A5100381488- Crystal Structures and Properties
- Metal-Organic Frameworks: Synthesis and Applications
- Polyoxometalates: Synthesis and Applications
- Organometallic Compounds Synthesis and Characterization
- Magnetism in coordination complexes
- Inorganic Chemistry and Materials
- Lanthanide and Transition Metal Complexes
- Nanocluster Synthesis and Applications
- Perovskite Materials and Applications
- Chalcogenide Semiconductor Thin Films
- Molecular Sensors and Ion Detection
- Iron-based superconductors research
- Conducting polymers and applications
- Photonic and Optical Devices
- Crystal structures of chemical compounds
- Advanced Fiber Optic Sensors
- Solid-state spectroscopy and crystallography
- Vanadium and Halogenation Chemistry
- Luminescence and Fluorescent Materials
- MXene and MAX Phase Materials
- Photonic Crystal and Fiber Optics
- Organic Light-Emitting Diodes Research
- Infrastructure Resilience and Vulnerability Analysis
- Parasitic infections in humans and animals
- Environmental Changes in China
First Affiliated Hospital of Xinjiang Medical University
2025
Xinjiang Medical University
2025
Chongqing Normal University
2014-2024
Électricité de France (France)
2024
CentraleSupélec
2024
Nantong University
2022-2023
Southwest University
2022
Nanchang University
2022
University of Science and Technology Beijing
2018
Huazhong Agricultural University
2014
Multifunctional RhB is applied for the passivation of defects in perovskite films, decreasing defect density, suppressing ionic migration and forming extra interface electric field. The PCE a modified PSC with improved stability increased from 18.79% to 20.70%.
The different connections of [VO<sub>x</sub>] (<italic>x</italic> = 4, 5, 6) and [AO<sub>x</sub>] (A B, <italic>x</italic> 3, 4; A P, 4) polyhedral units ultimately result in a fascinating variety vanadoborate anionic clusters.
The rare multi-dentate 2,6-pyridinedicarboxylic acid (2,6-PDA) is first applied for passivating the electronic defects in MAPbI 3 film. Consequently, PCE of 2,6-PDA-passivated PSC with good stability increased from 18.14% to 20.57%.
The exploitation of efficient and economical electrocatalysts for hydrogen evolution reaction (HER) is exceeding interest in renewable clean-energy technologies. Herein, the facile solvothermal S chromic acetate ethylenediamine (en) achieved a novel organic hybrid chromium sulfide [Cr4(μ3-S)4(en)4(SH)4]·0.25H2O (1), which offers new type antiferromagnetic cubane-like cluster with σ-donor en ligands. 1 was utilized combination Ni nanoparticles porous foam (NF) to fabricate Ni/1/NF electrode...
Three new 3-D polyoxovanadoborates {[Cu(dien)(H2O)]3V12B18O54(OH)6(H2O)}·4H3O·5.5H2O (1, dien = diethylenetriamine), {[Cd(H2O)2]3V12B18O54(OH)6(H2O)}·4H3O·9.5H2O (2) and {[Na(H2O)3]4Na2V12B18O56(OH)4(H2O)}(H3dien)2 (3) have been hydrothermally synthesized structurally characterized. Compounds 1–3 contain vanadoborate cluster [V12B18O60] constructed by two hexameric oxovanadate units [V6O9] one puckered [B18O42] ring via sharing O atoms. The cage can present different degrees of protonation,...
Both optically active 1-tetrazole-4-imidazole-benzene (TIB) with bifunctional azole groups and heterometals were utilized to build a new type of one-dimensional (1-D) hybrid cuprous-lead bromide [PbCu2Br4(TIB)2]n (1), which exhibits infrequent deep-red luminescent emission at 704 nm large Stokes shift 321 nm. Owing the existence rare free Lewis basic imidazole groups, 1 can be used as sole dual-responsive sensor for efficient selective detection Fe3+ Cr2O72- in an aqueous solution.
The exploration of an excellent triple sensor for monitoring Cu2+, Fe3+, and Cr2O72– ions is exceeding significance because their serious effects on the human body. Herein, optically active 1H-3,5-bis(pyrazinyl)-1,2,4-triazole (Hbpt) with triazolyl pyrazinyl groups was applied construction a new type organic hybrid cadmium iodide [Cd6I8(bpt)4(H2O)4]·2H2O (1) incorporating hitherto-unknown [Cd3I4(H2O)2]2+ trimeric-cationic unit, which shows orange light emission at 589 nm large Stokes shift...
A series of new lanthanoid thioarsenates were prepared and they would be helpful for gaining insights into the influence lanthanide contraction on formation other thioarsenates.
Two new 3-D boratopolyoxovanadates {[Zn2NaV12B16O50(OH)8(H2O)7]}·7(H3O)·4H2O (1) and [Cd3Na3.5V12B16O50(OH)8(H2O)8]·2.5(H3O)·11H2O (2) were synthesized employing hydrothermal reactions structurally characterized. Both 1 2 contain the boratopolyoxovanadate cluster [V12B16O50(OH)8]12− built up from one continuous contorted [V12O36] ring two [B8O17(OH)4] clusters. The clusters in both are linked by Zn2+/Cd2+ ions into sql layer self-penetrating layer, respectively, which further connected Na+...
