A5100744148- X-ray Diffraction in Crystallography
- Crystal Structures and Properties
- Crystallization and Solubility Studies
- Chemical Synthesis and Characterization
- Metal-Organic Frameworks: Synthesis and Applications
- Perovskite Materials and Applications
- Inorganic Chemistry and Materials
- Solid-state spectroscopy and crystallography
- Zeolite Catalysis and Synthesis
- Polyoxometalates: Synthesis and Applications
- Nanocluster Synthesis and Applications
- Advanced Photocatalysis Techniques
- Analytical Chemistry and Sensors
- Radioactive element chemistry and processing
- TiO2 Photocatalysis and Solar Cells
- Medical Research and Treatments
- Inorganic Fluorides and Related Compounds
- Electrochemical sensors and biosensors
- Nonlinear Optical Materials Research
- Crystallography and molecular interactions
- Magnetism in coordination complexes
- Innovative Microfluidic and Catalytic Techniques Innovation
- Covalent Organic Framework Applications
- Extraction and Separation Processes
- Educational Robotics and Engineering
Qingdao University
2015-2024
Qingdao Women and Children's Hospital
2024
Xuchang University
2021
Harbin Institute of Technology
2015-2016
Harbin University
2015-2016
PHENIX laboratory
2016
Sorbonne Université
2016
Centre National de la Recherche Scientifique
2016
China Academy of Engineering Physics
2016
Hengyang Normal University
2004-2014
Introducing stereochemically active lone-pair Sb3+ cations into sulfates, two three-dimensional (3D) antimony-sulfates, Sb4O5SO4 (1) and Sb4O(SO4)(OH)2 (2), were achieved under moderate hydrothermal conditions. Both structures are constructed by tetranuclear-{Sb4}-clusters-based layers SO4 tetrahedra. However, owing to the different packing patterns of layers, they display characteristics: 1 exhibits a centrosymmetric structure while 2 possesses noncentrosymmetric structure. UV–vis spectra...
Imatinib (IMA) is a common chemotherapy drug for the treatment of leukemia and can potentially lead to resistance toxicity during course treatment. Monitoring IMA concentrations in body fluids necessary optimize therapeutic schedules avoid overdosage. In this paper, novel ultrasensitive electrochemical sensor based on CuMOF SWCNTs@AuNPs was developed determine antileukemic drug. Herein, AuNPs were supported carboxylic single-walled carbon nanotubes (SWCNT-COOH), then...
Three zeolitic pentaborates (H2en)[B5O8(OH)] (1, en = ethylenediamine), (Hen)2[Al(B5O10)] (2), (H2en)[NH(CH3)2][Al(B5O10)] (3) were solvothermally obtained by employing ethanediamine molecules as structure-directing agents (SDAs). The nonmetal borate of 1 features a noncentrosymmetric two-dimensional layered structure. Through introducing Al atoms the linkers and regulating reaction conditions 1, two three-dimensional open-framework aluminoborates, (NCS) 2 centrosymmetric (CS) 3, achieved....
We report herein a 3D interrupted beryllium phosphite open-framework with low density (1.594 g cm<sup>−3</sup>), which is the first case of framework containing extra-large 18-ring channels.
Abstract Luminescent metal clusters have attracted great interest in current research; however, the design synthesis of Al with color‐tunable luminescence remains challenging. Herein, an [Al 8 (OH) (NA) 16 ] ( , HNA = nicotinic acid) molecular cluster dual properties fluorescence and room‐temperature phosphorescence (RTP) is synthesized by choosing ligand as phosphor. Its prompt photoluminescence (PL) spectrum exhibits approximately white light emission at room temperature. Considering that...
Three new open-framework aluminoborates (ABOs), Rb2AlB5O10·4H2O (), [C5N2H16]AlB5O10 (, C5N2H16 = N-ethyl-1,3-diaminopropane) and [H2dap][(CH3)2NH]AlB5O10 dap 1,2-diaminopropane) have been made under solvothermal conditions characterized by elemental analysis, IR, TGA, UV-vis, powder XRD, single-crystal fluorescence spectra NLO determination, respectively. These three ABOs display two structural types: are isostructural crystallize in acentric space groups C2221 P212121 respectively, showing...
This synergism, resulting from the combination of luminescence and DSSCs, opens up way to new multifunctional materials.
Complexes <bold>Zn1</bold> and <bold>Cd1</bold> exhibit tunable luminescence properties they can serve as co-sensitizers to enhance the power-conversion efficiency.
A new alkali-metal antimony(III) sulfate, NaSb3O2(SO4)3·H2O, has been discovered by introducing stereochemical active lone pair (SCALP) Sb3+ cations into sulfates. It exhibits a three-dimensional structure established from unique {Sb6} clusters and SO4 tetrahedra with Na+ ions located on the voids. diffuse reflection spectrum shows that NaSb3O2(SO4)3·H2O possesses an experimental band gap of 3.80 eV. Theoretical calculation was executed to explain structure–property relationships. The result...
An optically anisotropic alkali-earth-metal gallium fluoroiodate, Ba2[GaF5(IO3F)] (1), was ingeniously obtained by integrating fluoride and fluoroiodate functional units under moderate hydrothermal conditions. It features a three-dimensional (3D) structure constructed the highly polarizable unit [IO3F] groups [GaOF5] [BaO3Fx] (x = 6, 7). The compound is stable at temperatures up to 500 °C. With synergistic interaction between groups, mixed-metal induces short ultraviolet cutoff edge about...
This work reports on two new complexes with the general formula [Cd3(IBA)3(Cl)2(HCOO)(H2O)]n (1) and {[Cd1.5(IBA)3(H2O)6]·3.5H2O}n (2), which can be synthesized by reaction of Cd(II) rigid linear ligand 4-HIBA containing imidazolyl carboxylate functional groups [4-HIBA = 4-(1H-imidazol-1-yl)benzoic acid]. Single-crystal X-ray diffraction analyses indicate that complex 1 is a 2D "wave-like" layer structure constructed from trinuclear units 2 just mononuclear structure. Surprisingly, both...
A novel heterometallic cluster, Dy12Na6, has been prepared and characterized. It represents an unprecedented high-nuclearity alkali-metal-Ln cluster with a cage-like shape. In situ generated ligands participated in the formation of cluster. Magnetic measurements suggest that Dy12Na6 shows slow magnetic relaxation at low temperature.
2D → 3D SCSC complexes enhance DSSC conversion.
<italic>In situ</italic> template design and generation strategy is applied to synthesize microporous materials. We report five new organically templated gallium phosphates with different structures varying from 1D chain 2D layer 3D framework.
The reaction system employing titanium alkoxide and hydrofluoric acid under solvothermal conditions has been widely used to prepare anisotropic anatase crystals featuring a large percentage of reactive {001} facets. Nevertheless, such leads the stabilization both fluoride hydroxide‐substituting oxide in network. presence anions is compensated by vacancies. In this work, we demonstrate that synthesis temperature not only impacts morphology as prepared nanoparticles but also their chemical...
A series of haloargentates have been prepared exhibiting a reversible photochromic phenomenon and efficient photocatalytic properties.