A5024407096- Crystallization and Solubility Studies
- X-ray Diffraction in Crystallography
- Solid-state spectroscopy and crystallography
- Perovskite Materials and Applications
- Nanoplatforms for cancer theranostics
- Crystallography and molecular interactions
- Ferroelectric and Piezoelectric Materials
- Nonlinear Optical Materials Research
- Analytical Chemistry and Chromatography
- Immune cells in cancer
- Click Chemistry and Applications
- Nanoparticle-Based Drug Delivery
- Crystal structures of chemical compounds
- Metal-Organic Frameworks: Synthesis and Applications
- Photodynamic Therapy Research Studies
- Biotin and Related Studies
- Luminescence and Fluorescent Materials
- Magnetism in coordination complexes
- Advanced oxidation water treatment
- Polyoxometalates: Synthesis and Applications
- Natural product bioactivities and synthesis
- Thermal Expansion and Ionic Conductivity
- Lanthanide and Transition Metal Complexes
- Crystal Structures and Properties
- Ionic liquids properties and applications
Southeast University
2021-2025
Organic–inorganic hybrid perovskite materials have attracted much attention because they combine the advantages of organic and inorganic components at molecular level. both structural variability flexibility components, as well magnetic, electrical, thermal properties components. A novel one-dimensional organic–inorganic halide material [Et3NCH2Br][PbBr3] (compound 1) undergoes a high-temperature phase transition around 429.3 K, which is triggered by order–disorder change cations....
Phototherapy is considered a promising alternative to conventional tumor treatments due its noninvasive modality and effective therapeutic effect. However, designing photosensitizer with satisfactory effect high security remains considerable challenge. Herein, series of dimeric heptamethine cyanine photosensitizers an aromatic diphenol linker at the meso position developed improve photothermal conversion efficiency (PCE). Thanks extended conjugate system steric hindrance, screened 26NA-NIR...
Organic–inorganic hybrid phase-transition materials have attracted widespread attention in energy storage and sensor applications due to their structural adaptability facile synthesis. However, increasing the temperature (Tc) effectively remains a formidable challenge. In this study, we employed strategy regulate intermolecular interactions (different types of hydrogen bonds other weak interactions), utilizing bismuth chloride as an inorganic framework azetidine, 3,3-difluoro 3-carboxyl...
A B S T R C The focus of this study is on the development novel host‐guest inclusion compounds, which a crucial molecule model for synthesis dielectric phase transition materials. In research, new compound was successfully synthesized by selecting 18‐crown‐6 as host and 3‐aminocyclobutanone guest molecule. Thermal behavior crystal structure were analyzed in article. It found that exhibits reversible near 147 K, accompanied with anomaly, exhibiting switching characteristic. connected via...
Proximity labeling platforms (PLPs) have become a powerful tool for studying spatial cell‐cell interactions (CCIs) in living organisms. However, their effectiveness often relies on membranal catalytic modules of bait cells, such as natural enzymes or small‐molecule photocatalysts, which are typically constrained by complex genetic modifications the limited applicability visible light. Here, we present novel chemocatalytic approach, ArM‐Tag, utilizes an engineered artificial metalloenzyme...
Proximity labeling platforms (PLPs) have become a powerful tool for studying spatial cell‐cell interactions (CCIs) in living organisms. However, their effectiveness often relies on membranal catalytic modules of bait cells, such as natural enzymes or small‐molecule photocatalysts, which are typically constrained by complex genetic modifications the limited applicability visible light. Here, we present novel chemocatalytic approach, ArM‐Tag, utilizes an engineered artificial metalloenzyme...
Integrated multichannel response switches, characterized by their simple and compact structure, have a wide range of applications in the fields smart temperature sensors, communication devices. Starting from N,N-dimethylpropan-2-amine, this paper reports on three new perovskite materials introducing groups -OH -OMe through chemical design. All materials, namely, (DMIPA)PbBr3, (DMIPA-OH)PbBr3, (DMIPA-OMe)PbBr3, possess both enthalpic dielectric switching characteristics, with (DMIPA)PbBr3...
Ferroelectric materials have broad application prospects in photovoltaics, energy storage, information storage and other fields, it is always a challenge to obtain ferroelectric through rational molecular design. Noncentrosymmetric...
The second near-infrared window (NIR-II, 900–1700 nm) fluorescence imaging has garnered considerable attention for its deep tissue penetration and high contrast. However, the development of small molecular fluorophores that encompass NIR-II wavelength, brightness, large Stokes shift presents a formidable challenge. Herein, we report series phenanthridinium-based fluorophores, named YH dyes, which exhibit brightness shift. Among these YH-1c demonstrates best quantum yield (2.06% in DMSO)...
A novel one-dimensional hybrid perovskite ( trans -4-methylcyclohexylammonium)CdCl 3 undergoes successive structural phase transitions accompanied by switchable dielectric and photoluminescent behaviors.
Hybrid organic-inorganic perovskites with structural transformation have garnered continued interest in recent years for their potential as multifunctional materials the field of optoelectronics and smart devices. Herein, we report a novel hybrid halide, [C5NOH12]2[Cd1.5Cl5(H2O)] (1). Remarkably, centrosymmetric compound 1 undergoes to noncentrosymmetric perovskite [C5NOH12][CdCl3] (2) after dehydration. Accompanied by chemical bond cleavage reorganization, zero-dimensional (0D) trinuclear...
Abstract A total of seven compounds, including four triterpene acids and three lactones, were isolated from the ethanolic extract roots Astilbe grandis Stapf ex Wils. Two lactones ( 1 – 2 ) never reported before compounds 3 5 for first time plant. The structures these all identified by spectroscopic analysis. Compounds analyzed 2D NMR their absolute configurations determined using experimental CD in comparison with calculated ECD values. structure compound was also further confirmed single...
A novel organic–inorganic hybrid material (Et 3 NC 2 H 4 Br)FeCl , has been successfully synthesized. It demonstrates a dielectric switching ratio exceeding 10 at 500 Hz, which is tunable through temperature variations.
Dielectric and optical properties of an organic–inorganic hybrid phase transition material.
Structural analysis of two novel cyano-bridged coordination polymers synthesized by sealing the incomplete cage.
Abstract Host‐guest inclusion materials serve as an ideal model for designing phase transition materials. The typical host molecule, 18‐crown‐6 (1, 4, 7, 10, 13, 16‐hexaoxacyclo‐octadecane), is known its strong coordination with amino compounds through N−H⋅⋅⋅O hydrogen‐bonding interactions, attracting the attention of numerous scientific researchers. This study presented successful synthesis and characterization two host‐guest materials, [(trans‐4‐aminocyclohexanol)(18‐crown‐6)][ClO 4 ] ( 1...
Although chemotherapy can elicit antitumor immune response by the induction of immunogenic cell death (ICD), cyclooxygenase-2 (COX-2) and its downstream product prostaglandin E2 (PGE2), as negative regulators, impede effect immunotherapy. Herein, we rationally synthesized COX-2/PGE2-inhibiting poly(salicylic acid) (PSA) constructed esterase-responsive pemetrexed-conjugated PSA-PEG-FA prodrug nanoparticles (PEM–PPFs) a self-assembly strategy, thereby inducing sufficient ICD, boosting...