A5103002888- Crystallization and Solubility Studies
- X-ray Diffraction in Crystallography
- Metal-Organic Frameworks: Synthesis and Applications
- Advanced Photocatalysis Techniques
- Advanced Battery Materials and Technologies
- Crystallography and molecular interactions
- Advanced oxidation water treatment
- Nanocluster Synthesis and Applications
- Advancements in Battery Materials
- Supramolecular Self-Assembly in Materials
- Advanced battery technologies research
- Advanced Nanomaterials in Catalysis
- Quantum Dots Synthesis And Properties
- Sulfur-Based Synthesis Techniques
- Luminescence and Fluorescent Materials
- Nanoplatforms for cancer theranostics
- Environmental remediation with nanomaterials
- Supramolecular Chemistry and Complexes
- Renal Diseases and Glomerulopathies
- Adsorption and biosorption for pollutant removal
- Nanomaterials for catalytic reactions
- Polyoxometalates: Synthesis and Applications
- Treatment of Major Depression
- Synthesis and Properties of Aromatic Compounds
- Catalytic C–H Functionalization Methods
Zhejiang Chinese Medical University
2015-2025
University of Hong Kong
2022-2024
Jinan University
2019-2024
Zhuhai People's Hospital
2024
Wuhan University
2013-2023
University of Shanghai for Science and Technology
2022
Changzhou University
2019-2021
Guangxi University of Science and Technology
2019-2020
Donghua University
2020
Shantou University
2019
Abstract Aqueous rechargeable sodium‐ion batteries have the potential to meet growing demand for grid‐scale electric energy storage because of widespread availability and low cost sodium resources. In this study, we synthesized a Na‐rich copper hexacyanoferrate(II) Na 2 CuFe(CN) 6 as high cathode used NaTi (PO 4 ) 3 Na‐deficient anode assemble an aqueous ion battery. This battery works very well with average discharge voltage 1.4 V, specific 48 Wh kg −1 , excellent high‐rate cycle stability...
Abstract Aqueous Na‐ion batteries have the competitive advantages of being low costing and possessing inherent safety, they are particularly suitable for large‐scale energy‐storage applications. However, development this new battery system is hindered by lack Na hosts with sufficiently high capacity cycle life. Herein, we report vacancy‐free 2 CoFe(CN) 6 nanocubes synthesized a controlled crystallization reaction reveal their use as aqueous cathode reversible Na‐storage behavior. Owing to...
Visible-light copper photocatalysis has recently emerged as a viable technology for building sustainable synthetic processes. To broaden the applications of phosphine-ligated copper(I) complexes, we describe herein an effective metal-organic framework (MOF)-supported photocatalyst multiple iminyl radical-mediated reactions. Due to site isolation, heterogenized photosensitizer significantly higher catalytic activity than its homogeneous counterpart. Using hydroxamic acid linker immobilize...
A Na-host cathode is developed by grafting the polypyrrole chains with ionizable sodium sulfonate. Due to immobile p-doping of organic anions, self-doped polymer can act as a for reversible Na insertion-extraction reaction, thus offering low cost and renewable ion battery applications.
Abstract The fabrication of circularly polarized luminescence (CPL) active materials by self‐assembly is still in its challenge. In this work, a family homochiral metal–organic frameworks (MOFs) and cages (MOCs) are constructed solvothermal subcomponent self‐assembly. These MOFs feature an eta topology with trifold helical chains, while the MOCs adopt cubic cage structure. chiral ligands show two distinct types conformations: “opened” “closed” MOCs, respectively. Although similar spectra...
The systematic induction of structural defects at the atomic level is crucial to metal nanocluster research because it endows cluster-based catalysts with highly reactive centers and allows for a comprehensive investigation viable reaction pathways. Herein, by substituting neutral phosphine ligands surface anionic thiolate ligands, we establish that one or two Au3 triangular units can be successfully introduced into double-stranded helical kernel Au44 (TBBT)28 , where...
Abstract To develop a simple and general method for improving the circularly polarized luminescence (CPL) performances of materials is great significance. In this work, two pairs CPL‐active homochiral metal–organic frameworks (MOFs) P/M‐Et P/M‐Et(Cd) with eta topology are reported. comparison to reported isomorphic Zn‐imidazolate MOFs P‐Me M‐Me, both dissymmetry factor ( g lum ) photoluminescence quantum yields Φ PL P‐Et M‐Et largely improved by simply changing methyl group an ethyl ligands...