To improve the experimental interest and innovative ability of advanced undergraduate students, a luminescent sensing laboratory experiment with visual performance characteristics is introduced. Students have synthesized an organic hybrid cage-like europium-germanate oxo cluster formula [Eu8(phen)2Ge12(μ3-O)24(CH2CH2COO)12(H2O)16]·2phen·14H2O (Eu8Ge12, phen = 1,10-phenanthroline) by facile solvothermal reaction phen, Eu2O3 bis(carboxyethylgermanium)-sesquioxide in H2O solution at 150 °C...
A series of new lanthanoid thioantimonates [Ln(teta)2]SbS4 [teta = triethylenetetramine; Ln Eu (1), Gd (2), Er (3)], {[Ln(tepa)]2[μ2-SbIIIS3](μ2-OH)}2{[Ln(tepa)]2(μ2-OH)2(SbVS4)2}Cl2 [tepa tetraethylene-pentamine; Y(4), Eu(5), Er(6)], and [Gd2(tepa)2(μ2-OH)2(μ2-SbS4)]Cl·0.25H2O (7) were synthesized via reactions Sb, S LnCl3 in teta or tepa under solvothermal conditions structurally characterized. Compounds 1–3 consist isolated [Ln(teta)4]3+ cations tetrahedral [SbS4]3− anions. 4–6 contain...
Three new thioindate-thioantimonates [Ni(en)(3)][In(2)Sb(2)S(7)] (1, en = ethylenediamine), [(Ni(en)(3))](3)(en)[In(6)Sb(6)S(21)] (2), and [Co(tren)InSbS(4)] (3, tren tris(2-aminoethyl)amine) have been solvothermally synthesized structurally characterized. Compound 1 contains dimeric [In(2)S(7)] units built of two tetrahedral [InS(4)] sharing one corner [SbS(3)] trigonal-pyramids, which are interconnected to form a puckered [In(2)Sb(2)S(7)](n)(2n-) layer with 4-, 5- 6-heterorings....
A novel 3-D chiral polyoxovanadate {[Zn(en)2]2V15O36Cl}[Zn(en)2(H2O)]2·3H2O (1, en = ethylenediamine) has been hydrothermally synthesized under spontaneous resolution without any source. The unique architecture of 1 is built up from destroying high symmetry the spherical [V15O36Cl]8− cluster. Magnetic measurements illustrate that antiferromagnetic exchange interactions between metal centers.
Two types of lanthanide selenidostannates(iv) [Ln2(tepa)2(μ-OH)2Sn2Se6] {Ln = Y(), Pr (), Dy Er Tm (); tepa tetraethylenepentamine} and [Ln2(tepa)2(μ2-OH)2Cl2]2[Sn4Se10]·4H2O Y ()} have been synthesized under identical solvothermal conditions characterized structurally. Type I (, , ) displays 1-D neutral chains [Ln2(tepa)2(μ-OH)2Sn2Se6]n, while type II contains discrete adamantane-like [Sn4Se10](4-) ions with binuclear complex [Ln2(tepa)2(μ-OH)2Cl2](2+) as counterions. Although the synthetic...
A series of new 3-D boratopolyoxovanadates {K2V12B18O54(OH)6(H2O)[K8(H2O)16]}·3H2O (1), {K10V12B18O54(OH)6(H2O)}·14H2O (2), {V12B18O54(OH)6(H2O)[K6(H2O)12]}·2(H2dien)·3H2O (3, dien = diethylenetriamine), {V6B20O44(OH)8(H2O)[K8(H2O)6]} (4), and {V6B20O44(OH)8(H2O)[K(H2O)]2}·2(H3dien)·6H2O (5) have been hydrothermally synthesized structurally characterized. These compounds contain five types [KxOy]n building units, namely, a dimeric [K2O16] unit for 5, 1-D [K3O12]n chain 3, [K5O10]n...
Three new lanthanoid thioarsenates [Eu(en)3(η2-AsS4)] (1, en = ethylenediamine), [Er(teta)(en)(η2-AsS4)] (2, teta triethylenetetramine) and [La2(tepa)2(μ-η1,η3-AsS3)2] (3, tepa tetraethylenepentamine) have been solvothermally synthesized structurally characterized. In compounds 1and 2, the tetrathioarsenate [AsS4]3− anions act as η2-AsS4 chelating ligands to lanthanide complexes [Eu(en)3]3+/[Er(teta)(en)]3+, leading neutral molecules [Eu(en)3(η2-AsS4)]/[Er(teta)(en)(η2-AsS4)], whereas...
A novel 3-D chiral organic-inorganic hybrid zinc vanadate, [Zn2(μ-en)V2O7]n (1, en = ethylenediamine), which is assembled from rare 1-D [(ZnO3)(μ-en)(ZnO4)]n helical chains and dimeric [V2O7] units, has been hydrothermally synthesized. The theoretical band structure optical properties have also studied.
Integration of the photoactive Pb 2+ ion into cuprous iodide framework gives a new type luminescent heterometallic as promising dual material.