A5100359871- X-ray Diffraction in Crystallography
- Crystallization and Solubility Studies
- Advancements in Battery Materials
- Metal-Organic Frameworks: Synthesis and Applications
- Advanced Battery Materials and Technologies
- Covalent Organic Framework Applications
- Electrocatalysts for Energy Conversion
- Advanced battery technologies research
- Supercapacitor Materials and Fabrication
- Advanced Battery Technologies Research
- Polyoxometalates: Synthesis and Applications
- MXene and MAX Phase Materials
- Membrane Separation and Gas Transport
- Luminescence and Fluorescent Materials
- Photonic and Optical Devices
- Carbon Dioxide Capture Technologies
- Nanocluster Synthesis and Applications
- Magnetism in coordination complexes
- Advanced Nanomaterials in Catalysis
- Advanced Photocatalysis Techniques
- Extraction and Separation Processes
- 2D Materials and Applications
- Catalytic Processes in Materials Science
- Advanced Polymer Synthesis and Characterization
- Foot and Ankle Surgery
Northeast Normal University
2016-2025
Northwest Normal University
2025
Beijing University of Technology
2024
Marine Design & Research Institute of China
2024
Kunming Medical University
2012-2024
Tianjin University of Technology
2022-2024
Jilin University of Chemical Technology
2023-2024
Liaoning Technical University
2022-2024
Northeast Electric Power University
2022-2024
Yantaishan Hospital
2017-2024
Antimonene (AM) is a recently described two-dimensional (2D) elemental layered material. In this study, novel photonic drug-delivery platform based on 2D PEGylated AM nanosheets (NSs) developed. The platform's multiple advantages include: i) excellent photothermal properties, ii) high drug-loading capacity, iii) spatiotemporally controlled drug release triggered by near-infrared (NIR) light and moderate acidic pH, iv) superior accumulation at tumor sites, v) deep penetration both extrinsic...
A novel zeolite-like metal–organic framework (ZMOF) with sodalite topology, [Zn(HL)]·DMA (IFMC-1, L = 4,5-di(1H-tetrazol-5-yl)-2H-1,2,3-triazole and IFMC Institute of Functional Material Chemistry), was solvothermally synthesized based on an N-rich aromatic ligand without a NH2 group. It exhibits high CO2 uptake selective CO2/N2 adsorption capacity. For the first time, we investigated influence large number uncoordinated nitrogen atoms from rings for in ZMOFs. This result reveals that...
Although ether-based electrolytes have been extensively applied in anode evaluation of batteries, anodic instability arising from solvent oxidability is always a tremendous obstacle to matching with high-voltage cathodes. Herein, by rational design for solvation configuration, the fully coordinated electrolyte strong resistance against oxidation reported, which remains anodically stable Na3 V2 (PO4 )2 O2 F (NVPF) cathode under 4.5 V (versus Na+ /Na) protected an effective interphase. The...
Sodium-ion batteries (SIBs) have great potential for large-scale energy storage. Cellulose is an attractive material sustainable separators, but some key issues still exist affecting its application. Herein, a cellulose-based composite separator (CP@PPC) was prepared by immersion curing of separators (CP) with poly(propylene carbonate) (PPC). With the assistance PPC, CP@PPC able to operate cell stably at high voltages (up 4.95 V). The "pore-hopping" ion transport mechanism in opens up extra...
Abstract Regulating the H‐bond network between H 2 O molecules has been regarded as an effective strategy to reconfigure chemical environment at electrode/electrolyte interface (EEI), but intrinsic relationship hydrogen‐bond (H‐bond) network, solvation structure, and EEI in electrolyte remains unclear. To this end, three additives with same carbon skeleton different hydroxyl functional groups are chosen unlock their triangular relationship. Experimental theoretical calculations demonstrate...
Pretty porous POMs: Ionothermal synthesis was applied to prepare POM-based open frameworks. The structural integrity remains unchanged until 300 °C; most importantly, the bulky tetrabutylammonium cations within their nanosized channels can be replaced by transition-metal ions through a cation-exchange process, and subsequent gas adsorption measurements confirm permanent porosity. Detailed facts of importance specialist readers are published as "Supporting Information". Such documents...
