A5102982919- Luminescence and Fluorescent Materials
- Organic Light-Emitting Diodes Research
- Molecular Junctions and Nanostructures
- Crystallization and Solubility Studies
- X-ray Diffraction in Crystallography
- Organic Electronics and Photovoltaics
- Radical Photochemical Reactions
- Chemical Synthesis and Analysis
- Photonic and Optical Devices
- Click Chemistry and Applications
- Photochromic and Fluorescence Chemistry
- Synthesis and Properties of Aromatic Compounds
- Nanotechnology research and applications
- Catalytic Cross-Coupling Reactions
- Multicomponent Synthesis of Heterocycles
- Various Chemistry Research Topics
- Nonlinear Dynamics and Pattern Formation
- Porphyrin and Phthalocyanine Chemistry
- Nonlinear Optical Materials Studies
- Liquid Crystal Research Advancements
- Chemical synthesis and alkaloids
- Synthesis and Biological Evaluation
- Microwave-Assisted Synthesis and Applications
- Polydiacetylene-based materials and applications
- Crystallography and molecular interactions
Instituto de Ciencia de Materiales de Madrid
2023-2024
University of Castilla-La Mancha
2015-2024
Instituto de Ciencia de Materiales de Sevilla
2024
Hospital General Universitario de Ciudad Real
2016-2019
The aim of this work was to determine the parameters that have decisive roles in microwave-assisted reactions and develop a model, using computational chemistry, predict priori type can be improved under microwaves. For purpose, study carried out on variety reactions, which been reported microwave irradiation. This comprises six types reactions. outcomes obtained indicate most influential are activation energy, enthalpy, polarity all species participate. In addition this, cases, slower...
Abstract Herein, we report the de novo synthesis and characterization of a series substituted bithiophene derivatives as novel inexpensive organic photocatalysts. DFT calculations were used to predict priori their absorption spectra redox potentials, which then confirmed with empirical data. The photocatalytic activity this class photoredox catalyst was demonstrated in two visible‐light mediated strategies for C−H functionalization heteroarenes. implementation these continuous‐flow...
The 1,2,4-triazole system has shown excellent electron-transport and hole-blocking properties owing to its highly electron-deficient nature. Accordingly, a large number of derivatives have been described as having wide variety uses in materials science. Triazoles are widely used transition-metal complexes or metal-organic frameworks (MOFs), but metal-free also exhibited interesting useful materials. use these derivatives, either small molecules polymers, light-emitting devices allowed the...
The exploration of mechanical motion in molecular crystals under external stimuli is great interest because its potential applications diverse fields, such as electronics, actuation, or sensing. Understanding the underlying processes, including phase transitions and structural changes, crucial for exploiting dynamic nature these crystals. Here, we present a novel organic compound,
T-Shaped 2<italic>H</italic>-benzo[<italic>d</italic>][1,2,3]triazole derivatives have been synthesized by Sonogashira coupling reactions under microwave irradiation.
The design, synthesis and evaluation of the amplified spontaneous emission (ASE) properties a series arylalkynyl-benzo[<italic>c</italic>][1,2,5]thiadiazole (BTD) [1,2,5]thiadiazolo[3,4-<italic>g</italic>]quinoxaline (TDQ) derivatives are described.
We report a semiconducting triindole-based discotic liquid crystal (TRISMe) functionalized with six p-methylthiophenyl groups at its periphery. While initially crystalline solid room temperature, TRISMe transitions to columnar hexagonal mesophase upon heating and retains this supramolecular organization subsequent cooling, despite having only three flexible alkyl chains attached the core's nitrogens. The incorporation of methylthio effectively hinders tight molecular packing, stabilizing...
Herein, we present a novel C(sp3)–C(sp3) bond-forming protocol via the reductive coupling of abundant tertiary amides with organozinc reagents prepared in situ from their corresponding alkyl halides. Using multistep fully automated flow protocol, this reaction could be used for both library synthesis and target molecule on gram-scale starting bench-stable reagents. Additionally, excellent chemoselectivity functional group tolerance make it ideal late-stage diversification druglike molecules.
Crystalline assembly of naphthalenimide derivatives with a D–π–A structure gives rise to light guiding and mechanical thermal stimuli-responsiveness.
Abstract The fight against counterfeiting is a crucial concern for economies around the world, underscoring urgent need effective measures to ensure legitimacy of products and documents. Luminescent security inks have emerged as tools in this battle. third generation these inks, incorporating stimuli‐responsive organic materials, enables unique efficiency. In work, behavior three trialkylated triazatruxene dimers ( TRI1 , TRI2 TRI3) endowed with N ‐alkyl chains different length investigated....
Abstract A two‐step transition metal‐free methodology for the C( sp 3 )−C( ) functionalisation of saturated N ‐heterocyclic systems is disclosed. First, aminal derivatives are generated through anodic oxidation readily accessible carboxylic acids. Then, in presence BF ⋅ OEt 2 , iminium ions unmasked and rapidly alkylated by organozinc reagents under flow conditions. Secondary, tertiary quaternary carbon centers have been successfully assembled using this methodology. Such an approach...
Abstract Different alkynyl azoles and benzoazoles have been synthesized in good yields by carbon‐carbon coupling reactions. The self‐assembly of some these compounds the slow diffusion technique led to well‐defined ribbons needle‐like aggregates. X‐ray study materials showed that CH‐π interactions involving C≡C triple bond heteroatoms induce aggregation along with H‐bonds due methoxy groups. A fluorescence confocal optical microscopy most aggregates indicated waveguide behavior different colors.
A series of donor-π-acceptor-π-donor (D-π-A-π-D) benzoazole dyes with 2H-benzo[d][1,2,3]triazole or BTD cores have been prepared and their photophysical properties characterized. The these compounds display remarkable differences, mainly as a result the electron-donor substituent. Dyes best visible-light absorption over λ=400 nm, large Stokes shifts in range about 3500-6400 cm-1 , good fluorescence emission quantum yields up to 0.78. two-photon were also studied establish relationship...
Carbon nanohorns have been non-covalently functionalized with two different benzothiadiazoloquinoxalines prepared via Stille cross-coupling reactions under solvent-free conditions and microwave irradiation. The close interactions between these organic molecules the nanostructures resulted in a prominent Raman enhancement, which makes them attractive candidates for multiple applications. A complete experimental physico-chemical characterization has combined silico studies to understand...
Ambient pressure chemical vapour deposition of 5,5'-bis((2-(trifluoromethyl)phenyl)ethynyl)-2,2'-bithiophene provides ultrapure needle-shaped crystals. The crystal's supramolecular structure consists an array hydrogen bonds and π-π interactions leading to anisotropic arrangements. cyan emitting crystals exhibit optical waveguiding tendency with guided polarised emissions due molecular
2,4,6-Triphenylpyrylium fluorophores were covalently attached to the graphene walls of short single-wall carbon nanotubes (sSWCNTs) using carbene chemistry. Covalent functionalization was confirmed by Raman spectroscopy, atomic force microscopy, thermogravimetric analysis and solution ¹H NMR spectroscopy. The SWCNTs found quench fluorescence fluorophores.