- Crystallization and Solubility Studies
- X-ray Diffraction in Crystallography
- Metal-Organic Frameworks: Synthesis and Applications
- Magnetism in coordination complexes
- Crystallography and molecular interactions
- Molecular Sensors and Ion Detection
- Lanthanide and Transition Metal Complexes
- Covalent Organic Framework Applications
- Metal complexes synthesis and properties
- Polyoxometalates: Synthesis and Applications
- Crystal structures of chemical compounds
- Advanced Nanomaterials in Catalysis
- Sulfur Compounds in Biology
- Nanoplatforms for cancer theranostics
- Dendrimers and Hyperbranched Polymers
- Luminescence and Fluorescent Materials
- Information and Cyber Security
- Advanced Biosensing Techniques and Applications
- Boron Compounds in Chemistry
- Advanced Photocatalysis Techniques
- Software System Performance and Reliability
- Advanced Differential Equations and Dynamical Systems
- Porphyrin and Phthalocyanine Chemistry
- Nanocluster Synthesis and Applications
- Chemical Synthesis and Characterization
Zhejiang Gongshang University
2025
North University of China
2009-2023
A water-stable metal–organic framework exhibits multiresponsive fluorescence sensing for Fe(<sc>iii</sc>), Cr(<sc>iii</sc>/<sc>vi</sc>), and Mn(<sc>vii</sc>) ions the organochlorine pesticide 2,6-Dich-4-NA in aqueous solution.
Two novel metal–organic frameworks exhibited excellent CO<sub>2</sub> selective absorption and multiresponsive fluorescent sensing for Fe<sup>3+</sup>, CrO<sub>4</sub><sup>2−</sup>/Cr<sub>2</sub>O<sub>7</sub><sup>2−</sup> the pesticide 2,6-Dich-4-nitroaniline.
Five 3D CPs were constructed from a designed π-conjugated aromatic pentacarboxylate with diverse structures.
In this study, we designed an effective nanoplatform to improve the photodynamic therapy (PDT) of porphyrins. Combining a porphyrin-based metallacage (PM), hyaluronidase (HAase) and DSPE-mPEG2000 together, nanoparticle (PM@HAase-mPEG) showed enhanced PDT efficacy. The PM improved stability porphyrin, avoided its aggregation provided cavities concentrate oxygen molecules, which was beneficial for enhancing PDT. HAase degraded HA increase intracellular accumulation nanoparticles, normalized...
On the basis of bifunctional 1,4-bis(imidazol-1-yl)terephthalic acid (H2BTA), four three-dimensional (3D) Pb(II)/Zn(II) coordination polymers (CPs), {[Zn(BTA)]·1.5(DOA)}n (1), [Zn(BTA)]n (2), [Pb(BTA)]n (3), and (4), have been synthesized (DOA = dioxane). Structural analyses reveal that two Zn(II)-based complexes are 3D (4,4)-c pts pseudo-supramolecular isomers for 1 2, Pb(II)-based supramolecular with a (4,5,6)-c net 3 6-c pcu 4, respectively. Furthermore, gas adsorption behaviors 2 N2,...
Four three-dimensional (3D) Cd(II)/Mn(II) coordination polymers, namely, {[Mn1.5(TCPB)(H2O)(μ2-OH2)]·H2O}n (1), {[Cd3.5(TCPB)2(H2O)3(μ2-OH2)(μ3-OH)]·H2O}n (2), [Mn1.5(TCPB)(bib)0.5(DMF)]n (3), and {[Cd2(TCPB)(HCOO)(bib)(H2O)]·0.5dioxane}n (4), have been constructed from the flexible tripodal ligand of 1,3,5-tris(4-carbonylphenyloxy)benzene (H3TCPB) with or without help bib auxiliary linker (bib = 1,4-bis(imidazol-1-yl)benzene). On basis one-dimensional (1D) rod-like {Mn3(COO)8(μ2-H2O)2}n...
Based on the tris(<italic>p</italic>-carboxyphenyl)phosphane oxide ligand, two Cd(<sc>ii</sc>) CPs were obtained which could highly sense nitrobenzene derivatives and Hg<sup>2+</sup> cations.
Five terphenyl-tetracarboxylic acid based on CPs with variable-temperature magnetic susceptibilities and luminescence sensing of small organic molecules.
A zinc(<sc>ii</sc>)-based metal–organic framework exhibits fluorescence turn-on behaviour for Fe<sup>3+</sup>and AA with high sensitivity and selectivity.
Three lanthanide(III)-based metal-organic frameworks, formulated as [(CH3)2NH2]2[Ln6(μ3-OH)8(EBTC)3(H2O)6]·4H2O·2DMF (Ln = Eu (1), Tb (2) and Ce (3)), were synthesized using a rigid tetracarboxylate organic ligand (1,1'-ethynebenzene-3,3',5,5'-tetracarboxylic acid, H4EBTC). Complexes 1-3 possess 12-connected hexanuclear [Ln6(μ3-OH)8(OOC-)12(H2O)6] clusters with the ftw topology, which stable in water acid/alkaline aqueous solution. Due to antenna effect, complexes 1 2 presented double...
Four 3D novel coordination polymers (CPs) have been synthesized under solvothermal conditions. Furthermore, gas sorption behaviors revealed that complex <bold>1</bold> has excellent selective separation for CO<sub>2</sub>/CH<sub>4</sub>.
A zinc(<sc>ii</sc>) metal–organic framework exhibits fluorescence on–off–on behaviour for Fe<sup>3+</sup>and reduced glutathione in PBS solution and real samples.
Based on the tripodal tris(4-carboxyphenyl)phosphane oxide ligand, two lanthanide metal–organic frameworks were obtained, with <bold>1</bold> showing highly selective gas adsorption of CO<sub>2</sub>/CH<sub>4</sub> and <bold>2</bold> exhibiting direct alternating current magnetic properties.