A5115602883- Crystallization and Solubility Studies
- X-ray Diffraction in Crystallography
- Luminescence and Fluorescent Materials
- Covalent Organic Framework Applications
- Advancements in Battery Materials
- Advanced Battery Materials and Technologies
- Membrane Separation and Gas Transport
- Membrane Separation Technologies
- Supercapacitor Materials and Fabrication
- Crystallography and molecular interactions
- Metal-Organic Frameworks: Synthesis and Applications
- Molecular Sensors and Ion Detection
- Magnetism in coordination complexes
- Advanced Measurement and Metrology Techniques
- Photochemistry and Electron Transfer Studies
- Carbon and Quantum Dots Applications
- Graphene research and applications
- Advanced Battery Technologies Research
- Optical measurement and interference techniques
- Synthesis and Properties of Aromatic Compounds
- Surface Modification and Superhydrophobicity
- Conducting polymers and applications
- Fatigue and fracture mechanics
- Hydrogen embrittlement and corrosion behaviors in metals
- Inorganic Chemistry and Materials
Jiangnan University
2023-2024
Hunan University
2023-2024
State Key Laboratory of Chemobiosensing and Chemometrics
2023-2024
Southeast University
2024
China Academy of Space Technology
2024
Beihang University
2024
Taiyuan University of Technology
2024
Jiangsu University
2023
Shanxi Normal University
2020-2022
Sichuan University
2021-2022
Room temperature phosphorescence (RTP) has been extensively researched in heavy-metal containing complexes and purely organic systems. Despite the rapid blossom of RTP materials, it is still a tremendous challenge to develop highly efficient blue materials with long-lived lifetimes. Taking metal-organic framework (MOF) as model, herein, feasible strategy ligand functionalization proposed, including two essential elements, high efficiency lifetimes simultaneously under ambient conditions. One...
Abstract Covalent organic framework (COF) membranes featuring uniform topological structures and devisable functions, show huge potential in water purification molecular separation. Nevertheless, the inability of COF to be produced on an industrial scale their nonenvironmentally friendly fabrication method are bottleneck preventing applications. Herein, we report a new green industrially adaptable scraping‐assisted interfacial polymerization (SAIP) technique fabricate scalable TpPa...
Abstract Stimulus‐responsive membranes demonstrate promising applications in switchable oil/water emulsion separations. However, they are unsuitable for the treatment of double emulsions like oil‐in‐water‐in‐oil (O/W/O) and water‐in‐oil‐in‐water (W/O/W) emulsions. For efficient separation these complicated emulsions, fine control over wettability, response time, aperture structure membrane is required. Herein, dual‐coated fibers consisting primary photothermal‐responsive secondary CO 2...
Abstract Dynamic materials undergoing adaptive solid‐state transitions are attractive for soft mechanics and information technology. Here, we report a novel porous framework system based on macrocyclic trimers assembled from open‐shell tetraarylethylene building blocks with aryldicyanomethyl radicals as coupling linkers. Under mechanical, thermal, or chemical stimuli, the showed adaptability by activating conformational dynamics radical‐based transformations, thus displaying macroscopic...
Abstract Membranes are important in the pharmaceutical industry for separation of antibiotics and salts. However, its widespread adoption has been hindered by limited control membrane microstructure (pore architecture free‐volume elements), threshold, scalability, operational stability. In this study, 4,4′,4′′,4′′′‐methanetetrayltetrakis(benzene‐1,2‐diamine) (MTLB) as prepared a molecular building block fabricating thin‐film composite membranes (TFCMs) via interfacial polymerization. The...
Developing accurate and efficient measurement systems for blade profiles has always been a vital issue in manufacturing. Nowadays, optical-based measuring have attracted significant interest due to their high efficiency flexibility. However, as key steps optical of blades, system calibration establishment datum are normally accomplished based on objects, which may introduce uncertainty affect the accuracy measurement. In this article, we propose novel method blade-profile self-features. A...
We report herein an organic charge transfer cocrystal complex, consisting of a stable radical TPVr and electron acceptor TCNQF4, as rare sort all-organic-based magnetic bistable materials with thermally activated hysteresis loop over the temperature range from 170 to 260 K. Detailed X-ray crystallographic studies theoretical calculations revealed that while π-associated anion dimer was formed upon integer process TCNQF4 molecules within lattice, resulting TCNQF4·- π-dimers were found exhibit...
