A5025978406- Metal complexes synthesis and properties
- Crystallization and Solubility Studies
- X-ray Diffraction in Crystallography
- Magnetism in coordination complexes
- Metal-Organic Frameworks: Synthesis and Applications
- Crystal structures of chemical compounds
- Crystallography and molecular interactions
- Lanthanide and Transition Metal Complexes
- Synthesis and Characterization of Heterocyclic Compounds
- Nanocluster Synthesis and Applications
- Molecular Sensors and Ion Detection
- Catalysis and Hydrodesulfurization Studies
- Organometallic Complex Synthesis and Catalysis
- Nanomaterials for catalytic reactions
- Organic Electronics and Photovoltaics
- Covalent Organic Framework Applications
- Catalytic Processes in Materials Science
- Advanced Photocatalysis Techniques
- Conducting polymers and applications
- Polyoxometalates: Synthesis and Applications
- Ferrocene Chemistry and Applications
- Supramolecular Chemistry and Complexes
- Electrocatalysts for Energy Conversion
- Porphyrin and Phthalocyanine Chemistry
- Organometallic Compounds Synthesis and Characterization
Sun Yat-sen University
1997-2025
Zhengzhou University
2015-2024
Henan Provincial People's Hospital
2018-2024
Jilin University
2002-2022
Tufts University
2013-2022
Bridge University
2022
East China Normal University
2013-2021
Soochow University
2021
Nanjing Medical University
2021
Nanjing Traditional Chinese Medicine Hospital
2021
Abstract The self‐organization of the polymer in solar cells based on regioregular poly(3‐hexylthiophene) (RR‐P3HT):[6,6]‐phenyl C 61 ‐butyric acid methyl ester (PCBM) is studied systematically as a function spin‐coating time t s (varied from 20–80 s), which controls solvent annealing , taken by to dry after process. These blend films are characterized photoluminescence spectroscopy, UV‐vis absorption atomic force microscopy, and grazing incidence X‐ray diffraction (GIXRD) measurements....
Gold nanoclusters have become promising radiosensitizers due to their ultrasmall size and robust ability adsorb, scatter, re-emit radiation. However, most of the previously reported gold nanocluster do not a precise atomic structure, causing difficulties in understanding structure-activity relationship. In this study, structurally defined gold-levonorgestrel consisting Au8(C21H27O2)8 (Au8NC) with bright luminescence (58.7% quantum yield) satisfactory biocompatibility was demonstrated as...
All-polymer solar cells (all-PSCs) have drawn growing attention and achieved tremendous progress recently, but their power conversion efficiency (PCE) still lags behind small-molecule-acceptor (SMA)-based PSCs due to the relative difficulty on morphology control of polymer photoactive blends. Here, low-cost PTQ10 is introduced as a second donor (a third component) into PM6:PY-IT blend finely tune energy-level matching microscopic layer. The addition decreases π-π stacking distance, increases...
A copper(I) 3,5-diphenyltriazolate metal-organic framework (CuTz-1) was synthesized and extensively characterized by using a multi-technique approach. The combined results provided solid evidence that CuTz-1 features an unprecedented Cu5 tz6 cluster as the secondary building unit (SBU) with channels approximately 8.3 Å in diameter. This (MOF) material, which is both thermally chemically (basic acidic) stable, exhibited semiconductivity high photocatalytic activity towards degradation of dyes...
The application of membrane-based separation processes for propylene/propane (C3 H6 /C3 H8 ) is extremely promising and attractive as it poised to reduce the high operation cost established low temperature distillation process, but major challenges remain in achieving gas selectivity/permeability long-term membrane stability. Herein, a C3 facilitated transport using trisilver pyrazolate (Ag3 pz3 carrier filler reported, which uniformly dispersed polymer intrinsic microporosity (PIM-1) matrix...
