A5102859922- Fullerene Chemistry and Applications
- Advanced Sensor and Energy Harvesting Materials
- Boron and Carbon Nanomaterials Research
- Conducting polymers and applications
- Molecular Junctions and Nanostructures
- Diamond and Carbon-based Materials Research
- Advanced Materials and Mechanics
- Quantum and electron transport phenomena
- Graphene research and applications
- Nuclear materials and radiation effects
- Advanced Chemical Physics Studies
- Advanced battery technologies research
- Neuroscience and Neural Engineering
- Electrocatalysts for Energy Conversion
- Supercapacitor Materials and Fabrication
- Tactile and Sensory Interactions
- Electrochemical Analysis and Applications
Xi'an Jiaotong University
2022-2025
University of Cambridge
2023-2024
Equilibrium Research
2024
Institute for Molecular Science
2022
Shanxi University
2022
Kunming University of Science and Technology
2019
Abstract The functional and sensory augmentation of living structures, such as human skin plant epidermis, with electronics can be used to create platforms for health management environmental monitoring. Ideally, bioelectronic interfaces should not obstruct the inherent sensations physiological changes their hosts. full life cycle also designed minimize footprint. Here we report imperceptible systems through in situ tethering organic fibres. Using an orbital spinning technique,...
Abstract Single-atom magnetism switching is a key technique towards the ultimate data storage density of computer hard disks and has been conceptually realized by leveraging spin bistability magnetic atom under scanning tunnelling microscope. However, it rarely applied to solid-state transistors, an advancement that would be highly desirable for enabling various applications. Here, we demonstrate realization electrically controlled Zeeman effect in Dy@C 84 single-molecule thus revealing...
Spin qubits constructed in endohedral fullerenes benefit from the protective shielding of carbon cage, which effectively mitigates external decoherence and enables ultralong coherence times. However, fullerene spin face challenge charge transfer complex electrical environments, such as during qubit readout or large-scale integration, can induce state modifications. In this study, we developed transistors based on Lu2@C82 observed absence parity dependence Kondo effect; result was...
Although Ruthenium-based pyrochlore oxides can function as promising catalysts for acidic water oxidation, their limitations in terms of stability and activity still need to be addressed further application practical conditions. In this work, the possibility enhance both oxygen evolution reaction durability Gd
Endohedral metal-metal-bonding fullerenes, in which encapsulated metals form covalent metal-metal bonds inside, are an emerging class of endohedral metallofullerenes. Herein, we reported quantum-chemical studies on the electronic structures, chemical bonding, and dynamic fluxionality behavior fullerenes Lu2@C2n (2n = 76-88). Multiple bonding analysis approaches, including molecular orbital analysis, natural bond electron localization function, adaptive density partitioning quantum theory...
<p>Functional and sensory augmentation of living structures, such as the human skin plant epidermis, offers vast opportunities for biology-machine interface, wearable health, environmental monitoring. However, current sensor electronic formats could be obstructive to their hosts’ inherent sensations or physiological changes. Challenges are also faced in widening structures without drastically increasing global ecological burdens. Here, we demonstrate imperceptibly augmented systems,...
<p>Functional and sensory augmentation of living structures, such as the human skin plant epidermis, offers vast opportunities for biology-machine interface, wearable health, environmental monitoring. However, current sensor electronic formats could be obstructive to their hosts’ inherent sensations or physiological changes. Challenges are also faced in widening structures without drastically increasing global ecological burdens. Here, we demonstrate imperceptibly augmented systems,...
We performed quantum chemical calculations on the geometries, electronic structures, bonding properties, and stability strategy of endohedral metallofullerenes TM@C28 (TM = Sc−, Y−, La−, Ti, Zr, Hf, V+, Nb+, Ta+). Our revealed that there are three different lowest-energy structures with C2v, C3v, Td symmetries for TM@C28. The HOMO–LUMO gap all these ranges from 1.35 eV to 2.31 eV, in which [V@C28]+ has lowest eV. molecular orbitals mainly composed fullerene cage slightly encapsulated metal...
Clusterfullerenes, which contain a cluster rather than single-atom inclusions, exhibit more complex internal structures and greater degrees of freedom for motion. Trimetallic nitride clusterfullerenes have attracted significant attention due to their diversity potential applications, among Y3N@C80 stands out its charge-transfer characteristics in electronic excitations, owing the unique distribution molecular orbitals near Fermi level. Here, we fabricated single-molecule transistor devices...
Single-atom magnetism switching is a key technique towards the ultimate data storage density of computer hard disks and has been conceptually realized by leveraging spin bistability magnetic atom under scanning tunnelling microscope. However, it rarely applied to solid-state transistors, an advancement that would be highly desirable for enabling various applications. Here, we demonstrate realization electrically controlled Zeeman effect in Dy@C84 single-molecule thus revealing transition...
Endohedral metal-metal-bonding fullerenes have recently emerged, in which encapsulated metals form a metal-metal bond. However, the physical reasons why some metal elements prefer to bonds inside fullerene are still unclear. Herein, we reported first-principles calculations on electronic structures, bonding properties, dynamics, and thermodynamic stabilities of endohedral metallofullerenes M2@C82 (M = Sc, Y, La, Lu). Multiple analysis approaches unambiguously reveal existence one two-center...