Boron-dipyrromethene (BODIPY) compounds have been used extensively. However, their application in photocatalysis has not well-studied. In this report, iodo-BODIPYs were utilized as visible-light-driven photocatalysts. They demonstrated very high catalytic efficiencies and reaction rates for the photocatalyzed oxidation of thioanisole under visible light.
Abstract In this work, a phosphine‐based covalent organic framework (Phos‐COF‐1) is successfully synthesized and employed as template for the confined growth of broad‐scope nanoparticles (NPs). Ascribed to ordered distribution phosphine coordination sites in well‐defined pores, various stable well‐dispersed ultrafine metal NPs including Pd, Pt, Au, bimetallic PdAuNPs with narrow size distributions are prepared determined by transmission electron microscopy, X‐ray photoelectron spectroscopy,...
In this work, the lightweight and scalable organic macromolecule graphitic carbon nitride (g-C3N4) with enriched polysulfide adsorption sites of pyridinic-N was introduced to achieve effective functionalization separator at molecular level. This simple method overcomes difficulty low doping content as well existence an uncontrolled form nitrogen heteroatom in final product. Besides conventional pyridinic-N-Li bond formed vacancies g-C3N4, C-S interestingly observed between g-C3N4 Li2S, which...
Four new microporous isostructural anionic lanthanide metal–organic frameworks (Ln-MOFs), [(CH3)2NH2]1.5[Ln1.5(TATAT)(H2O)4.5]·x(solvent) {Ln = Tb, Eu, Dy, and Gd; H6TATAT 5,5′,5″-(1,3,5-triazine-2,4,6-triyl)tris(azanediyl)triisophthalate}, were successfully constructed. The Ln-MOFs are three-dimensional (3D) have two sizes of square channels (8.9 × 8.9 Å 4.3 Å) with a Lewis basic nitrogen-decorated pore environment. 3D can be simplified as (4,6)-connected she networks. Because the framework...
Background Immune exclusion (IE) where tumors deter the infiltration of immune cells into tumor microenvironment has emerged as a key mechanism underlying immunotherapy resistance. We recently reported novel role discoidin domain-containing receptor 1 (DDR1) in promoting IE breast cancer and validated its critical using neutralizing rabbit monoclonal antibodies (mAbs) multiple mouse models. Methods To develop DDR1-targeting mAb potential therapeutic, we humanized mAb9 with...
Abstract Polyoxometalates (POMs), as a unique class well‐defined metal‐oxo clusters with excellent multielectron redox properties, have attracted extensive attention in the field of energy storage and conversion, but it is still challenging to achieve their highly uniform stable monodispersed. In this study, for first time, polyoxovanadate (POV) used, (NH 4 ) 2 [V IV 3 V O 10 {NH C(CH O) } ] (tris‐V 6 19 ), nodes successfully obtain 3D covalent polyoxovanadate‐organic framework through green...
Rational control and understanding of isomerism are significance but still remain a great challenge in reticular frameworks, particular, for covalent organic frameworks (COFs) due to the complicated synthesis energy factors. Herein, reaction 3,3′,5,5′-tetra(4-formylphenyl)-2,2′,6,6′-tetramethoxy-1,1′-biphenyl (TFTB) with 3,3′,5,5′-tetrakis(4-aminophenyl)bimesityl (TAPB) under different conditions affords single crystals two 3D COF isomers, namely, USTB-20-dia USTB-20-qtz. Their structures...
2D compounds exfoliated from weakly bonded bulk materials with van der Waals (vdW) interaction are easily accessible. However, the strong internal ionic/covalent bonding of most inorganic crystal frameworks greatly hinders material exfoliation. Herein, we first proposed a radical/strain-synergistic strategy to exfoliate non-vdW interacting pseudo-layered phosphate framework. Specifically, hydroxyl radicals (⋅OH) distort covalent bond irreversibly, meanwhile, H