Four novel non-interpenetrating metal–organic co-ordination networks of the CdII–L–NCS− system have been prepared using potentially bridging nicotinic acid derivatives L [nicotinic (HL1), nicotinamide (L2), isonicotinamide (L3), or isonicotinate (L4)]. Their crystal structures were determined by X-ray diffraction. In [Cd(SCN)2(HL1)2]·HL11 each pair cadmium(II) ions is bridged two inversely related μ-NCS−-N,S ligands to form infinite chains with remaining trans positions six-co-ordinated Cd...
The supramolecular architecture of trinuclear gold(I) pyrazolato aggregates is held together by intermolecular aurophilic attractions, sterically governed the substituents on pyrazole rings. A two-dimensional network [Au(mu-pz)]3 complexes, 1 (pz = anion, C3H3N2-), and a large intricate aggregate 16 [Au(mu-4-Me-pz)]3 complexes in 2 have been determined crystallographically. Under UV irradiation at ambient temperature, solid samples luminesce with lambda max 626 631 cm-1, respectively,...
Comprehensive Summary Three three‐dimensional Hofmann‐type metal‐organic frameworks (MOFs) [Fe(bpn){Ag(CN) 2 } ]·Ph S ( 1·Ph , bpn = 1,4‐di(pyridin‐4‐yl)naphthalene, Ph diphenylsulfide), SO diphenylsulfoxide) and diphenylsulfone) were synthesized by employing sulfur‐containing aromatic guests varying in oxidation states. performed a complete four‐step spin crossover (SCO) behavior with the sequence of HS↔~LS 1/3 HS 2/3 ↔~LS 1/2 ↔ ~LS ↔LS, while an incomplete two‐step SCO profile faint at low...
This study aims to analyze the degeneration of paraspinal muscles after minimally invasive transforaminal lumbar interbody fusion (MIS-TLIF) surgery and its correlation with clinical outcome. Retrospective analysis was conducted on data from patients who underwent single-segment MIS-TLIF in our hospital. MRI examinations were performed before operation, at 6 months, 12 months operation evaluate changes volume steatosis psoas major muscle posterior muscles. VAS scores ODI filled out...
The reactions of silver(i) salts with 3,5-diphenyl-1,2,4-triazole result in three-dimensional, porous, cationic metal-organic frameworks based on novel 6-connected, trigonal-prismatic, pentanuclear silver-triazolate clusters, interconnected by linear N-Ag-N linkers; this robust water- and organic-insoluble structure exhibits both nonpolar-solvent adsorption anion-exchange properties.
The interplay of argentophilic and dipolar (π-acid···base) interactions, on one hand, the presence or absence interstitial solvent molecules, other, determines supramolecular organization trinuclear silver-pyrazolato complexes in solid state. crystal structures gold six silver metallacyclic type [MI(μ-pz*)]3, where pz* are substituted pyrazolato anions 3,5-Ph2-pz, 3-Me-5-Ph-pz, 4-Br-3,5-Ph2-pz, 4-Br-3-tBu-pz 3-(o-Cl-C6H4)-pz M = Ag Au, discussed context their organization. Two complexes, for...
UAV (Unmanned Aerial Vehicle) swarms are being utilized to launch military attacks due its technological development. At present, there is a lack of countermeasures against such attacks. In this article, we propose use GPS spoofing deceive the swarm's location sensing system as countermeasure. Based on two open-source tools, ROS and Gazebo, build simulation platform swarm position perception, design experiments system. Experimental results show that UAVs in flight can be maneuvered collide...
Three compounds [4,4′-bipyH2][M(NCS)4] (M = Mn2+, Co2+ or Zn2+; 4,4′-bipy 4,4′-bipyridine) were obtained from the reactions of with M(SCN)2 in acidic solution and their crystal structures determined by single-crystal X-ray diffraction. All crystallise isomorphously chiral orthorhombic space group P21212. The tetrahedral [M(NCS)4]2− anions are inter-connected S⋯S contacts (ca. 3.63 Å) hydrogen bonded diprotonated [4,4′-bipyH2]2+ cations [N⋯S 3.241 Å 1; 3.235 2; 3.239 3] to form...