A5003586101- Crystallization and Solubility Studies
- X-ray Diffraction in Crystallography
- Organoboron and organosilicon chemistry
- Advanced Machining and Optimization Techniques
- Synthesis and characterization of novel inorganic/organometallic compounds
- Organometallic Complex Synthesis and Catalysis
- Catalytic Cross-Coupling Reactions
- Corrosion Behavior and Inhibition
- Advanced Surface Polishing Techniques
- Coordination Chemistry and Organometallics
- Polyoxometalates: Synthesis and Applications
- Advanced Polymer Synthesis and Characterization
- Chemical Synthesis and Analysis
- Synthetic Organic Chemistry Methods
- Polymer composites and self-healing
- Conducting polymers and applications
- Nanofabrication and Lithography Techniques
- Anodic Oxide Films and Nanostructures
- Radical Photochemical Reactions
- Fluorine in Organic Chemistry
- Silicone and Siloxane Chemistry
- Advanced machining processes and optimization
- Advanced MEMS and NEMS Technologies
- Photopolymerization techniques and applications
- Force Microscopy Techniques and Applications
Xiamen University
2005-2024
Université Claude Bernard Lyon 1
2022
Centre National de la Recherche Scientifique
2022
Institut National des Sciences Appliquées de Lyon
2022
University of Waterloo
2011
National University of Singapore
2011
Chongqing University
2011
Abstract A germylene/borane Lewis pair ( 2 ) was prepared from a 1,1‐carboboration of amidinato phenylethynylgermylene 1 by B(C 6 F 5 3 . Compound reacted with i PrNCO and (4‐MeOC H 4 )C(O)Me, respectively, cleavage the C=O double bond. In first instance, O PrNC insert separately into Ge−B bond to yield GeBC O‐heterocycle ‐heterocycle ). second case )(Me)C inserts Ge−N while is incorporated in form Ge‐centered spiroheterocycle The reaction t BuNC give , which has almost same structure as...
Two borylaminoamidinatosilylenes (L)[(1,5-C8H14)B(Ar)N]Si (L = PhC(NtBu)2, Ar 2,6-iPr2C6H3 (1)) and (L)[(1,5-C8H14)B(Ar')N]Si (Ar' 2,4,6-Me3C6H2 (2)) have been prepared utilized to investigate the reaction toward isocyanide. Reactions of 1 with respective CN-2,6-Me2C6H3 CNCy (Cy cyclo-C6H11) produced compounds (L)Si(NAr)C(N-2,6-Me2C6H3)B(1,5-C8H14)(CN-2,6-Me2C6H3) (3) (L)Si(NAr)C(NCy)C(NCy)B(1,5-C8H14)(CNCy) (4). 2 yielded cyclo-(L)SiN(Ar')C(NCy)B(1,5-C8H14)C(NCy) (5)...
Tetrabutylammonium chloride (TBACl) salt alone has not been shown previously to be capable of removing methoxy groups. It is demonstrated here that the use TBACl achieves efficient folding-promoted chemo- and regioselective demethylations, eliminating up two out five methyl groups situated in similar macrocyclic chemical microenvironments.
In recent years, organophotocatalytic polymerizations have received significant interest as they enable metal-free and highly efficient macromolecular syntheses. Herein, we disclose the development of N-arylacridinium salts an effective class photocatalysts that could mediate cationic reversible addition–fragmentation chain transfer (RAFT) polymerization vinyl ethers with visible light regulation. Owing to their high stability matched redox potentials trithiocarbonate agents, are capable...
Electron-transferable oxidants such as B(C6 F5 )3 /nBuLi, /LiB(C6 )4 , /LiHBEt3 Al(C6 /(o-RC6 H4 )AlH2 (R=N(CMe2 CH2 )2 ), /AlEt3 /AlMe3 (CuC6 and Ag2 SO4 respectively were employed for reactions with (L)2 Si2 C4 (SiMe3 (C2 SiMe3 (L=PhC(NtBu)2 1). The stable radical cation [1]+. was formed paired the anions [nBuB(C6 ]- (in 2), [B(C6 3), [HB(C6 4), [EtB(C6 5), {[(C6 Al]2 (μ-F)]- 6), [nBuAl(C6 7), [Cu(C6 8), respectively. dication [1]2+ also generated (9) [MeAl(C6 (10), In addition, neutral...
We developed a technology for three dimensional (3D) electrochemical micromachining. The confined etchant layer technique (CELT) has been applied to achieve effective three-dimensional micromachining on different kinds of metals and semiconductors. This operates the basis indirect process, is low-cost microfabrication arbitrary 3D structures in single step.
A cuproussiloxane is prepared and utilized to catalyze the aerobic C–P coupling of terminal alkynes with H-phosphonates alkynylphosphonates.