Caliphs Zvinowanda

ORCID: 0000-0003-4849-2537
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About
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Research Areas
  • Adsorption and biosorption for pollutant removal
  • Mine drainage and remediation techniques
  • Pharmaceutical and Antibiotic Environmental Impacts
  • Freezing and Crystallization Processes
  • Water Quality Monitoring and Analysis
  • Tailings Management and Properties
  • Analytical chemistry methods development
  • Heavy metals in environment
  • Advanced Photocatalysis Techniques
  • Advanced oxidation water treatment
  • Arsenic contamination and mitigation
  • Magnetic and Electromagnetic Effects
  • Minerals Flotation and Separation Techniques
  • Metal Extraction and Bioleaching
  • Metal-Organic Frameworks: Synthesis and Applications
  • Effects and risks of endocrine disrupting chemicals
  • Thermochemical Biomass Conversion Processes
  • Coal and Its By-products
  • Membrane Separation Technologies
  • Odor and Emission Control Technologies
  • Wastewater Treatment and Nitrogen Removal
  • Nanopore and Nanochannel Transport Studies
  • Fluoride Effects and Removal
  • Thermal and Kinetic Analysis
  • Cassava research and cyanide

University of Johannesburg
2017-2024

Bindura University of Science Education
2019

Tshwane University of Technology
2008-2015

The contamination of the environment by organic pollutants is a major risk factor, particularly for developing countries. Selected (SOPs) like phenolic compounds, polyaromatic hydrocarbons (PAHs), pesticides, and herbicides pose serious environmental health issues owing to their toxic characteristics poor degradability. Apart from potential mutagenicity, carcinogenicity, tetragenicity high body accumulation, these have become an increase concern worldwide. Biosorption promising alternative...

10.1016/j.emcon.2021.12.005 article EN cc-by-nc-nd Emerging contaminants 2022-01-01

The intention of this study was to explore the efficacy and feasibility for Cu (II) adsorption onto fixed bed column maize tassel-PVA beads.The effects flow rate height were explored.The Thomas, Adams Bohart Yoon-Nelson models analysed evaluate performance.The constant correlation coefficient associated each model calculated.Thomas indicated that increase in increased values k Th q o .Thereafter, value decreased with decreasing height.With Adam-Bohart model, AB as continued decrease...

10.4172/2157-7048.1000131 article EN Journal of Chemical Engineering & Process Technology 2012-01-01

In the present work P-ZrO2CeO2ZnO nanoparticles were synthesised for first time using phytochemical extracts from Flacourtia indica leaves and applied in photocatalytic degradation of Congo Red presence Light Emitting Diode warm white light. The was optimized with respect to nanoparticle dosage, initial concentration, time. optimum conditions synthesis pH 9, F. dosage 4 g 100 mL-1, Zirconia, Cerium Zinc metal ion concentration 0.05 mg/L plant volume ratio 1:4. extract had most significant...

10.1016/j.heliyon.2022.e10277 article EN cc-by Heliyon 2022-08-01

Problem statement: Major adsorbent materials used in heavy metal ion removal from polluted aqueous streams are expensive and difficult to regenerate. In this study, the possibility of using Zea mays tassel, as an alternative low cost biosorbent material remediate pollution was investigated. Lead (II) because its wide application industrial products well documented toxicity. Approach: Tassel obtained mature cultivar R52 hybrid plants. The tassel milled a powder adsorb lead(II) ions simulated...

10.3844/ajbbsp.2010.1.10 article EN cc-by American journal of biochemistry & biotechnology/American journal of biochemistry and biotechnology 2010-01-01

This research employed the application of metal organic frameworks (MOFs) zinc and copper-based materials in removal naphthalene anthracene. Naphthalene anthracene adsorption were investigated with both zinc-benzene-1,4-dicarboxylic (Zn-BDC) copper-benzene-1,4-dicarboxylic (Cu-BDC) MOFs. Langmuir, Freundlich Temkin isotherms used to investigate mechanisms data obtained. Zn-BDC Cu-BDC MOFs stable at a wide range temperatures they exhibited appreciable desorption regenerating ability. About...

10.4314/bcse.v33i2.4 article EN cc-by Bulletin of the Chemical Society of Ethiopia 2019-07-15

Cooling and freezing can be used to produce fresh water from brackish water, industrial brines leachates wastes.The aim of this study was identify how cooling and/or for the recovery drinking sulphate rich solutions associated with various cations.It found that: (i) If solution contains only Na 2 SO 4 , after pre-treatment sodium alkalis, it removed through down 0.33 mol/L (31.7 g/L ) crystallization •10H O; (ii) solubility upon is influenced by Clconcentration; (iii) Reverse Osmosis-Cooling...

10.5004/dwt.2017.20927 article EN cc-by-nc-nd Desalination and Water Treatment 2017-06-01

Rooibos (Aspalathus linearis) plants are cultivated for the production of tea. In this work, biosorption process Pb(II) from aqueous solution on shoot powder (RSP) was studied in a batch process. The effect experimental parameters such as pH (2–9), contact time (30–180 min) and initial concentration (25–400 mg L−1), adsorbent dosage (0.2–2.1 g), temperature (25–80°C) examined. an attempt to determine capacity rate removal, isotherm kinetic data were modeled using different equations. To end,...

10.1080/19443994.2015.1004116 article EN cc-by-nc-nd Desalination and Water Treatment 2015-01-23

AbstractFreeze desalination of synthetic brines prepared from sodium chloride was investigated. Brine solutions levels between 2.3% to 10% were used as feed the plant operated in a batch and continuous mode. The effects pump, gear motor speed, differential temperatures on ice formation purity HybridICE process produced quality 80–96% purity. It observed that pump speed directly proportional effluent flow rate coming out heat exchangers. Generally, it product higher at low medium rates feed....

10.1080/19443994.2013.822175 article EN cc-by-nc-nd Desalination and Water Treatment 2013-08-02

Mining activities are the main cause of generation voluminous sludge waste, loaded with metals precipitated from treatment acid mine drainage (AMD) and this is always disposed to landfill. This study aimed at characterizing suggesting reusability potential AMD reduce environmental problem caused by its accumulation so that it could become a valuable material. The was obtained after treating synthetic green oxidant sodium ferrate (VI) (Na2FeO4) prepared wet oxidation method. Chemical physical...

10.1016/j.heliyon.2020.e05244 article EN cc-by-nc-nd Heliyon 2020-10-01
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