A5100721477- Advanced Photocatalysis Techniques
- Metal-Organic Frameworks: Synthesis and Applications
- Advancements in Battery Materials
- Advanced Battery Materials and Technologies
- Advanced battery technologies research
- Covalent Organic Framework Applications
- Supercapacitor Materials and Fabrication
- Gas Sensing Nanomaterials and Sensors
- Advanced Sensor and Energy Harvesting Materials
- X-ray Diffraction in Crystallography
- Analytical Chemistry and Chromatography
- Crystallization and Solubility Studies
- Advanced Battery Technologies Research
- Catalytic Processes in Materials Science
- CO2 Reduction Techniques and Catalysts
- Conducting polymers and applications
- Analytical Chemistry and Sensors
- Electrochemical sensors and biosensors
- MXene and MAX Phase Materials
- Copper-based nanomaterials and applications
- Advanced Nanomaterials in Catalysis
- Microfluidic and Capillary Electrophoresis Applications
- 2D Materials and Applications
- Electrocatalysts for Energy Conversion
- Graphene research and applications
Zhejiang Sci-Tech University
2021-2025
Guangxi University of Chinese Medicine
2024-2025
Jinan University
2020-2025
Guangxi University
2025
Fujian Institute of Research on the Structure of Matter
2014-2024
Chinese Academy of Sciences
2015-2024
Technical Institute of Physics and Chemistry
2018-2024
Materials Science & Engineering
2024
China Jiliang University
2024
China Railway Construction Corporation (China)
2024
A bifunctional imidazolium functionalized Zr-based metal–organic framework, (I<sup>−</sup>)Meim-UiO-66, was successfully prepared, which can serve as an efficient heterogeneous catalyst towards the capture and coupling of CO<sub>2</sub> with epoxides.
Direct conversion of methane into methanol and other liquid oxygenates still confronts considerable challenges in activating the first C-H bond inhibiting overoxidation. Here, we report that ZnO loaded with appropriate cocatalysts (Pt, Pd, Au, or Ag) enables direct oxidation to formaldehyde water using only molecular oxygen as oxidant under mild light irradiation at room temperature. Up 250 micromoles ∼95% selectivity is achieved for 2 h over 10 mg 0.1 wt % Au. Experiments isotopically...
Lithium sulfide (Li2S) is a promising cathode material for Li-S batteries with high capacity (theoretically 1166 mAh g(-1)) and can be paired nonlithium-metal anodes to avoid potential safety issues. However, the cycle life of coarse Li2S particles suffers from poor electronic conductivity polysulfide shuttling. Here, we develop flexible slurryless nano-Li2S/reduced graphene oxide paper (nano-Li2S/rGO paper) by simple drop-coating. The Li2S/rGO directly used as free-standing binder-free...
Developing unique single atoms as active sites is vitally important to boosting the efficiency of photocatalytic CO2 reduction, but directly atomizing metal particles and simultaneously adjusting configuration individual remain challenging. Herein, we demonstrate a facile strategy at relatively low temperature (500 °C) access in situ atomization coordination adjustment via thermo-driven gaseous acid. Using this strategy, pyrolytic acid (HCl) from NH4Cl could downsize large into corresponding...
Aqueous energy-storage systems have attracted wide attention due to their advantages such as high security, low cost, and environmental friendliness. However, the specific chemical properties of water induce problems narrow electrochemical stability window, water-electrode interface reactions, dissolution electrode materials intermediate products. Therefore, new low-cost aqueous electrolytes with different chemistry are required. The nature depends largely on its hydroxyl-based hydrogen...
Abstract Titanium (Ti)‐based metal–organic frameworks (MOFs) have attracted intensive attention due to the low toxicity, high earth's crust abundance, and unique photocatalytic properties of Ti elements. Great efforts been devoted synthesis novel architectures their potential applications involving photocatalysis. However, Ti‐MOFs are still very scarce owing challenges in controlling chemistry reaction system. Until now, some significant results achieved, which may shed new insight into...
