A5064262743- Carbon dioxide utilization in catalysis
- Metal-Organic Frameworks: Synthesis and Applications
- CO2 Reduction Techniques and Catalysts
- Asymmetric Hydrogenation and Catalysis
- Covalent Organic Framework Applications
- Ionic liquids properties and applications
- Nanomaterials for catalytic reactions
- Advanced Photocatalysis Techniques
- Gas Sensing Nanomaterials and Sensors
- Geotechnical Engineering and Soil Stabilization
- Chemical Synthesis and Reactions
- Analytical Chemistry and Sensors
- Crystallization and Solubility Studies
- Oxidative Organic Chemistry Reactions
- X-ray Diffraction in Crystallography
- Geotechnical Engineering and Soil Mechanics
- Luminescence Properties of Advanced Materials
- Electrocatalysts for Energy Conversion
- Copper-based nanomaterials and applications
- Biofuel production and bioconversion
- Carbon Dioxide Capture Technologies
- Gold and Silver Nanoparticles Synthesis and Applications
- Aerogels and thermal insulation
- Advanced Sensor and Energy Harvesting Materials
- Conducting polymers and applications
Hubei University of Technology
2024
Huazhong Agricultural University
2024
Institute of Process Engineering
2022-2024
Yanshan University
2020-2024
Ji Hua Laboratory
2022-2023
Peking University
2023
Ministry of Agriculture and Rural Affairs
2022
China Agricultural University
2022
Beijing Institute of Technology
2022
Northeastern University
2016-2021
Carbon dioxide, a greenhouse gas mainly from the consumption of fossil fuel, is regarded as an attractive feedstock in view synthetic chemistry. Great efforts have been devoted to developing catalytic processes for converting CO2 into value-added compounds with reduced carbon footprint. Among versatile applications organic synthesis, can serve promising raw material fuel production, especially methanol. 'Coming and returning fuel' appealing objective terms sustainable development associated...
Abstract Substrate‐supported metal–organic frameworks (MOFs) films are desired to realize their potential in practical applications. Herein, a novel substrate‐seeding secondary‐growth strategy is developed prepare composites of uniform MOFs on aerogel walls. Briefly, the organic ligand “pre‐seeded” onto walls, and then small amount metal‐ion solution sprayed prepared aerogel. The diffuses along walls form continuous thin layer, which confines nucleation reaction, promoting formation whole...
Selective oxidation of sulfides was successfully performed by employing oxone (2KHSO5·KHSO4·K2SO4) as oxidant without utilization any catalyst/additive under mild reaction conditions. Notably, the can be controlled chosen solvent. When ethanol used solvent, sulfoxides were obtained in excellent yield; almost exclusively gave sulfone water. Furthermore, this protocol worked well for various to corresponding or sulfones
CO2 in the air can be efficiently captured with simultaneous activation by PEI (polyethyleneimine) to form ammonium carbamate and/or carbonate species. Thus, situ hydrogenation of into energy-storage materials rather than going through desorption conventional CCS (carbon capture and storage) runs better comparison equivalent gaseous CO2, thus validating this potential application CCU utilization) for supplying renewable energy. PEI600 as an effective carbon absorbent study could also assumed...
Metal-organic frameworks (MOFs) are an intriguing class of porous crystalline inorganic-organic hybrid materials. The fabrication oriented, thin film MOFs is expected to open novel avenues traditional applications and serve myriad advanced technologies. Here, a facile spray-assisted miscible liquid-liquid interface (MLLI) synthetic strategy carried out reported under mild condition that utilizes for the rapid controllable large-area free-standing MOF films. methodology can employ various...
Bimetallic organic frameworks (Bi-MOFs) have been recognized as one of the most ideal precursors to construct metal oxide semiconductor (MOS) composites, owing their high surface area, various chemical structures, and easy removal sacrificial MOF scaffolds through calcination. Herein, we synthesized Zn/Ni Bi-MOF for first time via a facile ion exchange postsynthetic strategy, formed three-dimensional framework consisting infinite one-dimensional chains that is unattainable direct...
Precise and real-time detection of hydrogen peroxide (H2O2) is particularly necessary in pharmaceutical, industrial, military applications because the strong oxidability H2O2. Here, an electrocatalytic active film with Au nanoparticles (Au NPs) embedded a metal–organic framework (UiO-66) was situ prepared on surface electrode for H2O2 detection. The size electrochemical activity nanoparticles/UiO-66 could be controlled by manipulating electrodeposition conditions. Since NPs are encapsulated...
Protic onium salts, e.g.pyridium iodide, proved to be highly efficient and recyclable catalysts for the selective synthesis of 5-aryl-2-oxazolidinones under a CO2 atmosphere at room temperature, presumably due aziridine activation assisted by hydrogen bonding on basis 1H NMR in situ FT IR pressure study.
A porous core–shell nanocatalyst hydrazine hydrate water system has been developed for the catalytic transfer hydrogenation of nitroarenes.
A combined experimental and computational study on the imidazolium ionic liquid-promoted conversion of fructose to 5-hydroxymethylfurfural (HMF) was performed. In particular, 1-butyl-3-methyl-imidazolium bromide (BMImBr) found be unexpectedly effective for into HMF without utilizing any other additive or catalyst. Under optimized conditions, nearly 100% with a 95% yield could obtained. addition, BMImBr easily recovered reused over 6 times significant loss activity. This protocol represents...
CO 2 is very attractive as a typical renewable feedstock for manufacturing commodity chemicals, fuel, and materials since it an abundant, nontoxic, nonflammable, easily available C1 resource. The development of greener chemical methodologies replacing the utility hazardous environmentally undesirable phosgene largely relies on ingenious activation incorporation into valuable compounds, which paramount importance from standpoint green chemistry sustainable development. Great efforts have been...
We have developed a rapid and convenient method for fabricating metal-organic framework (MOF) infinite coordination polymer (ICP) nanosheets by spraying the atomized solution of metal ions onto organic ligand solution. Nanosheet formation could be attributed to anisotropic diffusion in solution, which may give rise lateral interface ligands, where crystals tend grow laterally form nanosheets. Three kinds Zn- Cu-based MOF two Co-based ICP been successfully obtained under mild conditions. The...
Macroautophagy (hereafter referred to as autophagy) is an evolutionarily conserved intracellular mechanism for lysosomal degradation of damaged cellular components. The specific nuclear components by the autophagy pathway called nucleophagy. Most studies have focused on autophagic turnover cytoplasmic materials, and little known about role in components.Human MDA-MB-231 MCF-7 breast cancer cell lines were used model systems vitro. Induction nucleophagy DNA leakage was determined western blot...
Developing a simple strategy to fabricate high-performance hydrogen sensors with long-term stability remains quite challenging. Here, we report the H2-sensing performance of Pd-decorated PdO hollow shells (Pd/PdO HSs). In this novel system, catalyst nanoparticles (Pd NPs) and semiconductor support (PdO) are interconvertible, which is different from traditional hydrogen-sensing systems such as Pd/TiO2 Pd/ZnO. This Pd/PdO system exhibits multiple unique properties. First, well-distributed Pd...