A5022104061- Crystallization and Solubility Studies
- X-ray Diffraction in Crystallography
- Metal-Organic Frameworks: Synthesis and Applications
- Crystal structures of chemical compounds
- Crystallography and molecular interactions
- Metal complexes synthesis and properties
- Magnetism in coordination complexes
- Nonlinear Optical Materials Research
- Polyoxometalates: Synthesis and Applications
- Lanthanide and Transition Metal Complexes
- Nonlinear Optical Materials Studies
- Porphyrin and Phthalocyanine Chemistry
- Analytical Chemistry and Chromatography
- Perovskite Materials and Applications
- Polymer crystallization and properties
- Molecular Sensors and Ion Detection
- Polymer Nanocomposites and Properties
- Organometallic Compounds Synthesis and Characterization
- Advanced battery technologies research
- Vanadium and Halogenation Chemistry
- Synthesis and Characterization of Heterocyclic Compounds
- Inorganic Fluorides and Related Compounds
- Supercapacitor Materials and Fabrication
- Layered Double Hydroxides Synthesis and Applications
- Chemical Synthesis and Characterization
Kaili University
2025
Henan Institute of Science and Technology
2013-2022
Xinxiang University
2015-2018
Henan Normal University
2015
State Council of the People's Republic of China
2015
National Postdoctoral Association
2015
Beijing Technology and Business University
2015
Jiaozuo University
2013
Fuzhou University
2003-2012
Hebei University of Technology
2009
Two iodoargentate hybrid solids {[Ni(2,2′-bipy)(THF)2(H2O)2](Ag10I12)·2DMF}n (1) and {[Cu(2,2′-bipy)3](Ag5I7)}n (2) (THF=tetrahydrofuran, DMF=N,N′-dimethyl formamide, 2,2′-bipy =2,2′-bipyridine) have been synthesized in a polar organic solvent, whose one-dimensional polymers are induced by second entrapped metal−organic complexes. In 1, the [Ag5I6]nn− chain exhibits columnar structure based on an Ag5I6 quasi-pentagram building block. 2, zigzag [Ag5I7]n2n− is constructed from Ag6I11 compounds...
Abstract In this study, we present the synthesis and characterization of three transition metal 1,5-naphthalenedisulfonates: [Ni(PTP)₂]·(1,5-NDS)·2H₂O ( 1 ), [Mn(PTP)(1,5-NDS)] 2 [Zn(PTP)(1,5-NDS)(H₂O)] ·2.5H₂O 3 ). Herein, PTP refers to 4′-phenyl-2,2′:6′,2″-terpyridine while 1,5-NDS denotes naphthalene-1,5-disulfonate dianion. Compound exhibits a structure in which sulfonate groups 1,5-naphthalenedisulfonate anions are not engaged coordination. compound , Mn(II) ions interconnected through...
Four novel supramolecular frameworks constructed by complex cation [Ag(INA)2]+ (INA = isonicotinamide) and 1,5-naphthalenedisulfonate (1,5-NDS, compound 1), 2,6-naphthalenedisulfonate(2,6-NDS, 2), biphenyldisulfonate (BPDS, 3) 4,4′-biphenyletherdisulfonate (PEDS, 4) anions were synthesized characterized X-ray single crystal diffraction, elemental analyses IR spectra. The building blocks extended into well-ordered complementary hydrogen bonds weak Ag–O interaction with the sulfonate group....
We extend our efforts to investigate the influence of ligand spacers on iodoargentate hybrids templated by cationic SDAs [structure-directing agents, BPB2+ (1,4-bis(pyridinium)butane), BPO2+ (1,8-bis(pyridinium)octane)] possessing both rigidity and flexibility two [(BPB)(Ag5I7)]n (1), [(BPO)(Ag5I7)]n (2) have been synthesized in polar organic solvents. 1 exhibits a 3-D network with cations trapped (Ag5I7)n2− cavities 2 contains one-dimensional infinite polymeric anions accompanied discrete...
Abstract Two new polymeric iodoargentate hybrids induced by rare earth metal complexes and conjugated organic cations, {[Er(DMF) 8 ][Ag 6 I 9 ]} n ( 1 ) [(MMP)(AgI 2 )] (MMP = 1‐methyl‐4‐methylpyridinium) were obtained the routine synthetic reaction structurally determined. In compound , a (Ag 3 – chain is defined edge‐sharing Ag 12 units, in 4 2– chains are constructed AgI tetrahedra. C–H ··· hydrogen bonds between cations polyanions contribute to their structural extension from 1D 2D layer...
We reported two Cd(<sc>ii</sc>) coordination polymers with trinodal (3, 4, 5) and dinodal (4, connected network topologies. Two compounds exhibit very strong NLO absorption in thin films solution.
Four coordination polymers with different structures are reported. They exhibit third-order nonlinear optical activities.
The design of nonlinear optical (NLO) materials with large NLO responses has been a challenge for scientists and chemists. Recently, organic polymers have received attention regarding their properties fast response, clusters involving delocalized dπ-pπ systems conjugated are expected to be new class materials. Metal-organic coordination combine the advantages inorganic species. Thus far, tuning third-order these significant challenge. A two-dimensional polymer, namely...
In the title compound, {[Cu(C15H11ClN2O3)(C4H9NO)]n, Cu(II) cation has square-pyramidal geometry. The morpholine ligand serves as a bridge to link two symmetry-related metal atoms, resulting in an infinite chain structure along axis. Adjacent chains are extended into two-dimensional layered via hydrogen bonds formed between and amide N atoms [N-H···N = 2.971 (3) Å].
A mononuclear VIV complex, (C4H12N2)[VO(C2O4)2(H2O)]·1.5H2O, with bis(oxalate) ligands, has been synthesized under hydrothermal conditions. The structure contains aquabis(oxalato)oxovanadium(IV) complex anions, [VO(C2O4)2(H2O)]2−, and diprotonated piperazine cations, [C4N2H12]2+. ions are connected through hydrogen bonds to form a three-dimensional network micropores, where uncoordinated water molecules located the some degree of disorder. V center distorted octahedral geometry one...