A5102821041- X-ray Diffraction in Crystallography
- Crystallization and Solubility Studies
- Crystal structures of chemical compounds
- Metal complexes synthesis and properties
- Synthesis and biological activity
- Metal-Organic Frameworks: Synthesis and Applications
- Magnetism in coordination complexes
- Chemical Synthesis and Analysis
- Crystallography and molecular interactions
- Metal-Catalyzed Oxygenation Mechanisms
- Lanthanide and Transition Metal Complexes
- Organometallic Complex Synthesis and Catalysis
- Polyoxometalates: Synthesis and Applications
- Microbial Natural Products and Biosynthesis
- Synthesis and Catalytic Reactions
- Asymmetric Hydrogenation and Catalysis
- Coordination Chemistry and Organometallics
- Extraction and Separation Processes
- Carbon dioxide utilization in catalysis
- Chemical Synthesis and Reactions
- Parasitic infections in humans and animals
- Click Chemistry and Applications
- Synthesis of Organic Compounds
- Inorganic Chemistry and Materials
- Advancements in Battery Materials
Shihezi University
2019-2025
East China University of Science and Technology
2024
Harbin Engineering University
2023
Lanzhou Jiaotong University
2012-2018
Xinjiang Medical University
2012
A new mononuclear Cu(II) complex, [Cu(L)2]·CH3OH·H2O, has been synthesized by the complexation of copper(II) acetate monohydrate with a oxime-type ligand (HL = 1-(4-{[(E)-3-ethoxyl-2-hydroxybenzylidene]amino}phenyl)ethanone oxime) in methanol/acetone solution. The atom is four-coordinated phenolate O atoms and imine N from two ligands, distorted square-planar geometry. O- N-donor are mutually cis dihedral angle between coordination plane (Cu1N2O2 Cu1N4O5) 48.06(3)°. In crystal structure,...
Summary Echinococcosis is a chronic parasitic infectious disease regulated by T‐cell subsets. CD4 + CD25 FoxP3 regulatory T (Treg) cells and Th17 have been described as two distinct subsets the opposite effect on inflammation. Th17/Treg balance controls inflammation may play an important role in pathogenesis of immune evasion. To assess whether this was broken, we detected functions different levels including cell frequencies, related cytokines secretion key transcription factors patients...
Abstract C 36 H 56 N 2 O 4 , monoclinic, P 1 / c (no. 14), a = 18.1240(10) Å, b 17.1409(9) 11.3102(6) β 95.659(2)°, V 3,496.5(3) Å 3 Z 4, R gt ( F ) 0.0638, wR ref 0.1634, T 173 K.
The functionzalization of NH-sulfoximines to construct N–C bonds from common carboxylic acids remained underdeveloped. Herein, electrochemical strategies were utilized enable the chemoselective decarboxylation or deoxygenation for...
An efficient, reliable and atom-economic strategy employing azomethine ylides isatin-derived trifluoromethyl acrylates via intermolecular [3+2] cycloaddition for construction of valuable highly substituted pyrroledines bearing adjacent all-carbon quaternary stereocenters (one which is a spirocyclic stereocenter the other trifluoromethylated stereocenter) at C3 C4 positions has been developed first time. The corresponding products with broad substrate scope, good functional group tolerance...
Abstract C 17 H 16 Cl 2 N O , monoclinic, P 1 / c (no. 14), a = 9.1238(5) Å, b 13.0575(4) 14.3740(5) β 104.616(4)°, V 1657.02(11) Å 3 Z 4, R gt ( F ) 0.0460, wR ref 0.1120, T 293(2) K.
Many methods have been utilized to adjust the size of superatomic metal nanoclusters, while tuning geometric conformations specific nanoclusters is rare. Here, we demonstrate that conformation variation can be realized by slightly modifying ligand under maintaining nuclei number atoms. A series novel "double-chair" Ln12 (Ln = Sm (1), Eu (2), Gd (3), Tb (4), and Dy (5)) clusters were generated replacing 3-formylsalicylic acid with 2,3-dihydroxybenzoic in nanocluster. Intriguingly, Dy12...
Abstract C 17 H 16 Br 2 N O , monoclinic, P 1 / c (no. 14), a = 9.2648(14) Å, b 13.3034(16) 14.510(2) β 105.261(15)°, V 1725.4(4) Å 3 Z 4, R gt (F) 0.0679, wR ref (F ) 0.1657, T 293(2) K.
