A5104669016- Sulfur-Based Synthesis Techniques
- Chemical Synthesis and Reactions
- Synthesis of Indole Derivatives
- Cyberloafing and Workplace Behavior
- Synthesis and Catalytic Reactions
Fuyang Normal University
2024-2025
Abstract This paper presents a green and efficient aqueous‐phase method for the synthesis of thiosulfonates, which has benefits no need catalysts or redox reagents short reaction time, providing with great economic value synthesizing thiosulfonates. Furthermore, 3‐Sulfenylindoles can be easily synthesized using this method, expands potential applications reaction.
A new synthetic method for disulfides and 3-sulfenylchromones is reported. This innovative approach based on the tetrabutylammonium iodide (TBAI)/H 2 SO 4 reduction system using sodium sulfinate as key component, thus eliminating need thiols redox reagents commonly used in traditional methods. Various were obtained moderate to excellent yields through this methodology. Mechanistic studies indicate that thiosulfonates play an important role reaction process.
We have developed a new synthesis method for α-sulfonyl ketoximes from pyridine alkenes, sodium sulfinate, and NaNO 2 in water. This three-component approach allows the one-step formation of C–N C–S bonds under mild conditions.