A5100461537- Organic Electronics and Photovoltaics
- Conducting polymers and applications
- Perovskite Materials and Applications
- Crystallization and Solubility Studies
- X-ray Diffraction in Crystallography
- Advanced Photocatalysis Techniques
- Catalytic C–H Functionalization Methods
- Advanced Nanomaterials in Catalysis
- Cyclopropane Reaction Mechanisms
- Nanoplatforms for cancer theranostics
- Nanomaterials for catalytic reactions
- Solar-Powered Water Purification Methods
- Sulfur-Based Synthesis Techniques
- Electrochemical sensors and biosensors
- Catalytic Alkyne Reactions
- Fullerene Chemistry and Applications
- Magnetism in coordination complexes
- Molecular Junctions and Nanostructures
- Photonic Crystals and Applications
- Liquid Crystal Research Advancements
- Organic Light-Emitting Diodes Research
- Lanthanide and Transition Metal Complexes
- Semiconductor materials and interfaces
- Advanced Chemical Physics Studies
- Catalytic Processes in Materials Science
Collaborative Innovation Center of Chemical Science and Engineering Tianjin
2015-2025
Tianjin University
2017-2025
Xinjiang Normal University
2024-2025
Affiliated Hospital of Qingdao University
2025
Qingdao University
2022-2025
Henan Provincial Chest Hospital
2024
Zhengzhou University
2008-2024
Nanjing Medical University
2024
Xuzhou Medical College
2024
Huazhong University of Science and Technology
2018-2024
A series of acceptor-donor-acceptor simple oligomer-like small molecules based on oligothiophenes, namely, DRCN4T-DRCN9T, were designed and synthesized. Their optical, electrical, thermal properties photovoltaic performances systematically investigated. Except for DRCN4T, excellent obtained DRCN5T-DRCN9T. The devices DRCN5T, DRCN7T, DRCN9T with axisymmetric chemical structures exhibit much higher short-circuit current densities than those DRCN6T DRCN8T centrosymmetric structures, which is...
Three small molecules named DR3TBDTT, DR3TBDTT-HD, and DR3TBD2T with a benzo[1,2-b:4,5-b′]dithiophene (BDT) unit as the central building block have been designed synthesized for solution-processed bulk-heterojunction solar cells. Power conversion efficiencies (PCEs) of 8.12% (certified 7.61%) 8.02% under AM 1.5G irradiation (100 mW cm–2) achieved DR3TBDTT- DR3TBDT2T-based organic photovoltaic devices (OPVs) PC71BM acceptor, respectively. The better PCEs were by improving short-circuit...
A small molecule named DR3TSBDT with dialkylthiol-substituted benzo[1,2-b:4,5-b']dithiophene (BDT) as the central unit was designed and synthesized for solution-processed bulk-heterojunction solar cells. notable power conversion efficiency of 9.95% (certified 9.938%) has been achieved under AM 1.5G irradiation (100 mW cm(-2)), an average PCE 9.60% based on 50 devices.
The first copper-catalyzed asymmetric decarboxylative [4 + 1] cycloaddition of propargylic carbamates and sulfur ylides was successfully developed. This strategy led to a series chiral indolines with synthetically flexible alkyne groups in good yields high enantio- diastereoselectivities (up 99% yield, 98% ee, >95:5 dr). A possible mechanism stereoinduction mode copper–allenylidenes were proposed as the dipolar intermediate.
Catalytic asymmetric cycloadditions of reactive ketene intermediates provide new opportunities for the production chiral heterocyclic molecules. Though known over 100 years, ketenes still remain underexplored in field transition-metal (TM)-catalyzed because (1) ketenes, as highly electron-deficient species, are possibly unstable to low-valence TMs (i.e., decarbonylation or aggregation) and (2) conventional thermal synthesis from acyl chlorides amines may be incompatible with TM catalysis...
Abstract Photonic elastomers that can change colors like a chameleon have shown great promise in various applications. However, it still remains challenge to produce artificial photonic with desired optical and mechanical properties. Here, the generation of metallosupramolecular polymer‐based tunable strength, angle‐independent structural color, self‐healing capability is reported. The are prepared by incorporating isotropically arranged monodispersed SiO 2 nanoparticles within...
The recent representative progress in the design and synthesis of A–D–A small molecules for organic solar cells is summarized.
Abstract Ternary solar cells comprising both fullerene and nonfullerene acceptors have shown a rapid increase in power conversion efficiency, which holds promise commercial applications. Despite the progress, there is still lack of fundamental understanding relations between microstructure (photovoltaic/mechanical) properties these ternary blend systems. In this work, dependence molecular packing, phase separation, mechanical properties, photovoltaic performance on acceptor composition...
