A5080466913- Carbon dioxide utilization in catalysis
- Ionic liquids properties and applications
- Crystallization and Solubility Studies
- X-ray Diffraction in Crystallography
- CO2 Reduction Techniques and Catalysts
- Phase Equilibria and Thermodynamics
- Covalent Organic Framework Applications
- Aerogels and thermal insulation
- Catalysis for Biomass Conversion
- Metal-Organic Frameworks: Synthesis and Applications
- Radioactive element chemistry and processing
- Microencapsulation and Drying Processes
- Chemical and Physical Properties in Aqueous Solutions
- Analytical Chemistry and Chromatography
- Electrochemical sensors and biosensors
- Thyroid Disorders and Treatments
- Zeolite Catalysis and Synthesis
- Molecular Sensors and Ion Detection
- Advanced Photocatalysis Techniques
- Organometallic Complex Synthesis and Catalysis
- Aerosol Filtration and Electrostatic Precipitation
- Neuropeptides and Animal Physiology
- Polymer Foaming and Composites
- Advanced Cellulose Research Studies
- Silicone and Siloxane Chemistry
Universidade Nova de Lisboa
2013-2024
Rede de Química e Tecnologia
2015-2024
University of Lisbon
2015-2024
Universidad de Valladolid
2021
Hovione (Portugal)
2016
Faculdade de Tecnologia e Ciências
2015
Instituto de Biologia Experimental e Tecnológica
2013
Five Covalent Organic Frameworks (COFs) were synthesized and applied to Dye-Sensitized Solar Cells (DSSCs) as dyes additives. These porous nanomaterials are based on cheap, abundant commercially available ionic (thionin acetate RIO-43, Bismarck brown Y RIO-55 pararosaniline hydrochloride RIO-70), antibiotics (dapsone RIO-60) used building blocks. The reticular innovative organic framework RIO-60 is the most promising dye for DSSCs. It possesses a short-circuit current density (Jsc) of 1.00...
This study reports a novel family of cage manganesesilsesquioxanes prepared via complexation with bathophenanthroline (4,7-diphenyl-1,10-phenanthroline). The resulting Mn4-, Mn6Li2-, and Mn4Na-compounds exhibit several unprecedented metallasilsesquioxane structural features, including intriguing self-assembly silsesquioxane ligands. Complexes were tested in vitro for fungicidal activity against seven classes phytopathogenic fungi. representative Mn4Na-complex acts as catalyst the...
Locust bean gum (LBG) is a natural polymer that belongs to the increasingly attractive biodegradable mesoporous matrices prepared from ionic liquids and scCO<sub>2</sub>sustainable method.
Three new zinc(II) complexes [Zn(H2L3)2(H2O)3] (Zn2), [Zn(H3L2a)(H2O)3]n (Zn3) (H3L2a = 2,4-diiodo-5-(2-(2,4,6-trioxotetrahydropyrimidin-5(2H)-ylidene)hydrazineyl)isophthalate) and [Zn(HL4)(DMF)(H2O)]n (Zn4) were synthesized by the reaction of Zn(II) salts with 5-(2-(2,4-dioxopentan-3-ylidene)hydrazineyl) isophthalic acid (H3L3), 2,4,6-triiodo-5-(2-(2,4,6-trioxotetrahydropyrimidin-5(2H)-ylidene)hydrazineyl) (H5L2) (in presence NH2OH·HCl)...
In this work, the ionic liquid [Aliquat][Cl] was supported into alginate and silica aerogel matrices applied as a catalyst in cycloaddition reaction between CO2 bio-based epoxide (limonene oxide). The efficiency of system is much higher than that one. method wet impregnation used for with zinc complex. procedure originated well-defined thin solvent film on surface support materials. Final materials were characterised by Fourier Transform Infrared Spectroscopy, N2 Adsorption–Desorption...
Thyroid diseases affect a considerable portion of the population, with hypothyroidism being one most commonly reported thyroid diseases. Levothyroxine (T4) is clinically used to treat and suppress stimulating hormone secretion in other In this work, an attempt improve T4 solubility made through synthesis ionic liquids (ILs) based on drug. context, [Na][T4] was combined choline [Ch]+ 1-(2-hydroxyethyl)-3-methylimidazolium [C2OHMiM] + cations order prepare desired T4-ILs. All compounds were...
Ionic Covalent Organic Frameworks are a special subgroup that has risen as promising materials for innovative applications. In parallel, some of the so-called Reticular Innovative compounds (RIOs), which ionic and non-ionic porous have been used with great versatility, several purposes. this work, dye-based RIO-55 was chosen to capture series lanthanides (Eu, Gd, Dy, Tb) from water, observing their affinity lattice performance adsorbent. Thus, higher adsorbed amount referred Eu
Selective water (by-product) separation from reaction mixtures stands as an important process intensification strategy for equilibrium-limited reactions. In this work, the possibility of using a high-pressure biphasic media composed hydrophobic ionic liquid, 1-hexy-3-methylimidazolium tetracyanoborate, and carbon dioxide was explored levulinic acid production 1,4-butanediol. Vapour-liquid equilibrium measurements were performed binary (diol+CO2), ternary (diol+CO2+IL), quaternary systems...
first_page settings Order Article Reprints Font Type: Arial Georgia Verdana Size: Aa Line Spacing: Column Width: Background: Open AccessAbstract Ionic and Aerogel Levothyroxine Formulations with Improved Bioavailability Properties † by António Barreira *, Ana B. Paninho, Luís C. Branco Márcia G. Ventura LAQV-REQUIMTE, Chemistry Department, Nova School of Science Technology, NOVA University Lisbon, Quinta da Torre, 2829-516 Caparica, Portugal * Author to whom correspondence should be...
Accurate measurement and prediction of the phase behaviour mixtures involved in a chemical process are crucial for its optimisation. Given importance CO2 conversion technologies considering possible benefits CO2-ionic liquid biphasic systems, i.e., facilitating product separation, we investigated high-pressure components interest recently developed cyclic carbonate synthesis directly from potentially bio-based alcohols. The solubility 1,2-butanediol 1,2-butylene dense carbon dioxide was...
Ionic Covalent Organic Frameworks are a special subgroup that has risen as promising materials for innovative applications. In parallel, some of the so-called Reticular Innovative compounds (RIOs), which ionic and non-ionic porous have been used with great versatility, several purposes. this work, dye-based RIO-55 was chosen to capture series lanthanides (Eu, Gd, Dy, Tb) from water, observing their affinity lattice performance adsorbent. Thus, higher adsorbed amount referred Eu3+ (Qmax= 370...