A5103101870- Crystallization and Solubility Studies
- X-ray Diffraction in Crystallography
- Metal-Organic Frameworks: Synthesis and Applications
- Polyoxometalates: Synthesis and Applications
- Polymer Surface Interaction Studies
- Advanced Photocatalysis Techniques
- Electrospun Nanofibers in Biomedical Applications
- Advancements in Battery Materials
- Vanadium and Halogenation Chemistry
- Extraction and Separation Processes
- Protein purification and stability
- Crystallography and molecular interactions
- 3D Printing in Biomedical Research
- Advanced Nanomaterials in Catalysis
- Welding Techniques and Residual Stresses
- Magnetism in coordination complexes
- Hemostasis and retained surgical items
- Advanced Sensor and Energy Harvesting Materials
- Geomechanics and Mining Engineering
- Supercapacitor Materials and Fabrication
- High Entropy Alloys Studies
- Organic and Molecular Conductors Research
- Advanced Welding Techniques Analysis
- Cardiac and Coronary Surgery Techniques
- Nanoparticles: synthesis and applications
Taiyuan University of Technology
2020-2024
Nanjing Tech University
2020-2024
Southern Medical University
2023-2024
Southwest Jiaotong University
2018-2024
China Railway Construction Investment Group Corporation
2023
China Railway Construction Corporation (China)
2023
State Key Laboratory of Materials-Oriented Chemical Engineering
2021
Chengdu University
2018
Jiangsu University of Science and Technology
2007
Tianjin University
2007
Abstract Endothelium can secrete vasoactive mediators and produce specific extracellular matrix, which contribute jointly to the thromboresistance regulation of vascular cell behaviors. From a bionic point view, introducing endothelium‐like functions onto cardiovascular stents represents most effective means improve hemocompatibility reduce late stent restenosis. However, current surface strategies for still have limitations, like lack multifunctionality, especially monotony in...
Thrombosis and infection are two major complications associated with central venous catheters (CVCs), which significantly contribute to morbidity mortality. Antifouling coating strategies currently represent an efficient approach for addressing such complications. However, existing antifouling coatings have limitations in terms of both duration effectiveness. Herein, we propose a durable zwitterionic polymer armor catheters. This is realized by pre-coating robust phenol-polyamine film...
Universal coatings with versatile surface adhesion, good mechanochemical robustness, and the capacity for secondary modification are of great scientific interest. However, incorporating these advantages into a system is still challenge. Here, we report series catechol-decorated polyallylamines (CPAs), denoted as pseudo-Mytilus edulis foot protein 5 (pseudo-Mefp-5), that mimic not only catechol amine groups but also backbone Mefp-5. CPAs can fabricate highly adhesive, robust, multifunctional...
The latest progress on polyoxovanadates modified with organic ligands or transition metals and is summarized. Not only the structural features main applications but also challenges focus of future research POV-based materials are discussed.
The photocatalytic reduction of CO2 to chemical fuels is attractive for addressing both the greenhouse effect and energy crisis, but key challenge design synthesis photocatalysts with remarkable performance under visible-light irradiation. Herein, we present two novel polyoxometalate-based organo–metallophosphate frameworks (POMPOs), formulated as [Zn4(PO4)(C7H8N4)6][BW12O40]·2H2O (1) [Co4(PO4)(C7H8N4)6][BW12O40]·1.5H2O (2). According single crystal analysis, compounds possess host (OMPO)...
Proteins, cells and bacteria adhering to the surface of medical devices can lead thrombosis infection, resulting in significant clinical mortality. Here, we report a zwitterionic polymers-armored amyloid-like protein engineering strategy called as "armored-tank" for dual functionalization devices. The is realized by decoration partially conformational transformed LZM (PCTL) assembly through oxidant-mediated process, followed armoring with super-hydrophilic poly-2-methacryloyloxyethyl...
Abstract Universal protein coatings have recently gained wide interest in medical applications due to their biocompatibility and ease of fabrication. However, the challenge persists activity preservation, significantly complicating functional design these coatings. Herein, an active dual‐protein surface engineering strategy assisted by a facile stepwise protein–protein interactions assembly (SPPIA) method for catheters reduce clot formation infection is proposed. This realized first partial...