Abstract Solar steam generation (SSG) through hydrogel‐based evaporators has shown great promise for freshwater production. However, developing with stable SSG performance in high‐salinity brines remains challenging. Herein, phase‐separated polyzwitterionic are presented sponge‐like structures comprising interconnected pores performance, which fabricated by photopolymerization of sulfobetaine methacrylate (SBMA) water‐dimethyl sulfoxide (DMSO) mixed solvents. It is that driven competitive...
Abstract Developing efficient and stable all‐polymer solar cells (all‐PSCs) has received increasing attention because of their mechanical robustness for flexible devices. Based on the CH‐series small molecule acceptors, a new polymer acceptor (PZC24) is reported obtains decent power conversion efficiency (PCE) 16.82% when blended with PM6. To further improve performance, an oligomeric (CH‐D1), which possesses same backbone structure as PZC24, proposed synthesized third component all‐PSC...
Abstract Structurally colored composite films, composed of orderly arranged colloids in polymeric matrix, are emerging flexible optical materials, but their production is bottlenecked by time-consuming procedures and limited material choices. Here, we present a mild approach to producing large-scale structurally films shearing supramolecular composites polymers with interactions. Leveraging dynamic connection dissociation interactions, force stretches the polymer chains drags migrate...
A series of solvents with different solubilities for DR3TBDTT and PC71 BM, boiling points, is used solvent vapor annealing (SVA) treatment to systematically investigate the solvent-morphology-performance relationship. The presence molecules inside bulk-heterojunction (BHJ) thin films promotes mobility both donor acceptor molecules, leading crystallization aggregation, which are important in modulating morphology.
Solar-driven water evaporation is of great importance for freshwater production via solar distillation and has attracted growing attention recently by the development heat localization strategies. Yet, when polluted used as source water, solar-driven might further deteriorate pollution. In this study, we report facile preparation multifunctional Ag3PO4-reduced graphene oxide (Ag3PO4-rGO) nanocomposite-coated textiles clean evaporation, photocatalysis, disinfection. The are obtained through...
We present an investigation of organic photovoltaic (OPV) cells with solution-processable graphene quantum dots (GQDs) as hole transport layers (HTLs). GQDs, uniform sizes and good conductivity, are demonstrated to be excellent HTLs in both polymer solar (PSCs) small-molecule (SMSCs) the blend poly(3-hexylthiophene):[6,6]-phenyl-C61-butyric acid methyl ester (P3HT:PC61BM) small molecule DR3TBDT:[6,6]-phenyl-C71-butyric (DR3TBDT:PC71M) active layer, respectively. The PSCs SMSCs based on GQDs...
Small molecules containing BDT units for solution processed organic solar cells have been reviewed.
A small molecule named DICTF was synthesized and an organic solar cell based on PTB7-Th:DICTF exhibited a high PCE of 7.93%.
Higher-order cycloadditions, particularly [8+2] are a straightforward and efficient strategy for constructing significant medium-sized architectures. Typically, configuration-restrained conjugated systems utilized as 8π-components higher-order concerted cycloadditions. However, this reason, 10-membered monocyclic skeletons have never been constructed via catalytic asymmetric cycloaddition with high peri- stereoselectivity. Here, we accomplished an enantioselective dipolar the merger of...
Abstract With the advances in organic photovoltaics (OPVs), development of low‐cost and easily accessible polymer donors is vital importance for OPV commercialization. Polythiophene (PT) its derivatives stand out as most promising members photovoltaic material family commercial applications, owing to their low cost high scalability synthesis. In recent years, PTs, paired with nonfullerene acceptors, have progressed rapidly performance. This Review gives an overview strategies designing PTs...
Two new acceptor–donor–acceptor (A-D-A) small molecules with 2,6-(4,4-bis(2-ethylhexyl)-4H-cyclopenta[2,1-b;3,4-b′]-dithiophene (DTC) and (4,4′-bis(2-ethylhexyl) dithieno[3,2-b:2′,3′-d]silole)–2,6-diyl (DTS) as the central building block unit 3-ethyl-rhodanine end-capping groups have been designed synthesized. The influence of bridging atoms on optical, electrochemical properties, packing morphology, device performance these two was systematically investigated. Although only difference one...
Two NIR-absorbing non-fullerene acceptors <bold>IDT2Se</bold> and <bold>IDT2Se-4F</bold> with selenophene as π bridges displayed high PCEs.
Two new wide-bandgap polythiophenes, i.e., poly[5,5′-bis(2-hexyldecyl)-(2,2′-bithiophene)-4,4′-dicarboxylate-alt-5,5′-3-chloro-2,2′-bithiophene] (PDCBT-Cl) and poly[5,5′-bis(2-hexyldecyl)-(2,2′-bithiophene)-4,4′-dicarboxylate-alt-5,5′-3,3′-dichloro-2,2′-bithiophene] (PDCBT-2Cl) comprising 3-chloro-2,2′-bithiophene 3,3′-dichloro-2,2′-bithiophene moieties, respectively, were synthesized for fullerene-free polymer solar cells (PSCs). For comparison, three other polymers based on...