A5032285138- Conducting polymers and applications
- Fuel Cells and Related Materials
- biodegradable polymer synthesis and properties
- Synthesis and properties of polymers
- Advanced Polymer Synthesis and Characterization
- Polymer Nanocomposites and Properties
- Advanced Drug Delivery Systems
- S100 Proteins and Annexins
- Membrane-based Ion Separation Techniques
- Drug Solubulity and Delivery Systems
- Lignin and Wood Chemistry
- Ionic liquids properties and applications
- Antibiotics Pharmacokinetics and Efficacy
- Electrocatalysts for Energy Conversion
- Polymer composites and self-healing
- Chemical Synthesis and Analysis
- Organic Light-Emitting Diodes Research
- Carbon dioxide utilization in catalysis
- Advanced Battery Materials and Technologies
- Orthopaedic implants and arthroplasty
- Medical Imaging Techniques and Applications
- Polymer Science and PVC
- Inorganic and Organometallic Chemistry
- Organic Electronics and Photovoltaics
- Advanced battery technologies research
MedinCell (France)
2021-2024
Institut Charles Gerhardt Montpellier
2008-2017
Université de Montpellier
2009-2017
Centre National de la Recherche Scientifique
2010-2017
Institut de Chimie
2008-2017
École Nationale Supérieure de Chimie de Montpellier
2017
Laboratoire de Chimie des Polymères Organiques
2015
Université de Bordeaux
2015
Institut Polytechnique de Bordeaux
2015
University of Yamanashi
2011
Abstract Six series of novel highly sulfonated polybenzimidazoles (sPBIs) with high molecular weight were prepared by direct polycondensation between 3,3′‐diaminobenzidine and original multisulfonated dinuclear dicarboxylic acids containing bridging ether, sulfone, hexafluoroisopropylidene moieties. All reactions carried out in polyphosphoric acid, which acts as both solvent catalyst. The degree sulfonation was modulated the final products varying proportion to nonsulfonated used synthesis....
This paper presents the in vitro and vivo degradation of BEPO, a marketed situ forming depot technology used for formulation long-acting injectables. BEPO is composed solution blend poly(ethylene glycol)-block-poly(lactic acid) (PEG–PLA) triblock diblock an organic solvent, where therapeutic agent may be dissolved or suspended. Upon contact with aqueous environment, solvent diffuses polymers precipitate, entrapping drug reservoir. Two representative compositions were subjected to 3-month...
Novel ionomers based on polybenzimidazole block sulfonated poly(arylene ether sulfone) show excellent thermal properties. The ionic aggregation of sulfonic acid groups leads to well-developed phase separated morphology and thus high proton conductivity at wide humidity range, up 65 mS cm(-1) 90% relative humidity.
ABSTRACT A series of four π‐conjugated carbazole‐ alt ‐benzothiadiazole copolymers (PCBT) were prepared by Suzuki cross‐coupling reaction between synthesized dibromocarbazoles as electron‐rich subunits and 4,7‐bis(4,4,5,5‐tetramethyl‐1,3,2‐dioxaborolan‐2‐yl)−2,1,3‐benzothiadiazole electron‐deficient subunits. The directly linked through 2,7‐ or 3,6‐ positions the carbazole. In addition, carbazole monomers have been N ‐substituted a branched linear side‐chain. chemical structure their...
A novel sulfonated polybenzimidazole has been prepared by solution copolycondensation of diaminobenzidine, 5-sulfobenzene-1,3-dicarboxylic acid and 4,4'-(hexafluoropropylidene) bis(benzoic acid) in various stoichiometric ratios using polyphosphoric as solvent. The resulting polymers, characterized 1H NMR spectroscopy, are soluble polar aprotic solvents show excellent film-forming characteristics. Mechanically tough flexible films casting. properties the polymer membranes have a function...
A novel type of polybenzimidazole containing cross-linkable phthalidene groups has been functionalized by direct sulfonation for use as a fuel cell membrane via electrophilic substitution using both concentrated and fuming sulfuric acid. This ether-linked presents different types site substitution. broad study the influence reaction conditions shows that degree have clear dependence on nature sulfonating agent, with less activated sites being sulfonated even short times oleum. The identified...
Copolymers of poly(lactic acid) (PLA) and poly(ethylene glycol) (PEG) are widely used in biomedical applications. As inactive ingredients formulations, tracking their degradation byproducts vivo stands as a major challenge but is pivotal endeavor to ensure safety further progress clinical stages. Current bioanalytical methods monitor this lack sensitivity quantification precision. This study introduces cost-effective synthetic route for 13C-labeled PEG–PLA copolymers, combined with...
This article presents the evaluation of diblock and triblock poly(ethylene glycol)-b-poly(1,3-trimethylene carbonate) amphiphilic copolymers (PEG-PTMCs) as excipients for formulation long-acting injectables (LAIs). Copolymers were successfully synthesised through bulk ring-opening polymerisation. The concomitant formation PTMC homopolymer could not be avoided irrespective catalyst amount, but by-product easily removed by gel chromatography. Pure PEG-PTMCs undergo faster erosion in vivo than...
This article describes the utilization of (methoxy)poly(ethylene glycol)-b-poly(1,3-trimethylene carbonate) ((m)PEG–PTMC) diblock and triblock copolymers for formulation in situ forming depot long-acting injectables by solvent exchange. The results shown this manuscript demonstrate that it is possible to achieve long-term drug deliveries from suspension formulations prepared with these copolymers, release durations up several months vitro. different PEG PTMC molecular weights affords...
Abstract not Available.
Abstract not Available.