Integration of two or more biomolecules with synergetic and complementary effects on a material surface can help to obtain multi-functions for various biomedical applications. However, the amounts integrated their physiological functions are compromised due limited anchoring sites. Herein, we propose novel concept film engineering strategy "from bulk modification". This new is realized by employing amine groups plasma polymerized allylamine (PPAm) grafting molecule e.g., thrombin inhibitor,...
Two hourglass-type molybdophosphate hybrids with the formulas [Cd(H2O)2DABT]4[Cd(H7P4Mo6O31)2]·19H2O (1) and (C2H5OH)(C3H5N2)6[Co3(H6P4Mo6O31)2]·H2O (2) (DABT= 3,3'-diamino-5,5'-bis(1H-1,2,4-triazole)) have been successfully designed synthesized via a hydrothermal method. Structure analysis revealed that inorganic moieties in compounds 1 2 are made up of {M[P4Mo6]2} (M = Cd/Co) structure, which were constructed by two (P4Mo6) units single transition metal (TM) (Cd/Co) atom as central metal....
The maximum exposure of polyoxometalates (POMs) is great significance to enhance the catalytic performance HKUST-1 with incorporated Keggin-type POMs. Herein, two phosphovanadomolybdates were encapsulated into via a hydrothermal method obtain polyoxometalate-based metal–organic frameworks, formulated as [Cu12(BTC)8(H2O)12][H4PMo11VO40]@(H2O)30 (1) and [Cu12(BTC)8(H2O)12][H5PMo10V2O40]@(H2O)49 (2). Single-crystal X-ray diffraction analysis indicates that compounds contain unique...
Carbon dioxide (CO2) and the combustion of sulfide in gasoline are main causes air pollution. A great deal attention has been paid to solving problem catalytic reaction seems be a decent choice. Due high-density Lewis acidic active sites, polyoxometalates undoubtedly an ideal choice for sulfur oxidation reaction. With reasons foregoing, two novel Zn-capped polyoxometalate-based organic-inorganic hybrids, {[α-PMoV2MoVI10O39(OH)Zn2][bbbm]3}·0.5C2H5OH (1) TBA2{[ε-PMoV8MoVI4O37(OH)3Zn4][phim]3}...
Percutaneous coronary intervention with stenting is the most widely adopted surgical technique for treatment of disease. However, in-stent restenosis (ISR) continues to cause serious concern. Improving functionality endothelial cells (ECs) importance dealing ISR. limited successes in vivo studies imply that underlying mechanism relating process a material has not been well understood date. Another determining factor long underestimated design stents immune response dominated by macrophages...
Two captivating molybdophosphate hybrids [M(P<sub>4</sub>Mo<sub>6</sub>O<sub>31</sub>)<sub>2</sub>]<italic>n</italic><sup>−</sup> (M = Co, Zn) have been successfully synthesized. Compound <bold>1</bold> shows good catalytic activity and the mechanism of its catalysis photoreduction CO<sub>2</sub> to CO has investigated.
Hydrogen energy is a renewable and clean source, which makes great difference in future sustainable systems. Visible-light-driven photocatalysis reaction involves harnessing the abundance of sunlight for hydrogen production among many catalytic technologies. However, fabrication photocatalysts that have distinctive performance visible light still primary challenge. Herein, two new Cu-modified polyoxotungstate hybrids, {[Cu2(bim)4(H2O)2](HBW12O40)2·(H2bim)2·8H2O} (1) (bim =...
Two MOFs display a rare cage-within-cage structure through MoO<sub>4</sub><sup>2−</sup> anions decomposed by H<sub>3</sub>PMo<sub>12</sub>O<sub>40</sub>. Meanwhile, <bold>Zn/Co/Mo-MOF</bold> exhibits remarkable CO production rate (7682 μmol g<sup>−1</sup> h<sup>−1</sup>) towards CO<sub>2</sub> photoreduction.
An innovative polyoxometalate-based cobalt-modified organophosphate framework was synthesized and applied for CO 2 reduction a high selectivity of 94.5% an ultra-high production rate 13 676 μmol g −1 h in photocatalytic investigations.