The photocatalytic conversion of CO2 into C2+ products such as ethylene is a promising path toward the carbon neutral goal but remains big challenge due to high activation barrier for and similar reduction potentials many possible multi-electron-transfer products. Herein, an effective tandem photocatalysis strategy has been developed support by construction synergistic dual sites in rhenium-(I) bipyridine fac-[ReI(bpy)(CO)3Cl] (Re-bpy) copper-porphyrinic triazine framework [PTF(Cu)]. With...
Utilizing porphyrin molecules as the building blocks (ligands) of metal–organic frameworks (MOFs) leads to porphyrinic MOFs (including incorporation functional materials into MOFs), whereas immobilization porous afford porphyrin@MOFs. These two kinds, collectively regarded porphyrin-based (PP-MOFs), are known feature distinct photophysical and electrochemical properties lending towards several applications. This is because PP-MOFs can overcome instability self-quenching issues...
Abstract Developing overall water splitting non‐noble metal electrocatalysts achieving long‐term stability with high activity at industrial‐grade current density remains challenging. Herein, a self‐reconstruction strategy of Co 9 S 8 ‐Ni 3 2 /NCF is employed to fabricate Ni x 3‐x O 4 ‐Ov‐ in which partial replaced by the structure. The reconstructed ‐Ov can enhance adsorbing ability leached from initial phase compared spinel, exceeding 1000‐h oxygen evolution reaction (OER) and 600‐h 1000 mA...
This study prepared (1−x)BaTiO3–xCaTiO3 (x=0.20–1.0) ceramics. Their structural and electric properties were analyzed. High electrostrictive strain of 0.22%, higher by 157% as compared to BaTiO3 ceramic, was obtained near the solubility limit in side composite (x=0.23), which is a diphasic ceramic composed ferroelectric tetragonal Ba0.8Ca0.2TiO3 solid solution normal dielectric orthorhombic Ba0.07Ca0.93TiO3 solution. enhanced electrostriction resulted from coupling large ionic polarization...
A mesoporous cationic Cr-based metal–organic framework (MOF), <bold>FJI-C10</bold>, has been obtained and exhibited excellent performances in chemical fixation of CO<sub>2</sub> into cyclic carbonates under co-catalyst free mild conditions.
A 3D water-stable anionic metal–organic framework [Zn4(hpdia)2]·[NH2(CH3)2]·3DMF·4H2O (FJI-C4) was constructed based on an elaborate phosphorus-containing ligand 5,5′-(hydroxyphosphoryl)diisophthalic acid (H5hpdia). FJI-C4 with narrow one-dimensional (1D) pore channels exhibits high selectivity of C3H8/CH4 and C2H2/CH4. It is the first time for MOF which contains phosphorus selective separation methane from natural gas pyrolysis gas.
Organic dye pollutants become a big headache due to their toxic nature the environment, and it should be one of best solutions if we can separate reuse them. Here, report synthesis characterization microporous anion metal-organic framework (MOF) with Lewis basic sites-rich based on TDPAT (2,4,6-tris(3,5-dicarboxylphenylamino)-1,3,5-triazine) ligand, FJI-C2, which shows high adsorption separation cationic charge-exclusive effect. Compared other MOF materials, FJI-C2 largest amount methylene...
Ultrasmall metal nanoparticles (MNPs) were decorated on soluble porous coordination polymers (PCPs) with high loadings. The solubility of the composite and size MNPs can be controlled by varying ratio precursors to supports. PCPs serve as a platform homogenize heterogeneous catalysts, which exhibited excellent activity recyclability in C–H activation Suzuki reactions. This strategy combines advantages homogeneous catalysis may bring new inspiration catalysis.
PTA@MIL-101(Cr)-NH<sub>2</sub> has been prepared <italic>via</italic> an anion exchange method, and showed high catalytic activity for oxidative desulfurization under mild conditions.