Grigory А. Кim

ORCID: 0000-0001-8814-5180
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About
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Research Areas
  • Crystallization and Solubility Studies
  • X-ray Diffraction in Crystallography
  • Lanthanide and Transition Metal Complexes
  • Magnetism in coordination complexes
  • Synthesis and Characterization of Heterocyclic Compounds
  • Luminescence and Fluorescent Materials
  • Molecular Sensors and Ion Detection
  • Polyoxometalates: Synthesis and Applications
  • Synthesis and Biological Evaluation
  • Chemical Reaction Mechanisms
  • Radical Photochemical Reactions
  • Metal complexes synthesis and properties
  • Quinazolinone synthesis and applications
  • Metal-Organic Frameworks: Synthesis and Applications
  • Nanocluster Synthesis and Applications
  • DNA and Nucleic Acid Chemistry
  • Medical Imaging Techniques and Applications
  • Synthesis and Properties of Aromatic Compounds
  • Transition Metal Oxide Nanomaterials
  • Photochromic and Fluorescence Chemistry
  • Phenothiazines and Benzothiazines Synthesis and Activities
  • Porphyrin and Phthalocyanine Chemistry
  • Synthesis and biological activity
  • Synthesis of Organic Compounds
  • Fullerene Chemistry and Applications

Ural Branch of the Russian Academy of Sciences
2014-2023

Institute of Organic Synthesis
2014-2023

Ural Federal University
2014-2023

Russian Academy of Sciences
2015-2022

Ekaterinburg State Theatre Institute
2016-2018

Pyrene-containing water-soluble probes for the fluorescent detection of nitroaromatic compounds (NACs), such as explosive components (2,4-DNT and 2,4,6-TNT) herbicides (2,4-dinitrocresol, 2,4-DNOC), in aqueous media are reported. In probes, introduction surface-active hydrophilic "heads" at periphery lipophilic (i.e., hydrophobic) pyrene "tails" resulted formation highly micelle-like aggregates/pre-associates solutions concentrations ≤10(-5) m. The enhanced fluorescence quenching herein...

10.1002/asia.201501310 article EN Chemistry - An Asian Journal 2016-01-12

Transparent-to-colored electrochromic devices exhibit promising application prospects and have gained popularity. Herein, two triphenylamine derivatives TPA-OCH3 TPA-CN with styryl moieties different donor or acceptor units were designed synthesized to further prepare solvent-resistant thermally cross-linking polymer P(TPA-OCH3) P(TPA-CN) without any additional initiator. possess pairs of redox peaks, shows a lower onset oxidation potential compared because the pendent unit. Correspondingly,...

10.1021/acsami.1c10089 article EN ACS Applied Materials & Interfaces 2021-08-25

Amino-[1,1']-biphenyl-containing 3-aryl-[1,2,4]triazolo[4,3-c]quinazoline derivatives with fluorescent properties have been designed and synthesized. The type of annelation the triazole ring to pyrimidine one has unambiguously confirmed by means an X-ray diffraction (XRD) method; molecules are non-planar, aryl substituents form pincer-like conformation. UV/Vis photoluminescent target compounds were investigated in two solvents different polarities a solid state. samples emit broad range...

10.3390/molecules28041937 article EN cc-by Molecules 2023-02-17

Novel dyes bearing a 5-(methylidene)barbituric acid moiety as new acceptor/anchor fragment were obtained and exhibited remarkable photophysical properties, according to preliminary assessment of their sensitization activity elements for dye-sensitized solar cells.

10.3998/ark.5550190.p008.686 article EN cc-by ARKIVOC 2014-06-28

The induced aggregation of the xanthene dye rhodamine B (RhB) on metal oxide centers belonging to highly symmetric surfaces precise nanoscale templates with Keplerate (Mo132 ) or toroidal (Mo138 structures has been studied. With joint use Langmuir isotherm and full Stern-Volmer models, thermodynamic reasons for adsorption nanocluster surface, such as a mixture monomer, H-aggregate (H-dimer), J-aggregate forms (which can coexist switch one into another under exact conditions), were...

10.1002/chem.201905781 article EN Chemistry - A European Journal 2020-02-19

Using {Mo 132 } as a nanoscale template, we demonstrate green synthetic strategy for the fabrication of injectable, self-healing hydrogels with pH-controlled release an Eu-fluorescent tag under physiologically relevant conditions.

10.1039/d3nj03041e article EN New Journal of Chemistry 2023-01-01

Abstract New series of highly luminescent DTTA (DTTA=diethylenetriaminetetraacetic acid) ‐ appended water‐soluble lanthanide complexes 4‐(het)aryl‐2,2′‐bipyridines were prepared. By using the Kröhnke method and alkylation reaction sequence, corresponding synthesized in good yields, their Eu(III), Tb(III), Dy(III) Sm(III) Photophysical properties studied for all obtained influence nature (het)aromatic substituent 2,2′‐bipyridine moiety on photoluminescence resulted was investigated. An...

10.1002/slct.201901080 article EN ChemistrySelect 2019-05-31

A series of new fused 5,11-dihydroindolo[3,2-<italic>b</italic>]carbazole derivatives, having nine-ring ladder-type structure, has been synthesized by regioselective Pd-catalyzed cyclization.

10.1039/c6ra11796a article EN RSC Advances 2016-01-01

The latest methods for the preparation/functionalization of azapyrenes, and their photophysical/electrochemical properties possible applications are overviewed.

10.1039/d1nj03531b article EN New Journal of Chemistry 2021-01-01
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