A5028093385- Chemical synthesis and alkaloids
- Chemical Synthesis and Analysis
- Alkaloids: synthesis and pharmacology
- Radical Photochemical Reactions
- Asymmetric Hydrogenation and Catalysis
- Ecology and Vegetation Dynamics Studies
- Catalytic C–H Functionalization Methods
- Organoboron and organosilicon chemistry
- Soil Carbon and Nitrogen Dynamics
- Synthesis and Catalytic Reactions
- Synthesis and Biological Activity
- Crystallization and Solubility Studies
- Catalytic Cross-Coupling Reactions
- Nematode management and characterization studies
- X-ray Diffraction in Crystallography
Instituto de la Grasa
2025
Universitat de Barcelona
2022-2024
Institute of Advanced Chemistry of Catalonia
2021
FC Barcelona
2021
Institut Químic de Sarrià
2021
The QBS-ar, based on the study of microarthropod community structure, is well known as a quick and low-cost indicator to monitor soil biological quality at farm scale. Temperature fluctuations other climate factors in European countries may indirectly influence communities by altering resource availability microhabitat conditions. In context crisis, along with drought erosion threats, especially southern Europe, it essential define limits advantages QBS-ar index. We applied index warm...
This work explores divergent reactivity of the benzylic <italic>gem</italic>-boron–silicon and boron–tin double nucleophiles, including arylation C–B bond with Ar–Cl, along a complementary oxidative λ<sup>3</sup>-iodane-guided C–Si/Sn moiety.
A Diels–Alder reaction leading to 4-nitrophenylcyclohexanones followed by a newly developed base-mediated reductive cyclization of the resulting ketone tethered nitrobenzene moiety gives access hexahydro-2,6-methano-1-benzazocine ring system present in several biologically interesting natural products such as aspernomine. The scope was explored with eight substituted nitrobenzenes, obtaining yields up 87%. highest cytotoxicity observed benzazocine 4h, bearing an enone moiety, which active...
We present a novel strategy for olefin construction via the reductive coupling of electron-neutral alkenes with electron-deficient alkynes under metal-catalyzed hydrogen atom transfer conditions. This methodology provides selective access to both
Abstract Several natural products, bearing an embedded hexahydro‐2,6‐methano‐1‐benzazocine framework (3,4‐benzomorphan) – a heterocyclic regioisomer of the 6,7‐benzomorphan substructure found in morphine alkaloids, have therapeutic potential for variety diseases. Biogenesis, biosynthetic approaches, and total syntheses alkaloids or synthetic azapolycyclic compounds featuring aforementioned azatricyclic ring system ( i. e ., 3,4‐benzomorphan scaffold) are reviewed.