversion Cr(<sc>ii</sc>) to should be attributed formation more species [CrF<sub>6</sub>]<sup>3−</sup> identified Raman spectroscopy.
Class II fructose-1,6-bisphosphate aldolases (FBA-II) are attractive new targets for the discovery of drugs to combat invasive fungal infection, because they absent in animals and higher plants. Although several FBA-II inhibitors have been reported, none these exhibit antifungal effect so far. In this study, novel from C. albicans (Ca-FBA-II) with potent effects were rationally designed by jointly using a specific protocols molecular docking-based virtual screening, accurate...
A series of novel 2,6-dimethyl-4-aminopyrimidine hydrazones 5 were rationally designed and synthesized as pyruvate dehydrogenase complex E1 (PDHc-E1) inhibitors. Compounds strongly inhibited Escherichia coli (E. coli) PDHc-E1 (IC50 values 0.94–15.80 μM). As revealed by molecular docking, site-directed mutagenesis, enzymatic, inhibition kinetic analyses, compounds competitively bound in a "straight" pattern at the E. active site, which is new binding mode. In vitro antifungal assays, most 50...
Molecular docking and three-dimensional quantitative structure−activity relationship (3D-QSAR) studies on the title compounds were performed to explore possible inhibitory mechanism. To determine probable binding conformations of phosphonate derivatives, most potent compound 12 was chosen as a standard template docked into active site PDHc E1. On basis conformations, highly predictive 3D-QSAR models developed with q2 values 0.872 0.873 for comparative molecular field analysis (CoMFA)...
Abstract A catalytic system of new titanium complexes with methylaluminoxane (MAO) was found to effectively polymerize ethylene for high molecular weight polyethylene as well highly active copolymerization and norbornene. The bis (imino‐indolide)titanium dichlorides (L 2 TiCl , 1 – 5 ), were prepared by the reaction N ‐((3‐chloro‐1 H ‐indol‐2‐yl)methylene)benzenamines 4 characterized elemental analysis, 13 C NMR spectroscopy. solid‐state structures determined X‐ray diffraction analysis...
In this paper, an industry-level new-generation EDA solution for reliability-aware design in nanoscale FinFET technology is presented the first time, with new compact transistor aging models and upgraded circuit reliability simulator. Our work solves various issues found silicon data of NBTI aging. Especially, instead ignoring or less accurate recovery effect model traditional simulators, degradation are proposed validated by full stress/recovery range technology. The history effect, one...
Device variability and reliability are becoming increasingly important for nano-CMOS technology circuits, due to the shrinking circuit design margin with downscaling supply voltage (V <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">dd</sub> ). Therefore, robust should have awareness of both reliability. In FinFET technology, strong correlation between variations device electrical parameters is found, larger impacts line-edge roughness (LER) in...
Atherosclerotic cardiovascular disease (ASCAD) is recognized as a chronic subclinical systemic inflammatory condition. The platelet-albumin ratio (PAR) has shown promise in prognosticating various inflammation-related disorders. Our study aimed to assess the connection between PAR and major adverse events (MACE) percutaneous coronary intervention (PCI)-treated patients with non-ST-segment elevation acute syndrome (NSTE-ACS).PAR, derived from platelet albumin counts, categorized participants...