- Crystallization and Solubility Studies
- X-ray Diffraction in Crystallography
- Asymmetric Hydrogenation and Catalysis
- Advanced Photocatalysis Techniques
- Advanced Chemical Physics Studies
- Molecular Junctions and Nanostructures
- Protein Structure and Dynamics
- Metalloenzymes and iron-sulfur proteins
- Carbohydrate Chemistry and Synthesis
- Electrocatalysts for Energy Conversion
- Nanomaterials for catalytic reactions
- Organometallic Complex Synthesis and Catalysis
- Catalytic Processes in Materials Science
- Crystallography and molecular interactions
- Quantum Dots Synthesis And Properties
- Catalysis and Oxidation Reactions
- Carbon and Quantum Dots Applications
- Additive Manufacturing and 3D Printing Technologies
- Synthesis and Properties of Aromatic Compounds
- Iron oxide chemistry and applications
- Catalysis for Biomass Conversion
- Advanced oxidation water treatment
- Luminescence and Fluorescent Materials
- Ammonia Synthesis and Nitrogen Reduction
- Chalcogenide Semiconductor Thin Films
Sichuan University of Science and Engineering
2020-2025
The University of Melbourne
2025
Prairie View A&M University
2003-2020
Hebrew University of Jerusalem
2019
University of Science and Technology of China
2019
Uppsala University
2019
University College London
2019
Jiangnan University
2019
Shizuoka University
2019
Iowa State University
2016
ADVERTISEMENT RETURN TO ISSUEPREVCommunicationNEXTA Capable Bridging Ligand for Fe-Only Hydrogenase: Density Functional Calculations of a Low-Energy Route Heterolytic Cleavage and Formation DihydrogenHua-Jun Fan Michael B. HallView Author Information Department Chemistry, Texas A&M University TAMU 3255, College Station, 77843-3255 Cite this: J. Am. Chem. Soc. 2001, 123, 16, 3828–3829Publication Date (Web):March 31, 2001Publication History Received30 November 2000Published online31 March...
We demonstrate molecular control of nanoscale composition, alloying, and morphology (aspect ratio) in CdS-CdSe nanocrystal dots rods by modulating the chemical reactivity phosphine-chalcogenide precursors. Specific precursors studied were sulfides selenides triphenylphosphite (TPP), diphenylpropylphosphine (DPP), tributylphosphine (TBP), trioctylphosphine (TOP), hexaethylphosphorustriamide (HPT). Computational (DFT), NMR ((31)P (77)Se), high-temperature crossover studies unambiguously...
The utilization of biochar, derived from agricultural waste, has garnered attention as a valuable material for enhancing soil properties and serving substitute adsorbent the elimination hazardous heavy metals organic contaminants wastewater. In present investigation, amide-modified biochar was synthesized via low-temperature pyrolysis rice husk harnessed removal Cr(VI) resultant treated with 1-[3-(trimethoxysilyl) propyl] urea to incorporate an amide group. characterized by employing Fourier...
Thermostability is "conditio sine qua non" (a necessity) if organometallic compounds are used in the homogeneous catalysis of endothermic processes such as dehydrogenation alkanes to alkenes and hydrogen (see scheme). This thermostability other requirements for a catalyst fulfilled by anthraphos iridium(III)dihydride complex 1.
Abstract 3D printing (3DP) has brought endless possibilities to the manufacturing industry. Biodegradable high‐polymer materials such as polylactic acid (PLA) and polycaprolactone (PCL) have attracted widespread attention. However, optimize performance, this study prepared six PLA/PCL composite with ratios of 4:6, 5:5, 6:4, by adding Polyethylene Glycol 4000 (PEG 4000) a plasticizer nano silica reinforcing agent. Parameters that can affect quality, including formulation, temperature (150,...
A better understanding of the chemistry molecular precursors is useful in achieving more predictable and reproducible nanocrystal preparations. Recently, an efficient approach was introduced that consists fine-tuning chemical reactivity synthetic used, while keeping all other reaction conditions constant. Using nickel phosphides as a research platform, we have studied how structure family commercially available organophosphite (P(OR)3, R = alkyl or aryl) alter preparation metallic metal...
Palladium(II)‐catalyzed C–H functionalization has attracted considerable attention as a pathway to late‐stage modification of peptides. Herein, we report the Pd‐catalyzed C(sp3)–H arylation peptides directed by an amidoxime ether, which can be easily incorporated into at any amide bond. Site‐ and stereoselective been achieved, including unprecedented example internal residue. Removal ether was achieved generate parent facilitate traceless process.
Over the years, abuse of antibiotics has increased, leading to their presence in environment. Therefore, a sustainable method for detecting these substances is crucial. Researchers have explored biomass-based carbon dots (CDs) detect various contaminants, due low cost, environmental friendliness, and support circular economy. In our study, we reported synthesis CDs using pinecones (PCs) pinebark (PB) through microwave method. We characterized PCCDs PBCDs X-ray diffraction, Raman...
Fluoride-ion batteries (FIBs) exhibit an energy density up to 10 times that of lithium-ion batteries, with improved safety features, making them a promising technology for future storage. However, the...
The solid–liquid solubility of indole-3-acetic acid in pure methanol, ethanol, n-propanol, isopropanol, acetone, n-butanol, acetonitrile, chloroform, ethyl acetate, 1,4-dioxane, N,N-dimethylformamide (DMF), and dimethyl sulfoxide (DMSO) was measured by using a isothermal saturation method. determination temperature range is from 278.15 to 323.15 K. order data high low acetate > DMSO DMF n-butanol acetone isopropanol 1,4-dioxane n-propanol ethanol methanol acetonitrile chloroform. Two...
In this study, the attapulgite (ATP) was modified by Fe and Ce with method of impregnation-roasting, degradation Methylene Blue (MB) in presence ozone investigated. The results showed that rate 80 mg/L MB wastewater could reach about 94%, when flow is 250 mL/min, reaction temperature 35 ℃, catalyst 0.4 g, initial pH solution 7. characterization ATP Fe3+ Ce4+ had been successfully loaded on gravimetric clay. Finally, mechanism speculated, kinetic equation obtained. model fit reliability are good.
Imaging of localized hybridization nucleic acids immobilized on a glass DNA microarray was performed by means generation collection (GC) mode scanning electrochemical microscopy (SECM). Amine-tethered oligodeoxynucleotide probes, spotted the surface, were hybridized with an unmodified target sequence and biotinylated indicator probe via sandwich hybridization. Spots where sequence-specific had occurred modified streptavidin-horseradish-peroxidase-(HRP)-wrapped SiO2 nanoparticles through...
Phosphine chalcogenides are useful reagents in chalcogen atom transfer reactions and nanocrystal syntheses. Understanding the strength electronic structure of these bonds is key to optimizing their use, but a limited number experimental computational studies probe issues. Using density functional theory (DFT), we computationally screen multiple series trisubstituted phosphine chalcogenide molecules with variety phosphorus substituents examine how affect phosphorus–chalcogen bond. DFT...