- Crystallization and Solubility Studies
- X-ray Diffraction in Crystallography
- Synthesis and Biological Evaluation
- Phenothiazines and Benzothiazines Synthesis and Activities
- Sulfur-Based Synthesis Techniques
- Fluorine in Organic Chemistry
- Synthesis and biological activity
- Natural Compound Pharmacology Studies
- Chemical Reaction Mechanisms
- Synthesis and Catalytic Reactions
- Porphyrin and Phthalocyanine Chemistry
- Cancer therapeutics and mechanisms
- Free Radicals and Antioxidants
- Dendrimers and Hyperbranched Polymers
- Antibiotic Resistance in Bacteria
- Biological Activity of Diterpenoids and Biflavonoids
- Porphyrin Metabolism and Disorders
- Nanoplatforms for cancer theranostics
- Chemical Reactions and Mechanisms
- Structural and Chemical Analysis of Organic and Inorganic Compounds
- Photosynthetic Processes and Mechanisms
- Metal-Organic Frameworks: Synthesis and Applications
- Cyclopropane Reaction Mechanisms
- Photochromic and Fluorescence Chemistry
- Click Chemistry and Applications
Arizona State University
2023
Universidad Nacional de Córdoba
2017-2023
Consejo Nacional de Investigaciones Científicas y Técnicas
2017-2023
University of South Carolina
2023
Photophysics tunability through alteration of framework aperture (metal–organic (MOF) = variable; guest constant) was probed for the first time in comparison with previously explored concepts (MOF constant; variable). In particular, analysis confinement effect on a photophysical response integrated 5-(3-chlorobenzylidene)-2,3-dimethyl-3,5-dihydro-4H-imidazol-4-one (Cl-BI) chromophore allowed us to establish photophysics–aperture relationship. To shed light observed correlation, confined...
Abstract Imidazoline derivatives with different exocyclic substituents were simply prepared from common starting materials. The procedures carried out in an eco‐friendly manner. antioxidant activity of these was explored by experimental assays, such as ABTS .+ and DPPH . scavenging assay, well reducing power assay. structural differences are discussed terms the results. Sulfur analogs showed higher than their oxygenated counterparts. same tendency observed microbiological studies, which...
The growing interest in the chemistry of unsaturated ring-fused 1,3-heterocycles, this particular case 1,3-oxazines, arise part from their versatile pharmacological applications. In present article, evaluation vitro and ex vivo antioxidant activity two cyclohexene-fused oxazines is discussed. was evaluated by trapping ABTS hydroxyl radicals as well inhibition enzyme acetyl-cholinesterase hemolysis erythrocytes 2,2’-Azobis(2-amidinopropane) dihydrochloride (AAPH). results suggest that both...
Static and flash vacuum pyrolysis were used to get insight into the mechanisms of decomposition 3-(2-chloroethyl)imidazolidine-2,4-dione 2,3-dihydroimidazo[2,1-<italic>b</italic>]thiazol-5(6<italic>H</italic>)-one derivatives.
Abstract In this work, we report the regiospecific and stereoselective synthesis of novel pyrrolo thioxoimidazolidinones with promising biological activities due to inherent pharmaceutical properties thioxoimidazolidinone core. The reaction different trans ‐4‐ethoxy‐1,1,1‐trifluorobut‐3‐en‐2‐one (ETFBO) yields bicyclic 1,3‐diaza heterocycles bearing trifluoromethyl (CF 3 ) moiety. Our investigation involved both depth experimental analysis theoretical calculations fathom out mode building...
The major constituent from the hexane extract of seeds P. insignis is GFC (garcinielliptone FC).Doses 25, 50 and 75 mg/kg were aseptically suspended in 0.05% Tween 80 dissolved 0.9% saline (vehicle) orally administered for 30, 90 120 consecutive days to adult Swiss mice.In this work, repeated oral administration, animals both sexes, demonstrates that compound not able induce mortality and/or behavioral changes addition, body weight gain, feed intake disposal excreta altered by administration...
Thermal isomerization reaction pathways through biradical species.