A5101761906- Crystallization and Solubility Studies
- X-ray Diffraction in Crystallography
- Toxic Organic Pollutants Impact
- Per- and polyfluoroalkyl substances research
- Atmospheric chemistry and aerosols
- Fluorine in Organic Chemistry
- Catalytic Cross-Coupling Reactions
- Catalytic C–H Functionalization Methods
- Cyclopropane Reaction Mechanisms
- Conducting polymers and applications
- Advanced Sensor and Energy Harvesting Materials
- Environmental Quality and Pollution
- Analytical Chemistry and Sensors
- Supercapacitor Materials and Fabrication
- Environmental and Agricultural Sciences
- Gas Sensing Nanomaterials and Sensors
- Anaerobic Digestion and Biogas Production
- Silicon and Solar Cell Technologies
- Chemical Synthesis and Analysis
- Synthesis and Catalytic Reactions
- Microbial bioremediation and biosurfactants
- Perovskite Materials and Applications
- Enhanced Oil Recovery Techniques
- Radical Photochemical Reactions
Chinese Academy of Sciences
2016-2025
Dalian Institute of Chemical Physics
2025
Institute of Soil Science
2020-2023
Shenzhen Institutes of Advanced Technology
2022-2023
Shenzhen Children's Hospital
2022-2023
University of Chinese Academy of Sciences
2017-2022
Shanghai Institute of Organic Chemistry
2016-2022
University of Vermont
2019
As a straightforward strategy for rapidly increasing molecular complexity, dicarbofunctionalization of alkenes has attracted substantial interests organic synthesis, medicine chemistry, and materials science. Nickel‐catalyzed cascade dicarbofunctionalizations have been flourished in this area recently, nickel‐mediated radical pathways particularly offer new opportunities conjunctive cross‐couplings with alkyl coupling partners. Herein, we give comprehensive review nickel‐catalyzed through...
Abstract A nickel‐catalyzed cross‐coupling between (hetero)arylborons and unactivated 1‐bromo‐1,1‐difluoroalkanes has been developed. The use of two ligands (a bidentate bipyridine‐based ligand, 4,4′‐ditBu‐bpy, a monodentate pyridine‐based DMAP) offers highly efficient nickel‐based catalytic system to prepare difluoroalkylated arenes which have important applications in medicinal chemistry.
In spite of the important applications difluoroalkylated molecules in medicinal chemistry, to date, reaction difluoroalkylating reagents with unactivated, aliphatic substrates through a controllable manner remains challenging and has not been reported. Here we describe an efficient nickel-catalyzed cross-coupling unactivated alkylzinc reagen\ts gem-difluoropropargyl bromides. The proceeds under mild conditions high efficiency excellent regiochemical selectivity. Transformations resulting...
Perovskite/perovskite/silicon triple-junction tandem solar cells (TSCs) hold significant potential for achieving higher efficiencies while lowering the levelized cost of electricity. The top subcell utilizing wide-bandgap (WBG) perovskite is crucial improving efficiency TSCs. However, defects caused by poorly crystallized WBG films and suboptimal energy level alignment lead to loss. Herein, we present a multifunctional interface engineering piperazinium bromide (PZBr) enhancing property...
A nickel-catalyzed tandem reaction of <italic>N</italic>-vinylamides with arylboronic acids and bromodifluoroacetate has been developed. The efficiently furnishes a series protected α,α-difluoro-γ-amino acid esters.
Abstract Efficient methods for the dicarbofuntionalization of cyclic alkenes 2‐pyrroline and 2‐azetine are limited. Particularly, dicarbofunctionalization endocyclic enecarbamates to achieve fluorinated compounds remains an unsolved issue. Reported here is a nickel‐catalyzed trans ‐selective N ‐Boc‐2‐pyrroline ‐Boc‐2‐azetine, class previously unexplored transition metal catalyzed dicarbofunctionalization. The reaction can be extended six‐ seven‐membered enamides. A variety arylzinc reagents...
Abstract A nickel‐catalyzed cross‐coupling between (hetero)arylborons and unactivated 1‐bromo‐1,1‐difluoroalkanes has been developed. The use of two ligands (a bidentate bipyridine‐based ligand, 4,4′‐ditBu‐bpy, a monodentate pyridine‐based DMAP) offers highly efficient nickel‐based catalytic system to prepare difluoroalkylated arenes which have important applications in medicinal chemistry.
Owing to the versatile synthetic utility of its carbon-carbon double bond, low-cost industrial chemical 3,3,3-trifluoropropene (TFP) represents one most straightforward and cost-efficient precursors prepare trifluoromethylated compounds. However, only limited methods for efficient transformations TFP have been reported so far. Here, we report a nickel-catalyzed dicarbofunctionalization TFP. The reaction uses inexpensive NiCl
Abstract In the Ni‐catalyzed cross‐coupling between (hetero)arylborons and unactivated bromodifluoroalkanes combination of a bidentate bipyridine‐based ligand, monodentate pyridine‐based ligand provides an efficient catalytic system to prepare difluoroalkylated arenes.