A5101536426- Asymmetric Hydrogenation and Catalysis
- Nanomaterials for catalytic reactions
- Carbon dioxide utilization in catalysis
- Ionic liquids properties and applications
- Chemical Synthesis and Reactions
- CO2 Reduction Techniques and Catalysts
- Chemical Synthesis and Analysis
- Dyeing and Modifying Textile Fibers
- Innovative Microfluidic and Catalytic Techniques Innovation
- Metal-Organic Frameworks: Synthesis and Applications
- biodegradable polymer synthesis and properties
- Covalent Organic Framework Applications
- Extraction and Separation Processes
- Dye analysis and toxicity
- Catalysis for Biomass Conversion
- Multicomponent Synthesis of Heterocycles
- Catalytic Processes in Materials Science
- Plant Virus Research Studies
- Skin Protection and Aging
- Recycling and Waste Management Techniques
- Plant Disease Resistance and Genetics
- Fiber-reinforced polymer composites
- Morinda citrifolia extract uses
- Chemistry and Chemical Engineering
- Fungal Plant Pathogen Control
Beijing National Laboratory for Molecular Sciences
2021-2025
Chinese Academy of Sciences
2021-2025
Guizhou University
2024
University of Chinese Academy of Sciences
2021-2024
Institute of Chemistry
2021-2024
Shanghai Institute of Organic Chemistry
2022-2023
Jiangnan University
2017-2021
Wuxi Institute of Technology
2019
South China University of Technology
2010
Abstract Four new polystyrene‐supported amino acids have been synthesized and applied to the chemical fixation of carbon dioxide for first time. Two series experiments with threonine (PS‐Thr) tyrosine (PS‐Tyr) as catalyst, respectively, were conducted study effect reaction conditions on carboxylation propylene oxide/carbon dioxide. There was no considerable decrease in yield carbonate after used five times, indicating that these catalysts are very stable. It demonstrated efficient various...
Abstract The chemical transformation of waste polymers into value-added chemicals is significance for circular economy and sustainable development. Herein, we report upcycling poly(succinates) (PSS) with amines N-substituted succinimides over succinimide anion-based ionic liquids (ILs, e.g, 1,8-diazabicyclo[5.4.0]undec-7-ene succinimide, [HDBU][Suc]). Assisted H 2 O, [HDBU][Suc]) showed the best performance, which could achieve complete a series PSS derivatives corresponding diols under mild...
Metal-free, base-free, biomimetic, and chemoselective synthesis of 2,4,6-trisubstituted pyridines was developed for the first time under mild conditions.
Upgrading polyester waste into high value-added chemicals can achieve carbon recycling, which is of great significance for sustainable development. Herein, we report a one-pot protocol to oxidatively degrade polycaprolactone (PCL) with air adipic acid (AA) mediated by ionic liquid (IL, e.g., 1-butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide, [BMIm][NTf2]) in water. In this protocol, IL catalyzes the hydrolysis PCL 6-hydroxyhexanoic (6-HHA) and further mediates oxidation 6-HHA AA...
Abstract Upgrading polyester waste into high value‐added chemicals can achieve carbon recycling, which is of great significance for sustainable development. Herein, we report a one‐pot protocol to oxidatively degrade polycaprolactone (PCL) with air adipic acid (AA) mediated by ionic liquid (IL, e.g., 1‐butyl‐3‐methylimidazolium bis(trifluoromethylsulfonyl)imide, [BMIm][NTf 2 ]) in water. In this protocol, IL catalyzes the hydrolysis PCL 6‐hydroxyhexanoic (6‐HHA) and further mediates...
The pursuit of sustainable practices through the chemical recycling polyamide wastes holds significant potential, particularly in enabling recovery a range nitrogen-containing compounds. Herein, we report novel strategy to upcycle tertiary amines with assistance H
Hydroxyl carboxylate-based ionic liquids can achieve degradation of biopolyesters derived from hydroxyl carboxylic acids into various chemicals under mild and metal-free conditions.
CO 2 mediates ILs to serve as base catalysts for the activation of triple bonds, which achieves hydration nitriles and CC containing compounds carbonyl under metal-free conditions.
Alcohol shifts the equilibrium of CO 2 hydrogenation via forming alkyl formate, which further reacts with amine to produce N -formamide, and Sn(OTf) promotes -formamide -methylamine.
Abstract Highly active catalysts play an important role in modern catalysis. A novel and efficient ligand benzotriazole‐pyrimidine (BTP) the corresponding rhodium composite on C 3 N 4 were successfully synthesized. The resulting was fully characterized by scanning electron microscopy (SEM), transmission (TEM), x‐ray diffraction (XRD), thermogravimetric analysis (TGA), photoelectron spectroscopy (XPS). obtained exhibited good catalytic activity recovery performance synthesis of quinoxaline...
A pyridine and pyrazole-based ruthenium porous organic polymer Ru@Py-POP was synthesized. This catalyst demonstrated broad applicability, high stability good recyclability in the synthesis of C3-alkylated indoles triazine derivatives.
Abstract The pursuit of sustainable practices through the chemical recycling polyamide wastes holds significant potential, particularly in enabling recovery a range nitrogen‐containing compounds. Herein, we report novel strategy to upcycle tertiary amines with assistance H 2 acetic acid under mild conditions (e.g., 180 °C), which is achieved over anatase TiO supported Mo single atoms and Rh nanoparticles. In this protocol, first converted into diacetamide intermediates via acidolysis, are...
Upcycling spent polyesters into useful chemicals is of great significance for achieving a circular carbon economy. Herein, we report the valorization polycaprolactone (PCL) to γ-caprolactone over binary ionic liquid systems derived from 1-butyl-3-methylimidazolium bromide ([BMIm]Br) and CuBr2 under mild conditions (e.g., 160 °C). It was found that in situ formed Lewis acidic [CuBr4]2– anion could activate ester group PCL via coordination with carbonyl O, while [Br]− attack C atom alkyl C–O...
Abstract Dioxolanones and oxazolidinones are prepared by treatment of epoxides or aziridines, respectively, with CO 2 under neat conditions in the presence only 0.6 mol% polymer‐supported threonine tyrosine.