A5102454727- Crystallization and Solubility Studies
- X-ray Diffraction in Crystallography
- Crystallography and molecular interactions
- Polyoxometalates: Synthesis and Applications
- Crystal Structures and Properties
- Metal-Organic Frameworks: Synthesis and Applications
- Asymmetric Synthesis and Catalysis
- Cyclopropane Reaction Mechanisms
- Catalytic C–H Functionalization Methods
- Advanced Antenna and Metasurface Technologies
- Solid-state spectroscopy and crystallography
- Advanced Photocatalysis Techniques
- Inorganic Chemistry and Materials
- Zeolite Catalysis and Synthesis
- Magnetism in coordination complexes
- Electromagnetic wave absorption materials
- Advanced Nanomaterials in Catalysis
- Heusler alloys: electronic and magnetic properties
- Electronic and Structural Properties of Oxides
- ZnO doping and properties
- Advanced Thermoelectric Materials and Devices
- Metamaterials and Metasurfaces Applications
- Synthesis of Indole Derivatives
- Lanthanide and Transition Metal Complexes
- Oxidative Organic Chemistry Reactions
Chongqing Normal University
2012-2024
Yangzhou University
2023-2024
Xi'an Shiyou University
2020
Qingdao University of Technology
2012
State University of New York
1991
We have developed a convenient synthetic protocol for efficient construction of significant dihydrobenzofuran and benzofuran scaffolds by Lewis base-mediated annulation reaction ortho-iminophenols ortho-vinylphenols with MBH carbonates isatins under mild metal-free conditions. The selective generation different kinds derivatives was successfully achieved employing substituted isatin-derived ortho-N-tosyliminophenols ortho-vinylphenols. features included broad substrate scopes, excellent...
The interconnection of [H 3 O⊃(V 2 BP O 12 ) 6 ] 17− clusters and unsaturated [Cd(H O) 2+ or [TM(H 2.5 (H aeae) 0.5 3+ (TM = Mn, Co) complexes leads to new types open-framework vanadium borophosphates with photocatalytic properties.
A straightforward synthetic protocol for the efficient construction of diazepine-containing spiroindolines has been developed and proceeds through a by base-promoted annulation reaction α-halogenated N -acylhydrazones isatin-derived MBH carbonates. The mechanism this formal [4 + 3] includes in situ generated allylic ylide, nucleophilic substitution, Michael additon, elimination processes. Additionally, similar with -tosylhydrazones also afforded -tosyl-substituted...
Two novel lanthanoid thioantimonates [Sm4(tepa)4(μ-η2,η3-Sb3S7)2(μ-Sb2S4)] (1, tepa = tetraethylenepentamine) and [Eu2(tepa)2(μ-SbS3)(μ-OH)]2(SbS4)(OH)·H2O (2) were solvothermally synthesized. Compound 1 represents the only example of different types [Sb3S7]5− [Sb2S4]2− anions coexisting in same thioantimonate framework, while 2 displays rare mixed-valent Sb3+/Sb5+ character with Sb3+ a noncondensed pyramid [SbIIIS3]3−. The theoretical band structure luminescence properties have also been...
One novel octasubstituted trisalkoxotetradecavanadate cluster, [V14O18(tri)2(Htri)6(HCOO)2]·2H2O [1; H3tri = tris(hydroxymethyl)aminomethane], was revealed by a hydrothermal method. 1 shows new type of fully reduced incorporating the highest number ligands, that is constructed interconnection two rare trisalkoxoheptavanadate units via O bridges. The magnetic and photocurrent response properties were investigated.
Abstract The crystal structures of the new compounds (III), (IV), and (V) are determined by single XRD.
Two new 1-D lanthanide selenidogermanates [Ln2(tepa)2(μ-OH)2(μ-Ge2Se6)]n·xnH2O (Ln = Tb (1), x 0.5; Ln Tm (2), 0; tepa tetraethylenepentamine) have been solvothermally synthesized and structurally characterized. Compounds 1 2 contain polymeric chains [Ln2(tepa)2(μ-OH)2(μ-Ge2Se6)]n constructed by a [Ge2Se6]4− anion as bridging ligand with trans terminal Se atoms linking [Ln2(μ-OH)2(tepa)2]4+ complex cations, but the stacking patterns of these neutral are different. The alternately stacked in...
Based on the first-principles calculation and quasi-harmonic Debye model, electronic thermodynamic properties of CuCl 2 -type PbSe compound a promising thermoelectric (TE) material are studied. According to analysis density states (DOS) Mulliken electron population, it is found that possesses weak metallic characterization, where covalent bonding exists in ionic between Pb Se atoms. Besides, temperature decreases with increasing at certain pressures, shows tendency under elevated pressure...