A5001818333- Chemical Reaction Mechanisms
- Synthesis and Biological Evaluation
- Synthesis and Reactions of Organic Compounds
- Structural and Chemical Analysis of Organic and Inorganic Compounds
- Chemical Reactions and Mechanisms
- Luminescence and Fluorescent Materials
- Synthesis and Reactivity of Heterocycles
- Lanthanide and Transition Metal Complexes
- Organic Light-Emitting Diodes Research
- Cyclopropane Reaction Mechanisms
- Molecular Sensors and Ion Detection
- X-ray Diffraction in Crystallography
- Ferrocene Chemistry and Applications
- Chemical Synthesis and Analysis
- Coordination Chemistry and Organometallics
- Synthesis and biological activity
- Crystallization and Solubility Studies
- Inorganic and Organometallic Chemistry
- Synthesis and Characterization of Heterocyclic Compounds
- Synthesis of Organic Compounds
- Organometallic Complex Synthesis and Catalysis
- Radical Photochemical Reactions
- Fluorine in Organic Chemistry
- Crystallography and molecular interactions
- Conducting polymers and applications
Southern Federal University
2014-2023
Institute of Physical and Organic Chemistry
1991-2023
Southern Scientific Center
2011-2020
Russian Academy of Sciences
2011-2020
Rostov State University of Civil Engineering
1994-1999
Humboldt-Universität zu Berlin
1995-1998
John Wiley & Sons (United Kingdom)
1992
Data on circumambulatory rearrangements caused by rapid migrations of substituents formed Group 13–17 elements around three- to nine-membered cyclopolyenes are generalised and systematised. Depending the ring size, nature migrating group, in medium, rate constants vary over a wide range from 106 10–8 s–1 at room temperature. Particular attention is given analysis mechanisms these ([1, j]-, [2,3]- [3,3]-sigmatropic shifts, haptotropic ionisation–recombination) correlation with structural...
Abstract The intrinsic mechanism of circumambulatory rearrangements 5‐bromo‐5‐methyl‐1,2,3,4‐tetramethoxycarbonylcyclopentadiene, 5‐bromo‐1,2,3,4 5‐pentamethoxycarbonylcyclopentadien and 5‐bromo‐ 1,2,3,4,5‐pentaphenylcyclopentadiene due to sigmatropic shifts bromine over the cyclopentadiene ring was proved, using dynamic 13 C 1 H NMR technique, be governed by successive intramolecular 1,5‐sigmatropic shifts. Semi‐empirical AM1 MINDO/3 calculations reactions paths performed for fluoro‐,...
N-Nitroso-N,N′-diarylamidines (1) and N-(1,2,3,4,5-pentakismethoxycarbonylcyclopentadienyl)-N,N′-diarylamidines (2) prepared by the reaction of N,N′-diarylamidines with 5-nitro-1,2,3,4,5-pentakismethoxycarbonylcyclopentadiene show fluxional behaviour arising from degenerate sigmatropic 1,3-shifts nitroso group in 3,3-shifts amidinyl moiety (2).