A5010653917- Metal-Organic Frameworks: Synthesis and Applications
- Extraction and Separation Processes
- Metal-Catalyzed Oxygenation Mechanisms
- X-ray Diffraction in Crystallography
- Advancements in Battery Materials
- Crystallization and Solubility Studies
- Chemical Synthesis and Characterization
- Radioactive element chemistry and processing
- Covalent Organic Framework Applications
- Magnetism in coordination complexes
- Metal complexes synthesis and properties
- Metalloenzymes and iron-sulfur proteins
- Gas Sensing Nanomaterials and Sensors
- Crystallography and molecular interactions
- Pickering emulsions and particle stabilization
- Recycling and Waste Management Techniques
- Enhanced Oil Recovery Techniques
- Sulfur-Based Synthesis Techniques
- Synthesis and Reactivity of Sulfur-Containing Compounds
- Synthesis of heterocyclic compounds
- Advanced Photocatalysis Techniques
- Phosphorus compounds and reactions
- Per- and polyfluoroalkyl substances research
- Lanthanide and Transition Metal Complexes
- Synthesis and Catalytic Reactions
Commissariat à l'Énergie Atomique et aux Énergies Alternatives
2015-2024
CEA Marcoule
2015-2024
École Nationale Supérieure de Chimie de Montpellier
2015-2024
Centre National de la Recherche Scientifique
2015-2024
Institut de Chimie Séparative de Marcoule
2015-2024
Université de Montpellier
2015-2024
Nanyang Technological University
2022
Laboratoire de Chimie et Biologie des Métaux
2010-2015
CEA Grenoble
2011-2015
University of Chicago
2013-2014
Three metal–organic frameworks (MOFs) of the UiO-68 network topology were prepared using amino-TPDC or TPDC bridging ligands containing orthogonal phosphorylurea groups (TPDC is p,p′-terphenyldicarboxylic acid), and investigated for sorption uranium from water artificial seawater. The stable porous phosphorylurea-derived MOFs shown to be highly efficient in sorbing uranyl ions, with saturation capacities as high 217 mg U g−1 which equivalent binding one ion every two sorbent groups....
Abstract Direct recycling is a novel approach to overcoming the drawbacks of conventional lithium‐ion battery (LIB) processes and has gained considerable attention from academic industrial sectors in recent years. The primary objective directly LIBs efficiently recover restore active electrode materials other components solid phase while retaining electrochemical performance. This technology's advantages over traditional pyrometallurgy hydrometallurgy are cost‐effectiveness, energy...
A robust and porous Zr metal–organic framework, sal-MOF, of UiO topology was synthesized using a salicylaldimine (sal)-derived dicarboxylate bridging ligand. Postsynthetic metalation sal-MOF with iron(II) or cobalt(II) chloride followed by treatment NaBEt3H in THF resulted Fe- Co-functionalized MOFs (sal-M-MOF, M = Fe, Co) which are highly active solid catalysts for alkene hydrogenation. Impressively, sal-Fe-MOF displayed very high turnover numbers up to 145000 recycled reused more than 15...
A series of functionalized mesoporous carbon (MC) materials were prepared by covalent grafting with amidoxime, carboxyl, and phosphoryl functional groups screened for uranium (U) sorption from aqueous media. The MC characterized nitrogen adsorption measurements thermogravimetric analysis investigated U(VI) extraction both acidic water (pH 4) artificial seawater 8.2). Under conditions, a phosphoric acid-functionalized exhibited the highest sorption, maximum capacity 97 mg U(VI)/(g sorbent) in...
A hydrophobic metal–organic framework has revealed high and fast sorption capacity for fluorine pollutants.
Two metal-organic frameworks (MOFs) with Zr-oxo secondary building units (SBUs) were prepared by using p,p'-terphenyldicarboxylate (TPDC) bridging ligands pre-functionalized orthogonal succinic acid (MOF-1) and maleic groups (MOF-2). Single-crystal X-ray structure analysis of MOF-1 provides the first direct evidence for eight-connected SBUs in UiO-type MOFs. In contrast, MOF-2 contains twelve-connected as seen traditional UiO MOF topology. These structural assignments confirmed extended...
By exchanging metals in a photoactive MOF, it has been possible to obtain material for the photodegradation of methylene blue.
A simple and efficient method for constructing sulfur heterocycles was developed using a phosphine-catalyzed tandem umpolung addition intramolecular cyclization of bifunctional pronucleophiles on arylpropiolates. The reaction offers promising route to synthetically useful as well biologically active under neutral conditions.
MOF thin films on a conductive support are reviewed with particular focus the growth control and binding strength of films.
Metal-organic frameworks (MOFs) show promise for the capture of greenhouse gases. To be used at a large scale in fixed-bed processes, their shaping under hierarchical structure is mandatory and remains major challenge, while keeping available high specific surface area. For that purpose, we propose herein an original method based on stabilization paraffin-in-water Pickering emulsion by fluorinated Zr MOF (UiO-66(F4)) with polyHIPEs (polymers from internal phase emulsions) strategy consisting...
This paper reports a simple method to recycle plastic-bottle and Li-ion-battery waste in one process by forming valuable coordination polymers (metal–organic frameworks, MOFs). Poly(ethylene terephthalate) from plastic bottles was depolymerized produce an organic ligand source (terephthalate), Li-ion batteries were dissolved as of metals. By mixing both dissolution solutions together, selective precipitation Al-based MOF, known MIL-53 the literature, observed. material can be recovered large...
The heterodinuclear complexes [FeIIIMnII(L-Bn)(μ-OAc)2](ClO4)2 (1) and [FeIIMnII(L-Bn)(μ-OAc)2](ClO4) (2) with the unsymmetrical dinucleating ligand HL-Bn {[2-bis[(2-pyridylmethyl)aminomethyl]]-6-[benzyl-2-(pyridylmethyl)aminomethyl]-4-methylphenol} were synthesized characterized as biologically relevant models of new Fe/Mn class nonheme enzymes. Crystallographic studies have been completed on compound 1 reveal an FeIIIMnIIμ-phenoxobis(μ-carboxylato) core. A single location FeIII ion in FeII...