A5044782900- Crystal structures of chemical compounds
- Metal-Organic Frameworks: Synthesis and Applications
- Synthesis and biological activity
- Metal complexes synthesis and properties
- Magnetism in coordination complexes
- Crystallization and Solubility Studies
- X-ray Diffraction in Crystallography
- Chemical Synthesis and Analysis
- Lanthanide and Transition Metal Complexes
- Crystallography and molecular interactions
- Chemical Synthesis and Reactions
- Polyoxometalates: Synthesis and Applications
- Molecular Sensors and Ion Detection
- Asymmetric Hydrogenation and Catalysis
- Metabolomics and Mass Spectrometry Studies
- Synthesis of Tetrazole Derivatives
- Synthesis of Organic Compounds
- Synthesis and Characterization of Heterocyclic Compounds
- Metal-Catalyzed Oxygenation Mechanisms
- Covalent Organic Framework Applications
- Medical Research and Treatments
- Microbial Metabolism and Applications
- Cancer therapeutics and mechanisms
- Hydrogen Storage and Materials
- Microbial Natural Products and Biosynthesis
Kunming Medical University
2022-2023
Yan'an Hospital Affiliated To Kunming Medical University
2022-2023
Shandong University
2022
Lanzhou Jiaotong University
2009-2020
North University of China
2017-2019
Xiamen University
2019
Collaborative Innovation Center of Chemistry for Energy Materials
2019
Nanjing Maternity and Child Health Care Hospital
2019
Nanjing Medical University
2019
Seventh People's Hospital of Shanghai
2018
A new mononuclear Cu(II) complex, [Cu(L)2]·CH3OH·H2O, has been synthesized by the complexation of copper(II) acetate monohydrate with a oxime-type ligand (HL = 1-(4-{[(E)-3-ethoxyl-2-hydroxybenzylidene]amino}phenyl)ethanone oxime) in methanol/acetone solution. The atom is four-coordinated phenolate O atoms and imine N from two ligands, distorted square-planar geometry. O- N-donor are mutually cis dihedral angle between coordination plane (Cu1N2O2 Cu1N4O5) 48.06(3)°. In crystal structure,...
Five 3D CPs were constructed from a designed π-conjugated aromatic pentacarboxylate with diverse structures.
On the basis of bifunctional 1,4-bis(imidazol-1-yl)terephthalic acid (H2BTA), four three-dimensional (3D) Pb(II)/Zn(II) coordination polymers (CPs), {[Zn(BTA)]·1.5(DOA)}n (1), [Zn(BTA)]n (2), [Pb(BTA)]n (3), and (4), have been synthesized (DOA = dioxane). Structural analyses reveal that two Zn(II)-based complexes are 3D (4,4)-c pts pseudo-supramolecular isomers for 1 2, Pb(II)-based supramolecular with a (4,5,6)-c net 3 6-c pcu 4, respectively. Furthermore, gas adsorption behaviors 2 N2,...
A new three-dimensional magnetic network, [Co9(OH)6(C42H24O18P3N3)2(H2O)8] (1), has been successfully prepared by utilizing the flexible hexacarboxylate ligand derived from cyclotriphosphazene, which had characterized single-crystal X-ray diffraction and measurement. This compound consists of one-dimensional (1D) cobalt-hydroxyl chains based on planar nonanuclear clusters, are located in b–c plane to form nearly two-dimensional cobalt layer. Magnetic measurements reveal that 1 shows...
Abstract C 17 H 16 Cl 2 N O , monoclinic, P 1 / c (no. 14), a = 9.1238(5) Å, b 13.0575(4) 14.3740(5) β 104.616(4)°, V 1657.02(11) Å 3 Z 4, R gt ( F ) 0.0460, wR ref 0.1120, T 293(2) K.
Abstract C 17 H 16 Br 2 N O , monoclinic, P 1 / c (no. 14), a = 9.2648(14) Å, b 13.3034(16) 14.510(2) β 105.261(15)°, V 1725.4(4) Å 3 Z 4, R gt (F) 0.0679, wR ref (F ) 0.1657, T 293(2) K.
Reactions of CdSO4·6H2O and Hpytz [Hpytz = 5-(4-pyridyl)tetrazole] under high pH values produced a known compound, [Cd(pytz)2(H2O)4]·2H2O (1), which can be used to prepare [Cd(Hpytz)(SO4)(H2O)2] (2) by adjusting the lower level using sulfuric acid hydrothermal conditions. These compounds were characterized elemental analysis, IR spectroscopy, single-crystal diffraction. X-ray analysis reveals that 1 features mononuclear structure, while 2 affords 1-D polymeric chain structure. Compound...
