A5101726037- Catalytic C–H Functionalization Methods
- Catalytic Cross-Coupling Reactions
- Oxidative Organic Chemistry Reactions
- Chemical Synthesis and Characterization
- Amphibian and Reptile Biology
- Turtle Biology and Conservation
- Wildlife Ecology and Conservation
- Radioactive element chemistry and processing
- Chemical and Physical Properties in Aqueous Solutions
- Soil and Water Nutrient Dynamics
- Immune cells in cancer
- Mine drainage and remediation techniques
- Antibiotic Use and Resistance
- Health and Medical Education
- Inflammation biomarkers and pathways
- Organophosphorus compounds synthesis
- Advanced Synthetic Organic Chemistry
- Freshwater macroinvertebrate diversity and ecology
- Catalytic Alkyne Reactions
- Phosphorus compounds and reactions
- Chemical Thermodynamics and Molecular Structure
- Calcium Carbonate Crystallization and Inhibition
- Accounting and Financial Management
- Nuclear materials and radiation effects
- Circular RNAs in diseases
Loyola University Chicago
2020-2023
University of Denver
2020-2023
University of Arizona
2020
Gesellschaft für Anlagen und Reaktorsicherheit
2013-2014
University of Bremen
1981
The myeloid differentiation factor Schlafen4 (Slfn4) marks a subset of myeloid-derived suppressor cells (MDSCs) in the stomach during Helicobacter -induced spasmolytic polypeptide-expressing metaplasia (SPEM). Objective To identify gene products expressed by Slfn4 + -MDSCs and to determine how they promote SPEM. Design We performed transcriptome analyses for both coding genes (mRNA RNA-Seq) non-coding (microRNAs using NanoString nCounter) flow-sorted SLFN4 – from -infected mice exhibiting at...
Habitat loss has been a primary driver of biodiversity declines throughout the United States. Native prairie ecosystems represent some most significant losses in land cover, and subsequently, prairie-dependent species are imperiled. Therefore, understanding ecology remaining remnant portions these is important to help manage their populations. Using radio-telemetry, we examined minimum convex polygon (MCP) 95% kernel density (KD) home ranges 20 (5 females, 15 males) Ornate Box Turtles...
As human-dominated land-use increases globally, urbanization is a prominent cause of decline in natural areas, including lentic ecosystems (i.e. lakes, ponds and wetlands). Lentic urban green spaces, such as parks, golf courses or forest preserves, could provide important habitat for organisms within the matrix. However, there lack data comparing habitats across these types. We quantified area preserve Chicago Metropolitan Region. measured pesticide concentrations, water chemistry,...
Declining reptilian populations has been a growing concern over the last couple of decades. One such declining species concern, Blanding's turtle Emydoidea blandingii , occurs as isolated in North American prairie‐wetlands and is at risk extirpation due to habitat loss fragmentation, increased predator (e.g. racoons, coyotes) supplemented resources urban environments. To help mitigate populations, wildlife managers have invested conservation this through head‐starting (i.e. reared ex situ)...
ADVERTISEMENT RETURN TO ISSUEPREVAddition/CorrectionORIGINAL ARTICLEThis notice is a correctionAddition to "Activity Coefficients of Fission Products in Highly Salinary Solutions Na+, K+, Mg2+, Ca2+, Cl–, and SO42–: Cs+"T. Scharge, A. G. Muñoz*, H. C. MoogCite this: J. Chem. Eng. Data 2013, 58, 1, 187–188Publication Date (Web):December 21, 2012Publication History Published online21 December 2012Published inissue 10 January...
Alkyne carbopalladation reactions represent a powerful approach to generating multiple new C–C bonds and substituted alkenes, however regioselectivity is often challenging for intermolecular variants. By utilizing ynol ethers as polarized alkynes we observe complete regiocontrol of migratory insertion with Pd–Ar species. A Heck reaction was used turn-over the catalytic cycle by intercepting vinyl-Pd adduct pendant alkene. When using o -iodo styrenes substrates resulting products are...
Alkyne carbopalladation reactions can rapidly generate multiple new C–C bonds; however, regioselectivity is challenging for intermolecular variants. Using ynol ethers, we observe complete regiocontrol of migratory insertion followed by a second with pendant alkene to turn-over the catalytic cycle. The resulting products are oligosubstituted 1-indenol ethers defined stereochemistry based on initial geometry. Blocking β-hydride elimination allowed C–H and reductive steps catalyst turnover.
Alkyne carbopalladation reactions represent a powerful approach to generating multiple new C–C bonds and substituted alkenes, however regioselectivity is often challenging for intermolecular variants. By utilizing ynol ethers as polarized alkynes we observe complete regiocontrol of migratory insertion with Pd–Ar species. A Heck reaction was used turn-over the catalytic cycle by intercepting vinyl-Pd adduct pendant alkene. When using <i>o</i>-iodo styrenes substrates resulting...