A5103225576- Crystallization and Solubility Studies
- X-ray Diffraction in Crystallography
- Organometallic Complex Synthesis and Catalysis
- Crystallography and molecular interactions
- Synthetic Organic Chemistry Methods
- N-Heterocyclic Carbenes in Organic and Inorganic Chemistry
- Coordination Chemistry and Organometallics
- Inorganic Chemistry and Materials
- Radioactive element chemistry and processing
- Synthesis and Properties of Aromatic Compounds
- Lanthanide and Transition Metal Complexes
- Catalytic Cross-Coupling Reactions
- Catalytic Processes in Materials Science
- Magnetism in coordination complexes
- Fluorine in Organic Chemistry
- Advanced NMR Techniques and Applications
- Fullerene Chemistry and Applications
- Advanced Chemical Physics Studies
- Synthesis and characterization of novel inorganic/organometallic compounds
Berry College
2018-2022
University of Tennessee at Knoxville
2015-2018
Knoxville College
2018
Hepta-coordinated Group 4 amidinate complexes have been synthesized and characterized by <sup>15</sup>N chemical shifts through <sup>1</sup>H–<sup>15</sup>N gHMBC NMR.
A series of Ni(ii), Pd(ii) and Pt(ii) complexes [ML][PF6]2 [L = L1, M Ni (1), Pd (2), Pt (3); L L2, (4), (5), (6)] [Pt(L2)(acac)] (7) have been prepared by the reactions two tetradentate macrocyclic amine-NHC ligand precursors, [H2L1][PF6]2 [H2L2][PF6]2, with Ni(OAc)2·4H2O, Pd(OAc)2 Pt(acac)2 in presence NaOAc. Complex 7 is isolated along 6 from same reaction between [H2L2][PF6]2 Pt(acac)2. There are atropisomers 1-3 achiral conformers 4-6. The crystal structures one conformer 4-6 (4a-6a)...