A5051747328- Crystallization and Solubility Studies
- X-ray Diffraction in Crystallography
- Photochromic and Fluorescence Chemistry
- Radical Photochemical Reactions
- Porphyrin and Phthalocyanine Chemistry
- Oxidative Organic Chemistry Reactions
- Lanthanide and Transition Metal Complexes
- Metal complexes synthesis and properties
- Metal-Organic Frameworks: Synthesis and Applications
Slovak University of Technology in Bratislava
2022-2023
An anticancer azo bond-containing half-sandwich Ir( iii ) complex oxidizes ascorbate to dehydroascorbate, and recovers in the presence of reduced glutathione.
Series of phenylazo substituted pyridyl-benzimidazole ligands and their ferrous complexes have been prepared. Photoirradiation experiments allowed to investigate E – Z isomerisation ligands, which was further rationalized by computational study.
Abstract A study on the oxidation of N ‐Boc‐ and , N' ‐bis‐Boc‐protected 1,2‐diarylhydrazines with (diacetoxyiodo)benzene is reported. The reactions proceed quickly in acetic acid at slightly elevated temperatures, giving diaryldiazenes good to excellent yields. Electron‐donating electron‐withdrawing groups are well tolerated. This synthetic protocol also applies synthesising (aryldiazenyl)pyridines unsymmetrical 1,3,5‐tris(arylazo)benzenes.