Background: Chronic kidney disease (CKD) is now globally recognized as a critical public health concern. Vascular calcification (VC) represents significant risk factor for cardiovascular events in individuals with CKD. It the accessible and precise diagnostic biomarkers monitoring progression of CKD concurrent VC are urgently needed. Methods: The adenine diet-induced rat model was utilized to investigate chronic injury, thoracic aorta, dysregulation biochemical indices. Enzyme-linked immune...
Inflammation in visceral adipose tissues (VATs) contributes to the pathology of diabetes. This study focused on inflammatory regulation VATs by a yeast β-1,3-glucan (BYG) orally administered ob/ob mice. BYG decreased pro-inflammatory modulators TNF-α, IL-6, IL-1β, CCL2, and SAA3, increased anti-inflammatory factors Azgp1 (2.53 ± 0.02-fold change) at protein and/or mRNA levels (p < 0.05). Remarkably, degree tissue macrophages (ATMs) infiltration 82.5 8.3%, especially newly recruited ATMs....
Objective: To observe the clinical efficacy of Dendrobium officinale in treatment radiotherapy-induced oral mucositis nasopharyngeal carcinoma patients, and to explore its regulating effect on immune function microbiota by comparing immune-related factors before after intervention. Methods: We conducted a randomized double-blinded controlled trial Zhejiang Cancer Hospital. Sixty patients with cancer combined were randomly divided into study group control group, 30 cases each The used...
Multifunctional nanoparticles hold great potential for clinical and medical research. Herein, Ag2Te QDs were applied as multifunctional contrast agents the second near-infrared region (NIR-II) fluorescence X-ray computed tomography (CT) imaging. In vitro in vivo experiments demonstrated that exhibited low toxicity remarkable CT imaging properties. Moreover, long-term was also achieved. These results indicated had
Fluorescence in the near infrared IIb window (NIR-IIb, 1500–1700 nm) shows higher signal-to-noise ratio, better space-time resolution, and deeper tissue penetration. However, materials with excellent fluorescence properties NIR-IIb region were rarely reported. Ag2Te quantum dots (QDs) could emit variable NIR-II due to their narrow band gap. Unfortunately, was not strong enough image vivo because lattice defects on surface of increased non-radiative transitions decreased performance. In this...
Recent decades have witnessed remarkable progress in ligand-promoted C–H activation with palladium catalysts. While a number of transformations been achieved fairly broad substrate scope, the general requirements for high loadings and enormous challenges catalyst recycling severely limit practical applications methodologies organic synthesis. Herein, we incorporate N,C-ligand-chelated palladacycles into rigid, porous, crystalline covalent frameworks arylation indole pyrrole derivatives....
While the formation of superatomic nanoclusters by three-dimensional assembly icosahedral units was predicted in 1987, synthesis and structural determination such clusters have proven to be incredibly challenging. Herein, we employ a mixed-ligand strategy prepare phosphinous acid-phosphinito gold nanocluster Au52(HOPPh2)8(OPPh2)4(TBBT)16 with tetra-icosahedral kernel. Unlike expected, each Au13 unit shares one vertex atom two adjacent units, resulting "puckered" ring shape nuclearity 48 The...
In the present work, novel salts of multimodal antidepressant drug vortioxetine (VT) were crystallized with pharmaceutically acceptable acids, aiming to improve solubility VT. The acids for VT selected based on ΔpKa being greater than 2 or 3. Salts hydrobromic acid (HBr), hydrochloric (HCl), p-hydroxybenzoic (PHBA), saccharin (SAC) and L-aspartic (ASP) reported. All characterized by single-crystal X-ray diffraction, FT-IR, powder diffraction (PXRD) differential scanning calorimetry (DSC)....
A family of polyhedral metal-imidazolate cages based on the flexible bi-imidazole ligand L and Cu2+ ions have been synthesized characterized, featuring an unusual Cu10L8 bicapped square antiprism structure (or Johnson solids, J17) with adaptable cavity. These metal-organic encapsulate anions, they will expand or compress after are filled different-sized anions.