Abstract C 16 H 15 BrN 2 O , monoclinic, P 1 / c (no. 14), a = 33.758(5) Å, b 7.1117(16) 6.2194(9) β 92.133(13)°, V 1492.1(4) Å 3 Z 4, R gt ( F ) 0.0693, wR ref 0.2153, T 278(4) K.
In our work, ciprofloxacin was extracted from the raw material hydrochloride and coordinated with metal ions of copper, manganese zirconium. The procedures include comparison autoclave method solvothermal method, synthesizing corresponding complexes conducting antibacterial test on nearly 20 kinds bacteria. It is shown that under condition PH1 110℃ - 116℃, can be utilized to obtain Cu2+, Mn2+ Zr2+ as ligands after reacting for 8 hours. material, monocrystals were characterized by IR, DSC, UV...
A protocol was developed to prepare linear amines by regioselective hydroaminomethylation of terminal olefins with pyrrole-based tetraphosphorus ligands. The reactivity the ligand is modulated substituent biphenylphosphane moiety, <bold>L5</bold> exhibiting highest reactivity.
Abstract C 36 H 38 CuN 4 O 6 , monoclinic, P 2 1 / c (no. 14), a = 10.7510(12) Å, b 6.4718(7) 24.254(2) β 101.99(1)°, V 1650.7(3) Å 3 Z 2, R gt ( F ) 0.0525, wR ref 0.1621, T 293(2) K.
Abstract C 34 H CuN 4 O 6 , Monoclinic, P 2 1 / c a = 10.4018(4) Å, b 6.1634(2) 24.2227(15) β 101.820(5)°, Z 2, V 1520.01(13) Å 3 R gt ( F ) 0.0565, wR ref 0.1455, T 292 K.
Abstract C 38 H 30 CuN 4 O , triclinic, P 1̅ (no. 2), a = 8.3882(7) Å, b 8.5024(9) c 11.3649(15) α 89.960(10)°, β 69.689(10)°, γ 80.269(8)°, Z 1, V 747.73(15) Å 3 R gt ( F ) 0.0701, wR ref 2 0.1308, T 294.68(10) K.
Abstract C 17 H 14 Cl 3 N 2 O 4 , orthorhombic, Fdd 2, a = 32.980(2) Å, b 24.6827(18) c 4.4872(3) V 3652.8(4) Å Z 8, R gt (F) 0.0783, wR ref (F ) 0.1862, T 293(2) K.
The coordination polymers of Ag<sup>+</sup> with a β-turn containing chiral thiol ligand exhibit supramolecular chirality showing simultaneously the majority rules effect (MRE) and racemate (RRE).
Article Crystal structure of 1-(4-{[(E)-5-bromo-2-hydroxybenzylidene]- amino}phenyl)ethanone oxime, C15H13BrN2O2 was published on June 1, 2012 in the journal Zeitschrift für Kristallographie - New Structures (volume 227, issue 2).
Abstract C 32 H 30 N 4 O Zn, triclinic, P 1̅ (no. 2), a = 8.6632(8) Å, b 12.7133(10) c 14.2719(12) α 98.585(3)°, β 94.985(3)°, γ 92.916(3)°, Z 2, V 1545.1(2) Å 3 , R gt ( F ) 0.0714, wR ref 2 0.1740, T 296(2) K.
Three new pyridine-2,4,6-tricarboxylic acid (H3ptc) complexes, [Mn3(ptc)2(H2O)9]n (1), [Co3(ptc)2(H2O)2]n (2), and [Co(bpy)(H2O)4]n[Co(ptc)(H2O)]2n (3) were hydrothermally synthesized characterized by single-crystal X-ray diffraction methods, elemental analyses, IR spectroscopy, thermal analyses magnetic measurements along with ferroelectric measurement for 1 carried out. Compound crystallizes in the acentric space groupCc exhibits significant ferroelectricity (a remnant polarization Pr =...
To evaluate the diagnostic value of BACs-on-Beads (BoBs) assay for rapid diagnosis common aneuploidies and microdeletions.A total 4961 pregnant women admitted to Wuxi Maternity Child Health Care Hospital Affiliated Nanjing Medical University from January 2017 March 2019 were enrolled. BoBs conventional karyotyping applied detect amniotic fluid samples with various indications prenatal diagnosis. Chromosomal microarray analysis (CMA) maternal cell contamination (MCC) tests used further...