A5026346737- X-ray Diffraction in Crystallography
- Crystallization and Solubility Studies
- Fullerene Chemistry and Applications
- Crystal structures of chemical compounds
- Metal-Organic Frameworks: Synthesis and Applications
- Carbon Nanotubes in Composites
- Crystal Structures and Properties
- Electrochemical sensors and biosensors
- Crystallography and molecular interactions
- Synthesis and Properties of Aromatic Compounds
- Organometallic Compounds Synthesis and Characterization
- Graphene research and applications
- Catalytic Processes in Materials Science
- Enzyme Catalysis and Immobilization
- Advanced Photocatalysis Techniques
- Supramolecular Chemistry and Complexes
- Analytical Chemistry and Chromatography
- Mesoporous Materials and Catalysis
- Magnetism in coordination complexes
- Cancer-related molecular mechanisms research
- TiO2 Photocatalysis and Solar Cells
- Polyoxometalates: Synthesis and Applications
- Zeolite Catalysis and Synthesis
- Ferroptosis and cancer prognosis
- Metal Alloys Wear and Properties
The People's Hospital of Guangxi Zhuang Autonomous Region
2023-2024
Southwest Jiaotong University
2023
Ningbo University
2008-2022
Zhejiang University
2008
Nankai University
2002-2006
Qiqihar University
2004
MXenes have attracted intensive attention because of their widespread applications. As a well-studied member the MXene family, Ti2CO2 has been demonstrated to be semiconducting with ultrahigh carrier mobility, acting as candidate material for electronic devices. In this work, influence layer thickness on electrical conductivity is investigated combined first-principles density functional calculations and Boltzmann transport theory. Because interaction-induced band splitting, gap generally...
Two novel Co(II)-organic frameworks with helical structures, [Co(hfipbb)(py)]n (1) and {[Co4(OH)(H2O)(hfipbb)3(Hhfipbb)(bpp)2]·H2O}n (2) (H2hfipbb = 4,4′-(hexafluoroisopropylidene)bis(benzoic acid), py pyridine, bpp 1,3-bis(4-pyridyl)propane), have been assembled from flexible bent ligands. Complex 1 displays a 2-fold parallel interpenetrated layer network one-dimensional double channels, while 2 exhibits three-dimensional pillared helical-layer open framework six-connected self-penetrating...
The tumor microenvironment (TME) plays a crucial role in tumorigenesis, progression, and therapeutic response many cancers. This study aimed to comprehensively investigate the of TME colorectal cancer (CRC) by generating TMEscore based on gene expression.The patterns CRC datasets were investigated, TMEscores calculated. An unsupervised clustering method was used divide samples into clusters. associations between clinical features, prognosis, immune score, mutations, checkpoint inhibitors...
We report the development of PbSbO2Cl as a new anode material for lithium-ion batteries. It is prepared by simple hydrothermal method from Pb(NO3)2 and SbCl3. The as-prepared shows well-dispersed nano-micro structure with particle sizes 200–500 nm. initial discharge capacity 1011.0 mAh g−1 corresponding to 14.6 Li per formula storage in structure. In inverse charge process, reversible 731.8 can be delivered. This suggests that may promising high-capacity
Abstract Gastric cancer (GC), known for its high incidence and poor prognosis, urgently necessitates the identification of reliable prognostic biomarkers to enhance patient outcomes. We scrutinized data from 375 GC patients alongside 32 non-cancer controls, sourced TCGA database. A univariate Cox Proportional Hazards Model (COX) regression was employed evaluate expressions ferroptosis-related genes. This followed by application Least Absolute Shrinkage Selection Operator (LASSO) multivariate...
The two isomorphous title compounds, [1,5,9-tris(2-aminoethoxy)-3,7,11-trihydroxy-3,7,11-tribora-1,5,9-triborata-2,4,6,8,10,12-hexaoxa-13-oxoniatricyclo[7.3.1.0(5,13)]tridecane]cobalt(II), [Co(C(6)H(21)B(6)N(3)O(13))] or Co{B(6)O(7)(OH)(3)[O(CH(2))(2)NH(2)](3)}, and the Ni(II) analogue, [Ni(C(6)H(21)B(6)N(3)O(13))], each consist of an M(II) cation inorganic-organic hybrid {B(6)O(7)(OH)(3)[O(CH(2))(2)NH(2)](3)}(2-) anion. lies on a crystallographic threefold axis (as does one O atom) is...
Abstract Silicalite‐1 (S‐1) nanoparticles (80∼200 nm) were controlled to grow on the silica nano‐film of macroporous monoliths (MSMs) in situ by crystallization xerogel under steaming. The MSMs not only improve dispersibility and adsorption capacity S‐1 due their continuous pass‐through macropores, but also overcome problem separation difficulty monolithic character. strengthen mechanical strength local thickening nano‐film. mesopores etched during steaming give convenience for molecule transmission.
Oxaliplatin-based chemotherapy is the first-line treatment for colorectal cancer (CRC). Long noncoding RNAs (lncRNAs) have been implicated in sensitivity. This study aimed to identify lncRNAs related oxaliplatin sensitivity and predict prognosis of CRC patients underwent oxaliplatin-based chemotherapy.Data from Genomics Drug Sensitivity Cancer (GDSC) was used screen Four machine learning algorithms (LASSO, Decision tree, Random-forest, support vector machine) were applied key lncRNAs. A...
The title compound, [Zn(C2H3O2)(C6H18N4)][B5O6(OH)4], contains mixed-ligand [Zn(CH3COO)(teta)]+ complex cations (teta is triethylenetetramine) and pentaborate [B5O6(OH)4]- anions. anions are connected to one another through hydrogen bonds, forming a three-dimensional supramolecular network, in which the located.
Two new 2D metal–organic frameworks were assembled in different conditions. Single X-ray diffraction analyses reveal that complex 1 possesses packing of large helical channels filled by guest water molecules; and 2 has a 2-fold interpenetration layer-like structure with relatively petite channels, molecules residing the void spaces between neighboring layers. The diverse structures may result from dissimilar crystal growth mechanisms distinct thermal stable energies confirmed theoretical...
Semiempirical AM1 and MNDO methods are used to examine the relative stability of different isomers C59BHX2n (X = H, F; n 1,2). The energies show that most stable isomer C59BH3 is 5,6-isomer, which a 1,2-adduct C59BH; however, for C59BH5, 7,24,11,27-isomer energetically preferred structure, 1,4/1,4-adduct C59BH. addition patterns C59BHF2 from C59BH3, 7,24-isomer (a 1,4-adduct C59BH), lowest energy while C59BHF4, structure corresponds C59BH5. Comparing C59BH C59HN, calculation results indicate...
The title compound, {[La(4)(CH(3)CO(2))(10)(C(2)O(4))(H(2)O)(2)]·2H(2)O}(n), exhibits a two-dimensional layered structure with the oxalate and acetate ligands acting as bridges. asymmetric unit contains two crystallographically independent lanthanum(III) ions, half of an ligand, five ligands, one coordinated water mol-ecule uncoordinated mol-ecule. coordination numbers La ions are 9 10. Adjacent layers structure, which extend parallel to (100), linked by O-H⋯O hydrogen bonds also held...
Abstract Background and Aim The microsurface structure reflects the degree of damage to glands, which is related invasion depth early gastric cancer. To evaluate diagnostic value quantitative analysis for estimating Methods White‐light imaging narrow‐band (NBI) endoscopy were used visualize lesions included patients. area ratio depth‐predicting score (DPS) each patient calculated; meanwhile, lesion was examined by endoscopic ultrasonography (EUS). Results Ninety‐three patients between 2016...