A5101503164- Catalytic C–H Functionalization Methods
- Radical Photochemical Reactions
- Sulfur-Based Synthesis Techniques
- Advanced Photocatalysis Techniques
- Metal-Organic Frameworks: Synthesis and Applications
- Oxidative Organic Chemistry Reactions
- Spinal Cord Injury Research
- Sulfur Compounds in Biology
- Molecular Sensors and Ion Detection
- Neuroinflammation and Neurodegeneration Mechanisms
- RFID technology advancements
- Spinal Dysraphism and Malformations
- Antenna Design and Optimization
- Synthesis and Catalytic Reactions
- Covalent Organic Framework Applications
- Plant Gene Expression Analysis
- Obstructive Sleep Apnea Research
- Organic Chemistry Cycloaddition Reactions
- Advanced Polymer Synthesis and Characterization
- Catalytic Cross-Coupling Reactions
- Mast cells and histamine
- Luminescence and Fluorescent Materials
- Asymmetric Hydrogenation and Catalysis
- Copper-based nanomaterials and applications
- Advanced Nanomaterials in Catalysis
Fuzhou University
2023-2025
Liaoning Shihua University
2024
Third Affiliated Hospital of Southern Medical University
2024
Huaibei Normal University
2019-2024
Hubei University
2024
Xi'an Polytechnic University
2024
Xuzhou Medical College
2024
Wuhan University of Science and Technology
2023
China Telecom
2023
China Telecom (China)
2023
A novel doubly interpenetrated indium-organic framework of 1 has been assembled by In3+ ions and highly conjugated biquinoline carboxylate-based bitopic connectors (H2L). The isolated exhibits an anionic possessing channel-type apertures repleted with exposed quinoline N atoms carboxyl O atoms. Owing to the unique architecture, displays a durable photoluminescence effect fluorescence quenching sensing toward CrO42–, Cr2O72–, Cu2+ reliable selectivity anti-interference properties, fairly high...
A visible-light-induced radical relay cyclization/C-C bond formation of quinoxalin-2(1
GSH is one of the most important reducing agents in biological systems. The depletion human body linked to many diseases. Therefore, it necessary develop suitable and efficient probes for detecting concentrations real samples. In this work, we designed synthesized two near-infrared emitting iridium(III) complex containing a novel ligand functionalized with an α,β-unsaturated ketone rapid sensitive detection GSH. molecular structure Ir2 was determined by X-ray crystallography. Due their large...
Crops must efficiently allocate their limited energy resources to survival, growth and reproduction, including balancing defense. Thus, investigating the underlying molecular mechanism of crop under stress is crucial for breeding. Chloroplasts immunity an important facet involving in plant resistance growth, however, whether how modulated by chloroplast influenced epigenetic regulation remains unclear. Here, cotton lysine 2-hydroxyisobutyrylation (Khib) succinylation (Ksuc) modifications are...
Argatroban is a synthetic thrombin inhibitor approved by U.S. Food and Drug Administration for the treatment of thrombosis. However, whether it plays role in repair spinal cord injury unknown. In this study, we established rat model T10 moderate using an NYU Impactor Moder III performed intraperitoneal injection argatroban 3 consecutive days. Our results showed that effectively promoted neurological function recovery after decreased expression activity local injured cord. RNA sequencing...
A direct alkynylation of C(sp 3 )–H bonds adjacent to an oxygen atom ethers under visible light irradiation was developed in the absence external photocatalyst. The reaction and alkynyl bromides underwent smoothly generate corresponding products good yields with excellent functional‐group tolerance. Initial mechanistic experimental results indicated that may involve a free radical pathway.
A poly( tert -butyl acrylate)- b -poly(β-myrcene)- -poly( acrylate) biobased thermoplastic elastomer was prepared by RAFT emulsion polymerization utilizing a precisely devised amphiphilic macro-RAFT agent and can be modified hydrolysis.
An alkylation of α-C(sp 3 )–H at N -aryltetrahydroisoquinolines with alkylboronic acids was developed under visible-light irradiation and metal-free conditions without additional photocatalyst.
Abstract This paper reports a visible‐light‐induced difunctionalization of 2,3‐dihydrofuran with quinoxalin‐2(1 H )‐ones and peroxides for the synthesis 2,3‐disubstituted tetrahydrofurans under mild reaction conditions good yields in most cases. The multicomponent exhibits excellent site‐selectivity carbon‐carbon double bond (exclusive anti ‐addition), functional group tolerance, high diastereoselectivity (d.r. >99 %).
The condensation of anilines and alkenyl ethers has been demonstrated by employing visible-light photoredox catalysis. resulting method enables the synthesis substituted 2-alkylquinolines under mild simple conditions with good substrate scope high yields.
Abstract A new strategy for the preparation of 10,10‐disubsituedphenanthren‐9(10 H )‐ones via a photo‐driven radical addition/cyclization biaryl vinyl ketones with CF 3 SO 2 Na and ArCF CO K has been developed. The reactions can proceed smoothly in air at room temperature under 380–385 nm LED irradiation without any external photocatalyst, corresponding products were obtained 55–89% yields.
Abstract A transition-metal-free visible-light photoredox-catalyzed decarboxylative alkylation of the benzylic C(sp3)–H bonds N-aryltetrahydroisoquinolines is reported. The method tolerates various functional groups and proceeds smoothly without requiring a stoichiometric oxidant. preliminary mechanistic study indicated that radical process involved in reaction.
A highly selective remote C(sp3)-H acetonation of N-(quinolin-8-yl)amide scaffolds at the C5-position under microwave irradiation has been developed. In absence a transition-metal-catalyst, benzoyl peroxide (BPO)-promoted cross-dehydrogenation coupling (CDC) N-(quinolin-8-yl)amides with acetone/acetonitrile occurred smoothly to generate corresponding 5-acetonated/acetonitriled in good yields. The transformation is operationally simple, rapid, easily scaled-up gram scale, and shows broad...