A5022266882- Transportation Planning and Optimization
- Traffic control and management
- Traffic Prediction and Management Techniques
- Advanced Photocatalysis Techniques
- Nonlinear Optical Materials Research
- Crystallization and Solubility Studies
- Catalytic Processes in Materials Science
- X-ray Diffraction in Crystallography
- TiO2 Photocatalysis and Solar Cells
- Synthesis and Properties of Aromatic Compounds
- Gas Sensing Nanomaterials and Sensors
- Transportation and Mobility Innovations
- Electrochemical Analysis and Applications
- Particle Dynamics in Fluid Flows
- Catalysis and Oxidation Reactions
- Organoboron and organosilicon chemistry
- Crystallography and molecular interactions
- Electrocatalysts for Energy Conversion
- Radioactive element chemistry and processing
- ZnO doping and properties
- Human Mobility and Location-Based Analysis
- Cyclone Separators and Fluid Dynamics
- Vehicle emissions and performance
- Polyoxometalates: Synthesis and Applications
- Fullerene Chemistry and Applications
Osaka Prefectural Institute of Public Health
2020-2024
Osaka University
1990-2022
Toyon (United States)
2017-2018
Graduate School USA
2017-2018
Kawamura Gakuen Women's University
2017-2018
Fujikura (Japan)
2003-2017
Tohoku University
2014
Kindai University
2001-2012
Tokushima University
1988-2008
Fujikura (United States)
2004-2008
A polymerized ionic liquid electrolyte and platinum-free counter electrode are employed for solid-state DSSCs. We able to prepare a thin polymer layer on nanocrystalline TiO2 in order reduce the cell resistance. In addition, an electron conductive (PEDOT/PSS) or single-wall carbon nanotube gel is used with as inexpensive instead of platinum. The overall photon-to-current conversion efficiency was 3.7% this study.
The impact of intermolecular interactions on the third-order nonlinear optical (NLO) properties open-shell molecular aggregates has been elucidated by considering one-dimensional π-π stacked phenalenyl radicals with different distances and long-range corrected spin-unrestricted density functional theory method. In dimer, which can be considered as a diradicaloid system, diradical character strongly depends distance, larger distance is, becomes. Then, around equilibrium stacking that...
It was investigated that the intrusion of water into electrolyte most critical reason for low stability a dye-sensitized solar cell. To prevent intrusion, robust cells and submodules with novel protection layer metal circuit tightly sealing package developed. The excellent cell ionic liquid at high temperature conditions also reveled. resulting employing noble construction showed an extremely to pass several endurance tests standardized in JIS photovoltaic submodule.
Abstract Bicyclo[1.1.0]tetrasil‐1(3)‐ene 1 , a tetrasilicon analogue of bicyclo[1.1.0]but‐1(3)‐ene that contains formal double bond between bridgehead silicon atoms in an inverted geometry, was synthesized and isolated the form thermally stable orange crystals. The distance Si is much longer than those typical Si=Si bonds, but still shorter previously reported pentasila[1.1.1]propellane. DFT calculations suggest comprises σ with geometry π bond. This notion supported by UV/Vis spectrum which...
Indium tin oxide (ITO) thin films were grown on SiO 2 glass and silicon (Si) substrates from a 95 wt% In O 3 –5 SnO sintered ceramic target by pulsed laser deposition (PLD). The deposited under different oxygen pressures ( P o2 ) of 5×10 -3 to -2 Torr at room temperature (RT) 200°C. was found have critical influence the optical electrical properties ITO films. Under 1×10 Torr, with resistivity as low 4.5×10 -4 1.8×10 Ωcm obtained RT 200°C, respectively. Moreover, increasing substrate T s...
In an investigation into the proton conductivity of crystallized water clusters confined within low-dimensional nanoporous materials, we have found that water-stable crystals are formed by complementary hydrogen bonding between [Co(III) (H2 bim)3 ](3+) bim: 2,2'-biimidazole) and TATC(3-) (1,3,5- tricarboxyl-2,4,6-triazinate); O atoms in -COO(-) groups porous outer wall strongly bonded with H2 O, forming two types WMCs (water molecular clusters): a spirocyclic tetramer chain (SCTC) forms...
The hyperpolarizabilities of three p-quinodimethane derivatives with low diradical character have been evaluated. As electron correlation effects rule the electric field response properties, wave function and density functional theory-based methods compared to benchmark values calculated coupled cluster method including single double excitations as well perturbative estimate triples [CCSD(T)]. basis set further assessed. This study shows that determination second hyperpolarizability CCSD...
Abstract A triaminotriborane(3) was isolated as purple crystals through the reduction of (TMP)BCl 2 (TMP=2,2,6,6‐tetramethylpiperidino) by sodium naphthalenide. Single‐crystal X‐ray diffraction and computational studies obtained revealed a bent structure [B(NR )] 3 chain. The bond lengths between central terminal boron atoms were similar to those observed in neutral diborene species. multiple‐bonding character may be best described three‐center two‐electron π‐bond along B distance two (2.177...
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTA Redox Gel. Electrochemically Controllable Phase Transition and Thermally ElectrochemistryTetsu Tatsuma, Kazutake Takada, Hiroshi Matsui, Noboru OyamaCite this: Macromolecules 1994, 27, 22, 6687–6689Publication Date (Print):October 1, 1994Publication History Published online1 May 2002Published inissue 1 October 1994https://pubs.acs.org/doi/10.1021/ma00100a067https://doi.org/10.1021/ma00100a067research-articleACS PublicationsRequest reuse...
The diradical and ionic natures of open-shell singlet systems have been investigated using new definitions the characters as well their densities within valence configuration interaction (VCI) model with two electrons in active orbitals. two-site symmetric asymmetric models are examined by these diradical/ionic characters. For realistic compounds, we investigate a diradicaloid diphenalenyl rectangular graphene nanoflake presence an external static electric field, π-stacked...
The promising potential of π-radical dithiadiazolyl dimers as a novel class highly-active external-field-driven NLO switches.
Quasi-one-dimensional open-shell singlet ladder oligomers composed of indenofluorene-like units show strong correlation between multiradical nature, aromaticity and second hyperpolarizability.
Low-resistivity (ρ) and highly transparent pure indium oxide (In2O3) thin films grown on glass substrates by pulsed laser deposition at substrate temperature (Ts) between room 200 °C are reported. As-deposited with resistivity of ∼3×10−4 Ω cm transmittance (visible), above 87% were obtained within a narrow range PO2 (1×10−2–1.5×10−2 Torr). Hall effect measurements showed that the low ρ resulted from high carrier concentration (n)∼7×1020 cm−3, whereas modest mobility (μ<45 cm2 V−1 s−1)...