A5088502431- X-ray Diffraction in Crystallography
- Crystallization and Solubility Studies
- Crystal Structures and Properties
- Metal-Organic Frameworks: Synthesis and Applications
- Polyoxometalates: Synthesis and Applications
- Magnetism in coordination complexes
- Organometallic Compounds Synthesis and Characterization
- Inorganic Chemistry and Materials
- Crystallography and molecular interactions
- Lanthanide and Transition Metal Complexes
- Crystal structures of chemical compounds
- Solid-state spectroscopy and crystallography
- Nanocluster Synthesis and Applications
- Metal complexes synthesis and properties
- Perovskite Materials and Applications
- Vanadium and Halogenation Chemistry
- Molecular Sensors and Ion Detection
- Chalcogenide Semiconductor Thin Films
- Iron-based superconductors research
- 2D Materials and Applications
- Electrocatalysts for Energy Conversion
- Multiferroics and related materials
- Ferroelectric and Piezoelectric Materials
- Advanced Photocatalysis Techniques
- Luminescence and Fluorescent Materials
Chongqing Normal University
2016-2025
Chinese Academy of Sciences
2009-2025
University of Chinese Academy of Sciences
2022-2025
Qingdao Institute of Bioenergy and Bioprocess Technology
2025
Nanjing Tech University
2024
Xi'an Jiaotong University
2022-2024
Fudan University
2011-2024
Anhui University of Technology
2023-2024
Beihang University
2024
Qingdao University
2024
Abstract A series of open‐framework aluminoborates (ABOs) [M(dien) 2 ][AlB 6 O 11 (OH)] (M=Co ( I a ), Ni b Cd c Zn d ); dien=diethylenetriamine) and [M(en) 3 7 12 (OH) ] ⋅ (H O) 0.25 II en=ethylenediamine) have been made under hydrothermal conditions characterized by elemental analysis, IR spectroscopy, thermogravimetric UV/Vis fluorescence powder X‐ray diffraction, single‐crystal nonlinear optical determination. These compounds were classified as two structural types: Type – ) contains AlO...
Two new tetra-CdII-substituted vanadogermanate frameworks {(CdX)4Ge8VIV10O46(H2O)[VIII(H2O)2]4(GeO2)4}·8H2O (X = ethylenediamine (en, 1) and 1,2-diaminopropane (dap, 2)) were hydrothermally prepared characterized by IR spectra, elemental analysis, powder X-ray diffraction (PXRD), energy-dispersive spectroscopy (EDX), photoelectron (XPS), thermogravimetric analysis (TGA), single-crystal diffraction. Both are isomorphic, their 3-D made up of {(CdX)4Ge8VIV10O46(H2O)}12– fundamental building...
A new oxidative C–O bond cleavage reaction-based probe FluHMPP was designed and prepared. displays excellent selective turn-on fluorescence response for CuII in aqueous solution under visible light excitation. The products are fully characterized. Fluorescein fragment is further oxidized to highly fluorescent MFME (3′-O-methylfluorescein methyl ester), benzyl ether of imine has been transformed carboxyl. Confocal microscopy experiments have demonstrated that could also be used live cells the...
A hierarchical heterostructure of NiFe-LDH/Ni/NiCo 2 S 4 nanowire grown on NF exhibits a superiority in the water-splitting reaction with low cell voltage 1.53 eV, which evidently exceeds standard Pt–C/NF//RuO /NF 1.61 V.
The catalytic oxidation of benzene faces challenges in achieving high activity and selectivity. While single-atom catalysts present intriguing potential for this transformation, their practical implementation is hindered by intrinsic limitations the mass-specific activity. In context, few-atom cluster have emerged as an alternative, leveraging well-defined metal ensemble effects that enable precisely tailored active sites enhanced interatomic synergies. Herein, we introduce atomic supported...
Although a number of chalcogenostannates have been obtained by using [M(amine)m]n+ as the structure director, these materials with chiral metal complex ions are usually achiral because they racemic mix cations. A selenidostannate, [Mn(tepa).Sn3Se7]n (1; tepa = tetraethylenepentamine), containing incorporated [Mn(tepa)]2+ units, is reported herein. The unique just like grapevine appended grapes. In same reaction, centrosymmetric compound, [Mn(tepa)]2(mu2-Sn2Se6) (2), in which Sn2Se64- anion...