Abstract C 16 H 15 BrN 2 O , monoclinic, P 1 / c (no. 14), a = 33.758(5) Å, b 7.1117(16) 6.2194(9) β 92.133(13)°, V 1492.1(4) Å 3 Z 4, R gt ( F ) 0.0693, wR ref 0.2153, T 278(4) K.
Abstract C 36 H 38 CuN 4 O 6 , monoclinic, P 2 1 / c (no. 14), a = 10.7510(12) Å, b 6.4718(7) 24.254(2) β 101.99(1)°, V 1650.7(3) Å 3 Z 2, R gt ( F ) 0.0525, wR ref 0.1621, T 293(2) K.
Abstract C 34 H CuN 4 O 6 , Monoclinic, P 2 1 / c a = 10.4018(4) Å, b 6.1634(2) 24.2227(15) β 101.820(5)°, Z 2, V 1520.01(13) Å 3 R gt ( F ) 0.0565, wR ref 0.1455, T 292 K.
Abstract C 38 H 30 CuN 4 O , triclinic, P 1̅ (no. 2), a = 8.3882(7) Å, b 8.5024(9) c 11.3649(15) α 89.960(10)°, β 69.689(10)°, γ 80.269(8)°, Z 1, V 747.73(15) Å 3 R gt ( F ) 0.0701, wR ref 2 0.1308, T 294.68(10) K.
Abstract C 32 H 30 N 4 O Zn, triclinic, P 1̅ (no. 2), a = 8.6632(8) Å, b 12.7133(10) c 14.2719(12) α 98.585(3)°, β 94.985(3)°, γ 92.916(3)°, Z 2, V 1545.1(2) Å 3 , R gt ( F ) 0.0714, wR ref 2 0.1740, T 296(2) K.
Abstract C 16 H 15 ClN 2 O , monoclinic, P 1 / c (no. 14), a = 33.491(11) Å, b 7.124(2) 6.1977(19) β 92.212(6)°, V 1477.6(8) Å 3 Z 4, R gt ( F ) 0.0418, wR ref 0.1193, T 296(2) K.
Abstract C 34 H N 4 NiO 6 , monoclinic, P 2 1 / c (no. 14), a = 10.5538(5) Å, b 6.1691(2) 24.2831(9) β 100.519(4)°, Z 2, V 1554.43(11) Å 3 R gt ( F ) 0.0402, wR ref 0.0973, T 294.39(10) K.
Abstract C 15 H 14 N 2 O , monoclinic, P 1 / c (no. 14), a = 13.5809(12) Å, b 9.7794(14) 9.8883(9) β 97.972(9)°, Z 4, V 1300.6(3) Å 3 R gt ( F ) 0.0635, wR ref 0.1758, T 291(2) K.
Abstract C 36 H 38 CuN 4 O , triclinic, P 1̄, a = 8.492(2) Å, b 9.574(2) c 10.512(2) α 100.170(7)°, β 103.421(7)°, γ 95.055(8)°, Z 1, V 810.8(3) Å 3 R gt ( F ) 0.0418, wR ref 2 0.1193, T 296(2) K.
Abstract C 34 H 32 Br 2 Cl 4 CoN O , monoclinic, 2/ c (no. 15), a = 30.281(3) Å, b 8.9971(8) 13.9050(13) β 107.053(5)°, Z 4, V 3621.7(6) Å 3 R gt ( F ) 0.0648, wR ref 0.1629, T 173(2) K.
Abstract C 16 H 15 FN 2 O , monoclinic, P 1 / c (no. 14), a = 6.0573(3) Å, b 13.8341(6) 33.0876(15) β 92.837(2)°, Z 8, V 2769.3(2) Å 3 R gt ( F ) 0.0581, wR ref 0.1605, T 173(2) K.
Abstract C 16 H 15 BrN 2 O , monoclinic, P 1 (no. 4), a = 10.9311(8) Å, b 3.9554(3) c 16.5215(12) β 92.743(2)°, V 713.52(9) Å 3 Z 2, R gt ( F ) 0.0335, wR ref 0.0655, T 173(2) K.
In the title compound, C(17)H(18)N(2)O(3), benzene rings form a dihedral angle of 3.34 (2)°. There is strong intra-molecular O-H⋯N hydrogen bonds (which induces planarity structure). crystal, mol-ecules are linked by pairs bonds, forming inversion dimers.
Abstract C 17 H ClN 2 O , monoclinic, Pc (no. 7), a = 17.789(2) Å, b 7.1127(7) c 6.2885(6) β 97.513(10)°, Z 2, V 788.83(15) Å 3 R gt ( F ) 0.0600, wR ref 0.1651, T 290.83(10) K.