This paper proposes a coordinated control system of autonomous vehicles’ lateral stability based on state estimation and path tracking, which contributes to enhancing path-tracking capability at the same time maintaining vehicles driving in complex dynamic road conditions. First, an extended Kalman filter observer is designed estimate vehicle parameters. Then, single-point preview theory, adaptive model built for accuracy tracking. When designing direct yaw-moment controller, sideslip angle...
[3]Radialene has a peculiar topology and cross-conjugation system, representing unique molecular scaffold in organic materials. Herein, we report special class of stereoisomeric α-cyano triaryl[3]radialenes (CTRs) that show concentration-caused quenching solution but emit red-shifted enhanced luminescence the crystalline state. Clustering multiple cyano groups their through-space interactions with [3]radialene ring significantly extend π-electron communication meanwhile rigidifying propeller...
Abstract The fir‐tree tenon/mortise structure in areo‐engine suffers from the combined high and low cycle fatigue (CCF) loads during service. structural integrity of is significantly affected by local strain distribution, while value under CCF difficult to acquire. In this study, a simulated specimen designed, test carried out using divided‐path loading fixture avoid interference between (HCF) (LCF) loads. speed digital image correlation (DIC) method adopted acquire real‐time distribution...
Abstract The properties of single molecules and molecular aggregates can differ dramatically, leading to a long‐standing interest in mesoscale aggregation processes. Herein, series acid‐base complexes is developed by using tetraphenylethylene‐backboned fluorophore, investigated the photophysical photochemical activities at different length scales. This with two basic diethylamine groups acidic tetrazole groups, exhibits sparse solubility due multivalent interactions that cause infinite...
Luminescent wood materials are an emerging class of biomass hybrid host owing to the hierarchical porous structure and functionalization versatility. The fluorescence properties largely dependent on exogenous fluorophores, which are, however, often plagued by notorious aggregation effects. In this work, efficient strategy for preparation luminescent transparent is developed incorporating tetraphenylethylene-derived aggregation-induced emission (AIE)-active fluorophores during a...
Abstract High‐performance photocatalysis requires efficient light absorption and low charge carrier recombination rates. Herein, a coupling confinement strategy is demonstrated to simultaneously enhance the efficiency suppress for high‐performance photocatalysis. The achieved by delicate incorporation of catalysts into dual‐core‐shell structure (e.g., CdS@SiO 2 @NaYF 4 :Yb/Tm), in which CdS (catalyst), SiO , NaYF :Yb/Tm serve as shell, outer core, inner respectively. Interestingly, absorbed...
Abstract Covalent organic framework (COF) membranes featuring uniform topological structures and devisable functions, show huge potential in water purification molecular separation. Nevertheless, the inability of COF to be produced on an industrial scale their nonenvironmentally friendly fabrication method are bottleneck preventing applications. Herein, we report a new green industrially adaptable scraping‐assisted interfacial polymerization (SAIP) technique fabricate scalable TpPa...
Abstract Dynamic materials undergoing adaptive solid‐state transitions are attractive for soft mechanics and information technology. Here, we report a novel porous framework system based on macrocyclic trimers assembled from open‐shell tetraarylethylene building blocks with aryldicyanomethyl radicals as coupling linkers. Under mechanical, thermal, or chemical stimuli, the showed adaptability by activating conformational dynamics radical‐based transformations, thus displaying macroscopic...
Abstract Porous frameworks that display dynamic responsiveness are of interest in the fields smart materials, information technology, etc. In this work, a novel copper‐based metal‐organic framework [Cu 3 TTBPE 6 (H 2 O) ] 4 = 1,1,2,2‐tetrakis(4″‐(1H‐tetrazol‐5‐yl)‐[1,1″‐biphenyl]‐4‐yl)ethane), denoted as HNU‐1, is reported which exhibits modulable photoelectromagnetic properties. Due to synergetic effect flexible tetraarylethylene‐backboned ligands and diverse copper‐tetrazole coordination...