Three new indium sulfides, [Ni(dien)2]0.5[InS2] (dien = diethylenetriamine) (1), [Ni(dap)3]0.5[InS2] (dap 1,2-diaminopropane) (2), and [Ni(tepa)]2[In4S7(SH)2].H2O (tepa tetraethylenepentamine) (3), have been prepared under solvothermal conditions characterized by single-crystal X-ray diffraction. Compounds 1 2 consist of discrete 1-D {[InS2]-} infinity chains with complex cations as charge-compensating ions, while compound 3 consists a novel anionic chain constructed from arachno-shaped...
Abstract Three novel extended vanadogermanates, {[(en) 2 Cd Ge 8 V 12 O 40 (OH) (H O)][Cd(en) ] } ⋅ 6 H ( 1 ), {[Zn (dap) 3 ][Zn(dap)] 15 48 O)}[Zn(dap) O)] and {[Cd (μ‐dien) (Hdien) O) ]Ge 4 16 42 O)} ; en=ethylenediamine, dap=1,2‐diaminopropane, dien=diethylenetriamine), have been hydrothermally synthesized structurally characterized by elemental analysis, IR spectroscopy, powder XRD, thermogravimetric single‐crystal XRD. Their Ge–V–O cluster anions are derived from the 18 shell replacing...
Multifunctional RhB is applied for the passivation of defects in perovskite films, decreasing defect density, suppressing ionic migration and forming extra interface electric field. The PCE a modified PSC with improved stability increased from 18.79% to 20.70%.
A new route for the synthesis of coordination compounds with dimethyl sulfide ligand is reported; prepared compound a novel 2-D framework 1-D right-handed and left-handed helical structure, which unique in sense that fundamental units are unusual Cu4I4 clusters.
A new layered aluminoborate [Zn(dien)2][{Al(OH)}{B5O9F}] (1, en = diethylenetriamine) with an acentric structure has been yielded under solvothermal conditions. In 1, the AlO3(OH) tetrahedra and B5O9F clusters interconnect to form a layer of [{Al(OH)}{B5O9F}]2− 7-MR helical channels. 1 exhibits weak SHG properties luminescence emission at 450 nm.
A zinc borate Zn(1,3-DAP)[B4O7] (1) was prepared. 1 revealed to be a rare chiral zeolitic framework based on [B4O9] cluster. The combination of cluster and Zn(1,3-DAP)O3 chain produced helical ribbon motif gave rise single-stranded channel.
The different connections of [VO<sub>x</sub>] (<italic>x</italic> = 4, 5, 6) and [AO<sub>x</sub>] (A B, <italic>x</italic> 3, 4; A P, 4) polyhedral units ultimately result in a fascinating variety vanadoborate anionic clusters.
The rare multi-dentate 2,6-pyridinedicarboxylic acid (2,6-PDA) is first applied for passivating the electronic defects in MAPbI 3 film. Consequently, PCE of 2,6-PDA-passivated PSC with good stability increased from 18.14% to 20.57%.
The exploitation of efficient and economical electrocatalysts for hydrogen evolution reaction (HER) is exceeding interest in renewable clean-energy technologies. Herein, the facile solvothermal S chromic acetate ethylenediamine (en) achieved a novel organic hybrid chromium sulfide [Cr4(μ3-S)4(en)4(SH)4]·0.25H2O (1), which offers new type antiferromagnetic cubane-like cluster with σ-donor en ligands. 1 was utilized combination Ni nanoparticles porous foam (NF) to fabricate Ni/1/NF electrode...
Porous ceramics usually requires high mechanical strength and maximized porosity simultaneously, while for conventional particle grading strategy it is highly challenging to meet both demands. To this end, a reverse was developed based on the linear packing model by unusually introducing coarse particles (<em>d</em><sub>50</sub> = 16 μm) into fine 5 matrix. Followed extrusion sintering process, tubular porous SiC ceramic supports with improved were successfully fabricated. Effects of...